**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 80-63-7 |Methyl-2-Chloroacrylate | 99 | 201-298-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 10 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Causes burns.Corrosive.Lachrymator (substance which
increases the flow of tears).
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. This material is a vesicant, that is, it will
induce blistering. May cause cyanosis of the extremities. May cause
skin rash (in milder cases), and cold and clammy skin with cyanosis
or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. May
cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Causes gastrointestinal tract burns. May cause perforation
of the digestive tract. Ingestion of large amounts may cause CNS
depression. May cause systemic effects.
Inhalation:
May be fatal if inhaled. Causes chemical burns to the respiratory
tract. Aspiration may lead to pulmonary edema. Vapors may cause
dizziness or suffocation. May cause systemic effects. May cause
burning sensation in the chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Keep away from heat, sparks
and flame. Do not get on skin or in eyes. Do not ingest or inhale.
Use with adequate ventilation. Discard contaminated shoes. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use.
Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 80-63-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: chlorine-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 52 deg C @ 50.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 33 deg C ( 91.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C4H5ClO2
Molecular Weight: 120.54
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 80-63-7: AS6380000
LD50/LC50:
CAS# 80-63-7: Draize test, rabbit, skin: 500 mg Severe; Inhalation,
mouse: LC50 = 500 mg/m3/2H; Inhalation, rabbit: LC50 = 500 mg/m3/2H;
Inhalation, rat: LC50 = 500 mg/m3/2H; Oral, rat: LD50 = 68 mg/kg;
Skin, rabbit: LD50 = 270 mg/kg.
Carcinogenicity:
Methyl-2-Chloroacrylate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S*
Hazard Class: 3 (8)
UN Number: 2924
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3.3 (8)
UN Number: 2924
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3
UN Number: 2924
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 34 Causes burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 28 After contact with skin, wash immediately
with...
S 33 Take precautionary measures against static
discharges.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 80-63-7: No information available.
Canada
CAS# 80-63-7 is listed on Canada's NDSL List.
CAS# 80-63-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 80-63-7 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/19/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3,4-Diacetoxy-1-Butene, 97% (GC)
| 18085-02-4 |
|
3-Cyano-4,6-Dimethyl-2-Hydroxypyridine, 97%
| 769-28-8 |
|
Tetramethylammonium Bromide
| 64-20-0 |
|
Sulfanilyl Fluoride
| 98-62-4 |
|
4-Chloro-2-Nitroaniline, 99%
| 89-63-4 |
|
Ethyl Picolinate, 99%
| 2524-52-9 |
|
Allyl heptanoate, 98+%
| 142-19-8 |
|
4-Hydroxypyrazolo(3,4-d)pyrimidine, 98%
| 315-30-0 |
|
2-Ethoxy-3-Buten-1-ol
| 34684-08-7 |
|
4-Phenyl-2-Butyl Acetate, 98+%
| 10415-88-0 |
|
2-Bromo-4-fluorotoluene, 97+%
| 1422-53-3 |
|
Glycidyl phenyl ether, 99%
| 122-60-1 |
|
Benzyl bromide, 98%
| 100-39-0 |
|
P-tert.-butyl-1,3-dihydroxy-2,4-dimercaptocalix(4)arene
| |
|
2',4'-Difluoropropiophenone, 98%
| 85068-30-0 |
|
4,4'Bicyclo??2.2.2??hept-2-Ylidenebisphenol
| 1943-96-0 |
|
1-Methoxy-4-Nitronaphthalene
| 4900-63-4 |
|
3,4-Dimethylphenol, 99%
| 95-65-8 |
|
Dipropylsulfide, 98+%
| 111-47-7 |
|
4-Methylpiperidine, 99%
| 626-58-4 |
|
4-Methyl-5-thiazoleethanol, 98%
| 137-00-8 |
|
2-Acetamidofluorene, 95+%
| 53-96-3 |
|
2-Chloro-6-Fluorophenylacetic Acid, 98%
| 37777-76-7 |
|
(2r,3s)-1-carboxy-4-pentyl-2,3-dihydroxy- cyclohexa-4,6-diene
| |
|
(R)-(-)-2-Amino-2-methylbutanedioic acid, 99+% (80% e.e.)
| 14603-76-0 |
|
Iodine Solution According to WIJS, 0.1 Mol ICl/l
| 64-19-7 |
|
2-Ethylbutyryl Chloride, 99% (Titr.)
| 2736-40-5 |
|
(1S,2S)-(-)-N,N'-Dimethyl-1,2-Diphenyl-1,2 -Ethane Diamine, 99%
| 70749-06-3 |
|
alpha, alpha-Diphenyl-gamma-butyrolactone, tech.
| 959-33-1 |
|
1-Naphthol-3,6-disulfonic acid, disodium salt, tech.
| 20349-39-7 |
|
Dibenzyl phosphite, tech.
| 17176-77-1 |
|
1,3-Dichloro-5,5-Dimethylhydantoin Min. Available Chlorine 68%
| 118-52-5 |
|
1-Phenyl-1-cyclopropanecarbonitrile, 97%
| 935-44-4 |
|
Ethyl Cyanoacetate, 98+%
| 105-56-6 |
|
Propylene sulfide, 98%
| 1072-43-1 |
|
N,N-Dimethyl-1,4-phenylenediamine sulfate, (2:1) 99% (titr.)
| 60160-75-0 |
|
2-Hydroxypyridine, 97%
| 142-08-5 |
|
5,6,7,8-Tetrahydro-1-naphthol, 99%
| 529-35-1 |
|
2-(Tetrahydrofurfuryloxy)-Tetrahydropyran 98%
| 710-14-5 |
|
1-Bromohexane, 99+%
| 111-25-1 |
|
5-Chloro-2-Methylaniline, 98%
| 95-79-4 |
|
1,2-Difluoro-4-iodobenzene, 99%
| 64248-58-4 |
|
3-Methyl-1-phenyl-1H-pyrazole
| 1128-54-7 |
|
1-Dodecyne, 98%
| 765-03-7 |
|
Fast Red TR Salt
| 3165-93-3 |
|
4-Methylsulphonylbenzoic Acid, 95+%
| 4052-30-6 |
|
Methyl Alpha-Chloroacrylate, 99% (GC)
| 80-63-7 |
|
Lumichrome
| 1086-80-2 |
|
Bisphenol A Diacetate, 99 +%
| 10192-62-8 |
|
3,4,5-Trimethoxyphenylacetic Acid, 99%
| 951-82-6 |
|
|