**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 935-44-4 |1-Phenyl-1-cyclopropanecarbonitrile | 97 | 213-304-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The
toxicological properties of this material have not been fully
investigated.Harmful.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin. The toxicological properties of this material have not been
fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. May be harmful if
inhaled.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Absorb spill using an absorbent, non-combustible
material such as earth, sand, or vermiculite. Do not use combustible
materials such as sawdust. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Keep containers tightly closed. Store in a cool, dry area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 935-44-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: very slightly yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 133.0 - 137.0 deg C @ 30.00mm
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: 1.0000g/cm3
Molecular Formula: C10H9N
Molecular Weight: 143.19
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong acids, strong
bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 935-44-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Phenyl-1-cyclopropanecarbonitrile -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 935-44-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 935-44-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 935-44-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3,4-Diacetoxy-1-Butene, 97% (GC)
| 18085-02-4 |
|
3-Cyano-4,6-Dimethyl-2-Hydroxypyridine, 97%
| 769-28-8 |
|
Tetramethylammonium Bromide
| 64-20-0 |
|
Sulfanilyl Fluoride
| 98-62-4 |
|
4-Chloro-2-Nitroaniline, 99%
| 89-63-4 |
|
Ethyl Picolinate, 99%
| 2524-52-9 |
|
Allyl heptanoate, 98+%
| 142-19-8 |
|
4-Hydroxypyrazolo(3,4-d)pyrimidine, 98%
| 315-30-0 |
|
2-Ethoxy-3-Buten-1-ol
| 34684-08-7 |
|
4-Phenyl-2-Butyl Acetate, 98+%
| 10415-88-0 |
|
2-Bromo-4-fluorotoluene, 97+%
| 1422-53-3 |
|
Glycidyl phenyl ether, 99%
| 122-60-1 |
|
Benzyl bromide, 98%
| 100-39-0 |
|
P-tert.-butyl-1,3-dihydroxy-2,4-dimercaptocalix(4)arene
| |
|
2',4'-Difluoropropiophenone, 98%
| 85068-30-0 |
|
4,4'Bicyclo??2.2.2??hept-2-Ylidenebisphenol
| 1943-96-0 |
|
1-Methoxy-4-Nitronaphthalene
| 4900-63-4 |
|
3,4-Dimethylphenol, 99%
| 95-65-8 |
|
Dipropylsulfide, 98+%
| 111-47-7 |
|
4-Methylpiperidine, 99%
| 626-58-4 |
|
4-Methyl-5-thiazoleethanol, 98%
| 137-00-8 |
|
2-Acetamidofluorene, 95+%
| 53-96-3 |
|
2-Chloro-6-Fluorophenylacetic Acid, 98%
| 37777-76-7 |
|
(2r,3s)-1-carboxy-4-pentyl-2,3-dihydroxy- cyclohexa-4,6-diene
| |
|
(R)-(-)-2-Amino-2-methylbutanedioic acid, 99+% (80% e.e.)
| 14603-76-0 |
|
Iodine Solution According to WIJS, 0.1 Mol ICl/l
| 64-19-7 |
|
2-Ethylbutyryl Chloride, 99% (Titr.)
| 2736-40-5 |
|
(1S,2S)-(-)-N,N'-Dimethyl-1,2-Diphenyl-1,2 -Ethane Diamine, 99%
| 70749-06-3 |
|
alpha, alpha-Diphenyl-gamma-butyrolactone, tech.
| 959-33-1 |
|
1-Naphthol-3,6-disulfonic acid, disodium salt, tech.
| 20349-39-7 |
|
Dibenzyl phosphite, tech.
| 17176-77-1 |
|
1,3-Dichloro-5,5-Dimethylhydantoin Min. Available Chlorine 68%
| 118-52-5 |
|
1-Phenyl-1-cyclopropanecarbonitrile, 97%
| 935-44-4 |
|
Ethyl Cyanoacetate, 98+%
| 105-56-6 |
|
Propylene sulfide, 98%
| 1072-43-1 |
|
N,N-Dimethyl-1,4-phenylenediamine sulfate, (2:1) 99% (titr.)
| 60160-75-0 |
|
2-Hydroxypyridine, 97%
| 142-08-5 |
|
5,6,7,8-Tetrahydro-1-naphthol, 99%
| 529-35-1 |
|
2-(Tetrahydrofurfuryloxy)-Tetrahydropyran 98%
| 710-14-5 |
|
1-Bromohexane, 99+%
| 111-25-1 |
|
5-Chloro-2-Methylaniline, 98%
| 95-79-4 |
|
1,2-Difluoro-4-iodobenzene, 99%
| 64248-58-4 |
|
3-Methyl-1-phenyl-1H-pyrazole
| 1128-54-7 |
|
1-Dodecyne, 98%
| 765-03-7 |
|
Fast Red TR Salt
| 3165-93-3 |
|
4-Methylsulphonylbenzoic Acid, 95+%
| 4052-30-6 |
|
Methyl Alpha-Chloroacrylate, 99% (GC)
| 80-63-7 |
|
Lumichrome
| 1086-80-2 |
|
Bisphenol A Diacetate, 99 +%
| 10192-62-8 |
|
3,4,5-Trimethoxyphenylacetic Acid, 99%
| 951-82-6 |
|
|