**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 372-09-8 |CYANOACETIC ACID | 99 | 206-743-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns.Hygroscopic (absorbs moisture
from the air).Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May be harmful if swallowed.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
None
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Use water spray to keep fire-exposed containers cool. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas. Containers may explode if exposed to fire.
Extinguishing Media:
Cool containers with flooding quantities of water until well after
fire is out. Use dry chemical, dry sand, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Take precautionary measures against static
discharges. Keep container tightly closed. Do not get on skin or in
eyes. Use with adequate ventilation. Use only in a chemical fume
hood. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Store in a tightly closed container. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 372-09-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: white
Odor: Odorless.
pH: Not available.
Vapor Pressure: 0.1 mm Hg @ 100
Viscosity: Not available.
Boiling Point: 108 deg C @ 15.00mm Hg
Freezing/Melting Point: 65 - 67 deg C
Autoignition Temperature: Not available.
Flash Point: 160 deg C ( 320.00 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: 160 deg C
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C3H3NO2
Molecular Weight: 85.06
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, exposure to
moist air or water, temperatures above 75C (167F).
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide,
acetonitrile.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 372-09-8: AG3675000
LD50/LC50:
CAS# 372-09-8: Oral, rat: LD50 = 1500 mg/kg.
Carcinogenicity:
CYANOACETIC ACID -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 372-09-8: 2
Canada
CAS# 372-09-8 is listed on Canada's DSL List.
CAS# 372-09-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 372-09-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/07/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Bis-(trimethylsilyl)-trifluoroacetamide, 98+%
| 25561-30-2 |
|
2-Chloro-m-xylene, 99%
| 6781-98-2 |
|
1,4-Dioxaspiro[4.5]Decan-8-One, 98%
| 4746-97-8 |
|
Alpha, Alpha, Alpha, 4-Tetrafluoro-M-Toluidine, 99%
| 2357-47-3 |
|
3-Aminophthalic Acid Hydrochloride, 98% (Titr.)
| 6946-22-1 |
|
Arsenic atomic absorption standard solution, 1mg/ml as in 2% koh
| 1310-58-3 |
|
5-Bromocytosine, 99%
| 2240-25-7 |
|
2-Methyl-3-nitrobenzyl alcohol, 99%
| 23876-13-3 |
|
1-Chloro-3,4-dinitrobenzene, tech., 90%
| 610-40-2 |
|
(R)-(-)-2-Hydroxy-2-phenylpropionic acid, 99%
| 3966-30-1 |
|
l-(+)-Leucinol, 98%
| 7533-40-6 |
|
Barium iodide hydrate
| 13718-50-8 |
|
2-Phenylglycinonitrile hydrochloride, tech., 95
| 53941-45-0 |
|
BOC-L-Methionine, 99+%
| 2488-15-5 |
|
(R)-(-)-Alpha-Methoxyphenylacetic Acid 99%
| 3966-32-3 |
|
1-Phenyl-3-pyrazolidinone, 97%
| 92-43-3 |
|
6-Fluoro-DL-Tryptophan, 97%
| 7730-20-3 |
|
1,3-Dibromo-2-propanol
| 96-21-9 |
|
Cyanoacetic Acid, 99%
| 372-09-8 |
|
Methyl 4-bromocrotonate, tech., 85%
| 1117-71-1 |
|
4-Methyl-2-Pentanol, 99+% (gc)
| 108-11-2 |
|
2-Methylpyrazine, 99+%
| 109-08-0 |
|
Prostaglandin E2, 98%
| 363-24-6 |
|
2,6-Dimethyl-4-heptanone, Tech., 80%, Remainder mainly
| 108-83-8 |
|
4-(Trifluoromethoxy)benzaldehyde, 99%
| 659-28-9 |
|
Diethylenetriaminepentaacetic acid, 97%
| 67-43-6 |
|
3-Cyclohexylpropylchloride, 99+%
| 1124-62-5 |
|
Urea Hydrogen Peroxide (1 gr Tablets), Contains 35 Wt% H2O2,
| 124-43-6 |
|
Mercury(II) sulfide, red, 99.5+%
| 1344-48-5 |
|
Tetramethylthiuram disulfide, 97%
| 137-26-8 |
|
Tris-(Triphenylphosphine)-Ruthenium(II)Chloride, 98%
| 15529-49-4 |
|
p-Hydroxyphenethyl Alcohol, 98%
| 501-94-0 |
|
5-(P-Dimethylaminobenzylidene)Rhodanine, 97%(UV-VIS)
| 536-17-4 |
|
Chloroacetaldehyde Diethyl Acetal, 99%
| 621-62-5 |
|
4-Chlorophenyl isothiocyanate
| 2131-55-7 |
|
D-Cycloserine, 98+%
| 68-41-7 |
|
4-Isopropylbenzyl Alcohol, 97+%
| 536-60-7 |
|
Basic Fuchsin, For Staining Flagella (Cert )
| 58969-01-0 |
|
3-Mercaptopropionic acid, 99+%
| 107-96-0 |
|
N-Phenyl-1-Naphthylamine Hydrobromide
| 0-00-1 |
|
2-Hydroxy-4-Methylpyrimidine Hydro-Chloride, 97%
| 5348-51-6 |
|
4-Chloro-2-fluoroaniline,99%
| 57946-52-2 |
|
Dodecahydrotriphenylene, 99%
| 1610-39-5 |
|
Cyclohexyl phenyl ether, 95+% (GC)
| 2206-38-4 |
|
2-Bromo-2-butene, 98%, mixture of cis and trans
| 13294-71-8 |
|
Pentafluorobenzene, 98%
| 363-52-0 |
|
2,5-Dichlorobenzotrifluoride, 98+%
| 320-50-3 |
|
Coumarin 343, Laser Grade
| 55804-65-4 |
|
9-(Chloromethyl)Anthracene, 98+%
| 24463-19-2 |
|
2,4-Dimethoxybenzonitrile, 99%
| 4107-65-7 |
|
|