**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 118-52-5 |1,3-Dichloro-5,5-dimethylhydantoin | ca 100 | 204-258-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and
skin.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Do NOT get water inside containers. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Avoid ingestion and inhalation. Use with
adequate ventilation. Do not allow contact with water. Keep from
contact with moist air and steam.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 118-52-5:
United Kingdom, WEL - TWA: 0.2 mg/m3 TWA
United Kingdom, WEL - STEL: 0.4 mg/m3 STEL
United States OSHA: 0.2 mg/m3 TWA
Belgium - TWA: 0.2 mg/m3 VLE
Belgium - STEL: 0.4 mg/m3 VLE
France - VME: 0.2 mg/m3 VME
Germany: 0.2 mg/m3 TWA (inhalable fraction)
Malaysia: 0.2 mg/m3 TWA
Netherlands: 0.2 mg/m3 MAC
Spain: 0.2 mg/m3 VLA-ED
Spain: 0.4 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white
Odor: chlorine-like
pH: ~4.4 (aq. soln.)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Decomposes
Freezing/Melting Point: 134 - 136 deg C
Autoignition Temperature: Not available.
Flash Point: 191 deg C ( 375.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 191 deg C
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C5H6Cl2N2O2
Molecular Weight: 197.02
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, moisture, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, water, easily oxidizable materials, strong
reducing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, phosgene, carbon monoxide,
irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 118-52-5: MU0700000
LD50/LC50:
CAS# 118-52-5: Draize test, rabbit, skin: 500 mg/24H Severe; Draize
test, rabbit, skin: 100 mg/24H Severe; Oral, rabbit: LD50 = 1520
mg/kg; Oral, rat: LD50 = 542 mg/kg; Skin, rabbit: LD50 = >20 gm/kg.
Carcinogenicity:
1,3-Dichloro-5,5-dimethylhydantoin -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 118-52-5: No information available.
Canada
CAS# 118-52-5 is listed on Canada's DSL List.
CAS# 118-52-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 118-52-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/15/1998 Revision #3 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3,4-Diacetoxy-1-Butene, 97% (GC)
| 18085-02-4 |
|
3-Cyano-4,6-Dimethyl-2-Hydroxypyridine, 97%
| 769-28-8 |
|
Tetramethylammonium Bromide
| 64-20-0 |
|
Sulfanilyl Fluoride
| 98-62-4 |
|
4-Chloro-2-Nitroaniline, 99%
| 89-63-4 |
|
Ethyl Picolinate, 99%
| 2524-52-9 |
|
Allyl heptanoate, 98+%
| 142-19-8 |
|
4-Hydroxypyrazolo(3,4-d)pyrimidine, 98%
| 315-30-0 |
|
2-Ethoxy-3-Buten-1-ol
| 34684-08-7 |
|
4-Phenyl-2-Butyl Acetate, 98+%
| 10415-88-0 |
|
2-Bromo-4-fluorotoluene, 97+%
| 1422-53-3 |
|
Glycidyl phenyl ether, 99%
| 122-60-1 |
|
Benzyl bromide, 98%
| 100-39-0 |
|
P-tert.-butyl-1,3-dihydroxy-2,4-dimercaptocalix(4)arene
| |
|
2',4'-Difluoropropiophenone, 98%
| 85068-30-0 |
|
4,4'Bicyclo??2.2.2??hept-2-Ylidenebisphenol
| 1943-96-0 |
|
1-Methoxy-4-Nitronaphthalene
| 4900-63-4 |
|
3,4-Dimethylphenol, 99%
| 95-65-8 |
|
Dipropylsulfide, 98+%
| 111-47-7 |
|
4-Methylpiperidine, 99%
| 626-58-4 |
|
4-Methyl-5-thiazoleethanol, 98%
| 137-00-8 |
|
2-Acetamidofluorene, 95+%
| 53-96-3 |
|
2-Chloro-6-Fluorophenylacetic Acid, 98%
| 37777-76-7 |
|
(2r,3s)-1-carboxy-4-pentyl-2,3-dihydroxy- cyclohexa-4,6-diene
| |
|
(R)-(-)-2-Amino-2-methylbutanedioic acid, 99+% (80% e.e.)
| 14603-76-0 |
|
Iodine Solution According to WIJS, 0.1 Mol ICl/l
| 64-19-7 |
|
2-Ethylbutyryl Chloride, 99% (Titr.)
| 2736-40-5 |
|
(1S,2S)-(-)-N,N'-Dimethyl-1,2-Diphenyl-1,2 -Ethane Diamine, 99%
| 70749-06-3 |
|
alpha, alpha-Diphenyl-gamma-butyrolactone, tech.
| 959-33-1 |
|
1-Naphthol-3,6-disulfonic acid, disodium salt, tech.
| 20349-39-7 |
|
Dibenzyl phosphite, tech.
| 17176-77-1 |
|
1,3-Dichloro-5,5-Dimethylhydantoin Min. Available Chlorine 68%
| 118-52-5 |
|
1-Phenyl-1-cyclopropanecarbonitrile, 97%
| 935-44-4 |
|
Ethyl Cyanoacetate, 98+%
| 105-56-6 |
|
Propylene sulfide, 98%
| 1072-43-1 |
|
N,N-Dimethyl-1,4-phenylenediamine sulfate, (2:1) 99% (titr.)
| 60160-75-0 |
|
2-Hydroxypyridine, 97%
| 142-08-5 |
|
5,6,7,8-Tetrahydro-1-naphthol, 99%
| 529-35-1 |
|
2-(Tetrahydrofurfuryloxy)-Tetrahydropyran 98%
| 710-14-5 |
|
1-Bromohexane, 99+%
| 111-25-1 |
|
5-Chloro-2-Methylaniline, 98%
| 95-79-4 |
|
1,2-Difluoro-4-iodobenzene, 99%
| 64248-58-4 |
|
3-Methyl-1-phenyl-1H-pyrazole
| 1128-54-7 |
|
1-Dodecyne, 98%
| 765-03-7 |
|
Fast Red TR Salt
| 3165-93-3 |
|
4-Methylsulphonylbenzoic Acid, 95+%
| 4052-30-6 |
|
Methyl Alpha-Chloroacrylate, 99% (GC)
| 80-63-7 |
|
Lumichrome
| 1086-80-2 |
|
Bisphenol A Diacetate, 99 +%
| 10192-62-8 |
|
3,4,5-Trimethoxyphenylacetic Acid, 99%
| 951-82-6 |
|
|