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MSDS 
:
 Mercury(II) sulfide, red, 99.5+%
CAS 
:
 1344-48-5
SYNONYMS 
:
 Vermilion; Chinese Red; C.I. Pigment 106; C.I. 77766
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1344-48-5 |Mercury(II) sulfide, red | 99.5+% | 215-696-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+
Risk Phrases: 26/27/28 33

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Very toxic by inhalation, in contact with skin and if swallowed.
Danger of cumulative effects.

Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be fatal if absorbed through the
skin.
Ingestion:
May be fatal if swallowed. May cause irritation of the digestive
tract. May cause central nervous system effects.
Inhalation:
May be fatal if inhaled. May cause respiratory tract irritation.
Chronic:
May cause kidney injury. Chronic exposure to mercury may cause
permanent central nervous system damage, fatigue, weight loss,
tremors, personality changes.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Antidote:
The use of Dimercaprol or BAL (British Anti-Lewisite) as a chelating
agent should be determined by qualified medical personnel.

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Wash area with soap and water. Clean up spills
immediately, observing precautions in the Protective Equipment
section. Avoid generating dusty conditions.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Do not store in direct sunlight. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Poison room locked.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1344-48-5:
United States OSHA: 0.1 mg/m3 Ceiling (listed under Mercury, ary
and inorganic compounds).
Belgium - TWA: (listed as mercury inorganic compounds): 0.025 mg/
VLE (as Hg)
France - VME: (listed as mercury inorganic compounds): 0.1 mg/m3
(as Hg)
Germany: (listed as mercury inorganic compounds): 0.1 mg/m3 VME (
Hg)
Germany: (listed as mercury inorganic compounds): Skin absorber
Malaysia: (listed as mercury, aryl and inorganic compounds): 0.1
mg/m3 TWA (as Hg)
Netherlands: (listed as mercury inorganic compounds): 0.15 mg/m3
Netherlands: (listed as mercury inorganic compounds): 0.05 mg/m3
Russia: (listed as mercury inorganic compounds): 0.2 mg/m3 TWA (a
Hg)
Russia: (listed as mercury inorganic compounds): 0.05 mg/m3 STEL
Hg)
Spain: (listed as mercury inorganic compounds): 0.025 mg/m3 VLA-E
(as Hg)

Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Powder
Color: bright red - red
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 583.5 deg C subl
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 8.1000g/cm3
Molecular Formula: HgS
Molecular Weight: 232.65

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
May decompose when exposed to light.
Conditions to Avoid:
Light, dust generation, temperatures above 250C.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids.
Hazardous Decomposition Products:
Oxides of sulfur, mercury/mercury oxides.
Hazardous Polymerization: Has not been reported

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 1344-48-5: OX0720000
LD50/LC50:
Not available.
Carcinogenicity:
Mercury(II) sulfide, red -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: MERCURY COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 2025
Packing Group: III
IMO
Shipping Name: MERCURY COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 2025
Packing Group: III
RID/ADR
Shipping Name: MERCURY COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 2025
Packing group: III

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 1344-48-5: No information available.
Canada
CAS# 1344-48-5 is listed on Canada's DSL List.
CAS# 1344-48-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1344-48-5 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 1/27/1998 Revision #3 Date: 10/31/2003

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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