**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 122-60-1 |Glycidyl phenyl ether | 99 | 204-557-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 37/38 43 45 20 52/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to respiratory system and skin. May cause sensitization
by skin contact. May cause cancer. Harmful by inhalation. Harmful to
aquatic organisms, may cause long-term adverse effects in the
aquatic environment.Cancer suspect agent.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
May be harmful if absorbed through the skin.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema. Harmful if inhaled.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. May cause cancer according to animal studies. Cancer
suspect agent.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation. Use only in a chemical fume
hood.
Storage:
Keep container closed when not in use. Deep freeze (below -20C).
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 122-60-1:
United States OSHA: 10 ppm TWA; 60 mg/m3 TWA
Belgium - TWA: 0.1 ppm VLE; 0.6 mg/m3 VLE
France - VME: 1 ppm VME; 6 mg/m3 VME
Malaysia: 0.1 ppm TWA; 0.6 mg/m3 TWA
Netherlands: 0.1 ppm MAC; 0.6 mg/m3 MAC
Spain: 0.1 ppm VLA-ED; 0.62 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 11.4 hPa @ 120
Viscosity: 7 MPA 20.00 deg C
Boiling Point: 245 deg C @ 760.00mm Hg
Freezing/Melting Point: 3.5 deg C
Autoignition Temperature: Not available.
Flash Point: 115 deg C ( 239.00 deg F)
Explosion Limits, lower: 1.10 vol %
Explosion Limits, upper: .00 vol %
Decomposition Temperature:
Solubility in water: 2.4 g/l (20 c)
Specific Gravity/Density: 1.1080g/cm3
Molecular Formula: C9H10O2
Molecular Weight: 150.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, acids, bases, amines.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 122-60-1: TZ3675000
LD50/LC50:
CAS# 122-60-1: Draize test, rabbit, eye: 111 mg Mild; Draize test,
rabbit, eye: 250 ug/24H Severe; Draize test, rabbit, skin: 20 mg/24H
Moderate; Inhalation, mouse: LC50 = >100 ppm/4H; Inhalation, rat:
LC50 = >100 ppm/8H; Oral, mouse: LD50 = 1400 mg/kg; Oral, rat: LD50
= 3850 mg/kg; Skin, rabbit: LD50 = 1500 uL/kg.
Oral, mouse LD50: 1400 mg/kg
mg/kg
LC50: >100ppm/8H
Carcinogenicity:
Glycidyl phenyl ether -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
California: carcinogen, initial date 10/1/90
IARC: Group 2B carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Goldfish: LC50 = 43 mg/L; 96 Hr.; Modified ASTMD1345
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 45 May cause cancer.
R 20 Harmful by inhalation.
R 37/38 Irritating to respiratory system and skin.
R 43 May cause sensitization by skin contact.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 122-60-1: 2
Canada
CAS# 122-60-1 is listed on Canada's DSL List.
CAS# 122-60-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 122-60-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/16/1999 Revision #4 Date: 2/02/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3,4-Diacetoxy-1-Butene, 97% (GC)
| 18085-02-4 |
|
3-Cyano-4,6-Dimethyl-2-Hydroxypyridine, 97%
| 769-28-8 |
|
Tetramethylammonium Bromide
| 64-20-0 |
|
Sulfanilyl Fluoride
| 98-62-4 |
|
4-Chloro-2-Nitroaniline, 99%
| 89-63-4 |
|
Ethyl Picolinate, 99%
| 2524-52-9 |
|
Allyl heptanoate, 98+%
| 142-19-8 |
|
4-Hydroxypyrazolo(3,4-d)pyrimidine, 98%
| 315-30-0 |
|
2-Ethoxy-3-Buten-1-ol
| 34684-08-7 |
|
4-Phenyl-2-Butyl Acetate, 98+%
| 10415-88-0 |
|
2-Bromo-4-fluorotoluene, 97+%
| 1422-53-3 |
|
Glycidyl phenyl ether, 99%
| 122-60-1 |
|
Benzyl bromide, 98%
| 100-39-0 |
|
P-tert.-butyl-1,3-dihydroxy-2,4-dimercaptocalix(4)arene
| |
|
2',4'-Difluoropropiophenone, 98%
| 85068-30-0 |
|
4,4'Bicyclo??2.2.2??hept-2-Ylidenebisphenol
| 1943-96-0 |
|
1-Methoxy-4-Nitronaphthalene
| 4900-63-4 |
|
3,4-Dimethylphenol, 99%
| 95-65-8 |
|
Dipropylsulfide, 98+%
| 111-47-7 |
|
4-Methylpiperidine, 99%
| 626-58-4 |
|
4-Methyl-5-thiazoleethanol, 98%
| 137-00-8 |
|
2-Acetamidofluorene, 95+%
| 53-96-3 |
|
2-Chloro-6-Fluorophenylacetic Acid, 98%
| 37777-76-7 |
|
(2r,3s)-1-carboxy-4-pentyl-2,3-dihydroxy- cyclohexa-4,6-diene
| |
|
(R)-(-)-2-Amino-2-methylbutanedioic acid, 99+% (80% e.e.)
| 14603-76-0 |
|
Iodine Solution According to WIJS, 0.1 Mol ICl/l
| 64-19-7 |
|
2-Ethylbutyryl Chloride, 99% (Titr.)
| 2736-40-5 |
|
(1S,2S)-(-)-N,N'-Dimethyl-1,2-Diphenyl-1,2 -Ethane Diamine, 99%
| 70749-06-3 |
|
alpha, alpha-Diphenyl-gamma-butyrolactone, tech.
| 959-33-1 |
|
1-Naphthol-3,6-disulfonic acid, disodium salt, tech.
| 20349-39-7 |
|
Dibenzyl phosphite, tech.
| 17176-77-1 |
|
1,3-Dichloro-5,5-Dimethylhydantoin Min. Available Chlorine 68%
| 118-52-5 |
|
1-Phenyl-1-cyclopropanecarbonitrile, 97%
| 935-44-4 |
|
Ethyl Cyanoacetate, 98+%
| 105-56-6 |
|
Propylene sulfide, 98%
| 1072-43-1 |
|
N,N-Dimethyl-1,4-phenylenediamine sulfate, (2:1) 99% (titr.)
| 60160-75-0 |
|
2-Hydroxypyridine, 97%
| 142-08-5 |
|
5,6,7,8-Tetrahydro-1-naphthol, 99%
| 529-35-1 |
|
2-(Tetrahydrofurfuryloxy)-Tetrahydropyran 98%
| 710-14-5 |
|
1-Bromohexane, 99+%
| 111-25-1 |
|
5-Chloro-2-Methylaniline, 98%
| 95-79-4 |
|
1,2-Difluoro-4-iodobenzene, 99%
| 64248-58-4 |
|
3-Methyl-1-phenyl-1H-pyrazole
| 1128-54-7 |
|
1-Dodecyne, 98%
| 765-03-7 |
|
Fast Red TR Salt
| 3165-93-3 |
|
4-Methylsulphonylbenzoic Acid, 95+%
| 4052-30-6 |
|
Methyl Alpha-Chloroacrylate, 99% (GC)
| 80-63-7 |
|
Lumichrome
| 1086-80-2 |
|
Bisphenol A Diacetate, 99 +%
| 10192-62-8 |
|
3,4,5-Trimethoxyphenylacetic Acid, 99%
| 951-82-6 |
|
|