**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 118-75-2 |Tetrachloro-1,4-Benzoquinone | 99% | 204-274-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI N
Risk Phrases: 36/38 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes and skin. Very toxic to aquatic organisms, may
cause long-term adverse effects in the aquatic environment.Light
sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause digestive tract disturbances. Ingestion of large amounts
may cause CNS depression. Ingestion of large amounts may cause pain,
constipation or diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Prolonged or repeated exposure can cause psychic abnormalities such
as anxiety, depression and excitability.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. If irritation
develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Wash clothing before
reuse. Get medical aid if symptoms occur.
Ingestion:
Never give anything by mouth to an unconscious person. Do NOT induce
vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls
of milk or water. Get medical aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid if cough or other symptoms
appear. Do NOT use mouth-to-mouth resuscitation. If breathing has
ceased apply artificial respiration using oxygen and a suitable
mechanical device such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Runoff from
fire control or dilution water may cause pollution.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use agent most appropriate to extinguish
fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Avoid ingestion and
inhalation. Store protected from light.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 118-75-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: yellow to green
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 290 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.9700g/cm3
Molecular Formula: C6Cl4O2
Molecular Weight: 245.88
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants, slowly decomposed by light.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 118-75-2: DK6825000
LD50/LC50:
CAS# 118-75-2: Inhalation, rat: LC50 = 2485 mg/m3/4H; Oral, rat:
LD50 = 4 gm/kg.
Carcinogenicity:
Tetrachloro-1,4-Benzoquinone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI N
Risk Phrases:
R 36/38 Irritating to eyes and skin.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 37 Wear suitable gloves.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 118-75-2: No information available.
Canada
CAS# 118-75-2 is listed on Canada's DSL List.
CAS# 118-75-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 118-75-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/24/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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Phenylacetylene, 98%
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Polyoxyethylene Non-Ionic Detergents Kit
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Nitric acid-d, 68 wt. % solution in d2o, 99+ atom % d
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4-Vinylbenzyl Alcohol, Tech. 85% (GC), Stabilized with 0.1%
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3-Amino-3-phenyl-1-propanol, 94%
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2-Methyl-1,3-cyclopentanedione, 98%
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|
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| 322-97-4 |
|
1-Hexanesulfonic acid sodium salt
| 2832-45-3 |
|
4-Allylanisole, 98%
| 140-67-0 |
|
Nylon 6
| 25038-54-4 |
|
l(+)-Tartaric acid, diammonium salt, 99%
| 3164-29-2 |
|
Benzyldimethylphenylammonium chloride, monohydrate, 98% (titr.)
| 3204-68-0 |
|
5-Azacytosine
| 931-86-2 |
|
3-Ethylthio-1,2-Propanediol, 97%
| 60763-78-2 |
|
3-Isopropoxypropylamine, 98+%
| 2906-12-9 |
|
Potassium Tetrafluoroborate, C.P.
| 14075-53-7 |
|
Dl-methylsuccinic acid, 99%
| 498-21-5 |
|
Tetrachloro-1,4-Benzoquinone (Pract.)
| 118-75-2 |
|
3-(4-Methoxyphenoxy)Benzaldehyde, 95%
| 62373-80-2 |
|
Ethyl Oxamate, 99%
| 617-36-7 |
|
Terbium Trifluoride, 99.5%
| 13708-63-9 |
|
1-Hexadecanol, 90% (gc)
| 36653-82-4 |
|
1-Naphthol >98%
| 90-15-3 |
|
Iron(iii) acetylacetonate, 99+%
| 14024-18-1 |
|
Ethyl (methylthio)acetate, 95%
| 4455-13-4 |
|
3,4-Dihydroxy-1,5-hexadiene, 98%, mixture of DL and Meso, stab. with
| 1069-23-4 |
|
4-Tert.-butylcyclohexanone, 99%
| 98-53-3 |
|
Montmorillonite ksf
| 1318-93-0 |
|
Ethyl 2-(bromomethyl)acrylate, 97%
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|
2-Chloro-5-Nitrobenzophenone, 99%
| 34052-37-4 |
|
3-Chloro-6-methoxypyridazine, 97%
| 1722-10-7 |
|
Diethyl Cyanomethylphosphonate, 96%
| 2537-48-6 |
|
(Chloromethyl)-Triphenylphosphonium Chloride, Tech., 95%(Titr.)
| 5293-84-5 |
|
3,3-Dimethylacryloyl Chloride, 97%
| 3350-78-5 |
|
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| 22767-49-3 |
|
2,2-Difluorotetrachloroethane, 97%
| 76-11-9 |
|
4-Chloro-3-methylanisole, 99%
| 13334-71-9 |
|
Poly(ethylenimine), 50wt% aq. solution, average m.w. 50-60.000
| 7732-18-5 |
|
Mesitaldehyde, 98%
| 487-68-3 |
|
Poly(caprolactone) triol
| 54735-63-6 |
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D,l-Arabinose, 98%
| 20235-19-2 |
|
|