**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13718-50-8 |Barium iodide hydrate | 96.0 | 237-276-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 42/43 68
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. May
cause sensitization by inhalation and skin contact.Possible risk of
irreversible effects.Hygroscopic (absorbs moisture from the air).Air
sensitive.Light sensitive.The toxicological properties of this
material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin. May
cause an allergic reaction in certain individuals.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
The toxicological properties of this substance have not been fully
investigated. The barium ion is a muscle poison causing stimulation
and then paralysis. Initial symptoms are gastrointestinal, including
nausea, vomiting, colic, and diarrhea, followed by myocardial and
general muscular stimulation with tingling in the extremities.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation. The
toxicological properties of this substance have not been fully
investigated. May cause an allergic response.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 13718-50-8:
United States OSHA: 0.5 mg/m3 TWA (listed under Barium).
Belgium - TWA: (listed as barium): 0.5 mg/m3 VLE
Malaysia: (listed as barium): 0.5 mg/m3 TWA
Netherlands: (listed as barium): 0.5 mg/m3 MAC
Spain: (listed as barium): 0.5 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white to off-white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 740 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density: 5.1500g/cm3
Molecular Formula: BaI2.xH2O
Molecular Weight: 391.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Air sensitive. Sensitive to light. Hygroscopic: absorbs moisture or
water from the air. Exposure to light can cause decomposition
forming Iodine particularly in acid conditions.
Deliquescent-dissolves and become liquid by absorbing moisture from
the air.
Conditions to Avoid:
Light, dust generation, exposure to air, exposure to moist air or
water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen iodide, iodine.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 13718-50-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Barium iodide hydrate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BARIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1564
Packing Group: III
IMO
Shipping Name: BARIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1564
Packing Group: III
RID/ADR
Shipping Name: BARIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1564
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 42/43 May cause sensitization by inhalation and
skin contact.
R 68 Possible risk of irreversible effects.
Safety Phrases:
S 22 Do not breathe dust.
S 24 Avoid contact with skin.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13718-50-8: No information available.
Canada
CAS# 13718-50-8 is listed on Canada's NDSL List.
CAS# 13718-50-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13718-50-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/15/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Bis-(trimethylsilyl)-trifluoroacetamide, 98+%
| 25561-30-2 |
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2-Chloro-m-xylene, 99%
| 6781-98-2 |
|
1,4-Dioxaspiro[4.5]Decan-8-One, 98%
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|
Alpha, Alpha, Alpha, 4-Tetrafluoro-M-Toluidine, 99%
| 2357-47-3 |
|
3-Aminophthalic Acid Hydrochloride, 98% (Titr.)
| 6946-22-1 |
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Arsenic atomic absorption standard solution, 1mg/ml as in 2% koh
| 1310-58-3 |
|
5-Bromocytosine, 99%
| 2240-25-7 |
|
2-Methyl-3-nitrobenzyl alcohol, 99%
| 23876-13-3 |
|
1-Chloro-3,4-dinitrobenzene, tech., 90%
| 610-40-2 |
|
(R)-(-)-2-Hydroxy-2-phenylpropionic acid, 99%
| 3966-30-1 |
|
l-(+)-Leucinol, 98%
| 7533-40-6 |
|
Barium iodide hydrate
| 13718-50-8 |
|
2-Phenylglycinonitrile hydrochloride, tech., 95
| 53941-45-0 |
|
BOC-L-Methionine, 99+%
| 2488-15-5 |
|
(R)-(-)-Alpha-Methoxyphenylacetic Acid 99%
| 3966-32-3 |
|
1-Phenyl-3-pyrazolidinone, 97%
| 92-43-3 |
|
6-Fluoro-DL-Tryptophan, 97%
| 7730-20-3 |
|
1,3-Dibromo-2-propanol
| 96-21-9 |
|
Cyanoacetic Acid, 99%
| 372-09-8 |
|
Methyl 4-bromocrotonate, tech., 85%
| 1117-71-1 |
|
4-Methyl-2-Pentanol, 99+% (gc)
| 108-11-2 |
|
2-Methylpyrazine, 99+%
| 109-08-0 |
|
Prostaglandin E2, 98%
| 363-24-6 |
|
2,6-Dimethyl-4-heptanone, Tech., 80%, Remainder mainly
| 108-83-8 |
|
4-(Trifluoromethoxy)benzaldehyde, 99%
| 659-28-9 |
|
Diethylenetriaminepentaacetic acid, 97%
| 67-43-6 |
|
3-Cyclohexylpropylchloride, 99+%
| 1124-62-5 |
|
Urea Hydrogen Peroxide (1 gr Tablets), Contains 35 Wt% H2O2,
| 124-43-6 |
|
Mercury(II) sulfide, red, 99.5+%
| 1344-48-5 |
|
Tetramethylthiuram disulfide, 97%
| 137-26-8 |
|
Tris-(Triphenylphosphine)-Ruthenium(II)Chloride, 98%
| 15529-49-4 |
|
p-Hydroxyphenethyl Alcohol, 98%
| 501-94-0 |
|
5-(P-Dimethylaminobenzylidene)Rhodanine, 97%(UV-VIS)
| 536-17-4 |
|
Chloroacetaldehyde Diethyl Acetal, 99%
| 621-62-5 |
|
4-Chlorophenyl isothiocyanate
| 2131-55-7 |
|
D-Cycloserine, 98+%
| 68-41-7 |
|
4-Isopropylbenzyl Alcohol, 97+%
| 536-60-7 |
|
Basic Fuchsin, For Staining Flagella (Cert )
| 58969-01-0 |
|
3-Mercaptopropionic acid, 99+%
| 107-96-0 |
|
N-Phenyl-1-Naphthylamine Hydrobromide
| 0-00-1 |
|
2-Hydroxy-4-Methylpyrimidine Hydro-Chloride, 97%
| 5348-51-6 |
|
4-Chloro-2-fluoroaniline,99%
| 57946-52-2 |
|
Dodecahydrotriphenylene, 99%
| 1610-39-5 |
|
Cyclohexyl phenyl ether, 95+% (GC)
| 2206-38-4 |
|
2-Bromo-2-butene, 98%, mixture of cis and trans
| 13294-71-8 |
|
Pentafluorobenzene, 98%
| 363-52-0 |
|
2,5-Dichlorobenzotrifluoride, 98+%
| 320-50-3 |
|
Coumarin 343, Laser Grade
| 55804-65-4 |
|
9-(Chloromethyl)Anthracene, 98+%
| 24463-19-2 |
|
2,4-Dimethoxybenzonitrile, 99%
| 4107-65-7 |
|
|