**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 98-29-3 |4-tert-Butylcatechol | 0.1 | 202-653-9 |
|----------------|--------------------------------------|----------|-----------|
| 2039-87-4 |2-Chlorostyrene | 99 | 218-026-8 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause cardiac disturbances. Ingestion of large amounts
may cause CNS depression.
Inhalation:
Causes respiratory tract irritation. Aspiration may lead to
pulmonary edema. Vapors may cause dizziness or suffocation. May
cause cardiac abnormalities. Inhalation at high concentrations may
cause CNS depression and asphixiation. May cause burning sensation in
the chest.
Chronic:
May cause liver and kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Use water spray to keep
fire-exposed containers cool. Containers may explode in the heat of
a fire. Flammable liquid and vapor. Vapors are heavier than air and
may travel to a source of ignition and flash back. Vapors can spread
along the ground and collect in low or confined areas. Hazardous
polymerization may occur under fire conditions.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Water may be ineffective. Do NOT use
straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames. Keep away
from heat, sparks and flame. Avoid breathing vapor or mist. Pure
vapor will be uninhibited and may polymerize in vents or other
confined spaces.
Storage:
Keep away from sources of ignition. Do not store in direct sunlight.
Store in a tightly closed container. Flammables-area. Keep
refrigerated. (Store below 4C/39F.) Keep away from polymerization
catalysts. Inhibitor level should be checked periodically.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 98-29-3:
CAS# 2039-87-4:
Belgium - TWA: 50 ppm VLE; 287 mg/m3 VLE
Belgium - STEL: 75 ppm VLE; 431 mg/m3 VLE
France - VME: 50 ppm VME; 285 mg/m3 VME
Malaysia: 50 ppm TWA; 283 mg/m3 TWA
Netherlands: 50 ppm MAC; 285 mg/m3 MAC
Spain: 50 ppm VLA-ED; 288 mg/m3 VLA-ED
Spain: 75 ppm VLA-EC; 432 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless - light yellow
Odor: disagreeable odor
pH: Not available.
Vapor Pressure: 0.961 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 189 deg C
Freezing/Melting Point: -63.15 deg C
Autoignition Temperature: Not available.
Flash Point: 58 deg C ( 136.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 1.0800g/cm3
Molecular Formula: C8H7Cl
Molecular Weight: 138.60
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. However, it may undergo explosive polymerization if
uninhibited.
Conditions to Avoid:
Light, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, metal salts, polymerizing initiators.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 98-29-3: UX1400000
CAS# 2039-87-4: WL4160000
LD50/LC50:
CAS# 98-29-3: Draize test, rabbit, skin: 750 ug/24H Severe; Oral,
rat: LD50 = 2820 mg/kg; Skin, rabbit: LD50 = 630 uL/kg.
CAS# 2039-87-4: Oral, rabbit: LD50 = 4230 uL/kg; Oral, rat: LD50 =
3810 uL/kg.
Carcinogenicity:
4-tert-Butylcatechol -
Not listed by ACGIH, IARC, or NTP.
2-Chlorostyrene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 98-29-3: No information available.
CAS# 2039-87-4: No information available.
Canada
CAS# 98-29-3 is listed on Canada's DSL List.
CAS# 98-29-3 is listed on Canada's Ingredient Disclosure List.
CAS# 2039-87-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 98-29-3 is listed on the TSCA inventory.
CAS# 2039-87-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #7 Date: 5/29/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Aminobenzimidazole-2-sulfonic acid, 99%
| 120341-04-0 |
|
Cytochalasin E
| 36011-19-5 |
|
n-Methyl-2-phenylacetamide
| 6830-82-6 |
|
D(+)-cellobiose, 98%
| 528-50-7 |
|
Ammonium tetrachloropalladate(ii)
| 13820-40-1 |
|
Phenylacetylene, 98%
| 536-74-3 |
|
Polyoxyethylene Non-Ionic Detergents Kit
| 0-01-1 |
|
Nitric acid-d, 68 wt. % solution in d2o, 99+ atom % d
| 13587-52-5 |
|
4-Vinylbenzyl Alcohol, Tech. 85% (GC), Stabilized with 0.1%
| 1074-61-9 |
|
3-Amino-3-phenyl-1-propanol, 94%
| 14593-04-5 |
|
2-Methyl-1,3-cyclopentanedione, 98%
| 765-69-5 |
|
5-Nitroso-2,4,6-triaminopyrimidine
| 1006-23-1 |
|
2-Chlorostyrene, 99%, stabilized with 0.1% tert-butylcatechol
| 98-29-3 |
|
1-Heptanesulfonic Acid Sodium Salt
| 22767-50-6 |
|
(1S,3S)-3-Acetyl-2,2-dimethylcyclobutane acetonitrile, 98%, mixt.
| 28353-00-6 |
|
7-(Trifluoromethyl)-4-quinolinol, 97%
| 322-97-4 |
|
1-Hexanesulfonic acid sodium salt
| 2832-45-3 |
|
4-Allylanisole, 98%
| 140-67-0 |
|
Nylon 6
| 25038-54-4 |
|
l(+)-Tartaric acid, diammonium salt, 99%
| 3164-29-2 |
|
Benzyldimethylphenylammonium chloride, monohydrate, 98% (titr.)
| 3204-68-0 |
|
5-Azacytosine
| 931-86-2 |
|
3-Ethylthio-1,2-Propanediol, 97%
| 60763-78-2 |
|
3-Isopropoxypropylamine, 98+%
| 2906-12-9 |
|
Potassium Tetrafluoroborate, C.P.
| 14075-53-7 |
|
Dl-methylsuccinic acid, 99%
| 498-21-5 |
|
Tetrachloro-1,4-Benzoquinone (Pract.)
| 118-75-2 |
|
3-(4-Methoxyphenoxy)Benzaldehyde, 95%
| 62373-80-2 |
|
Ethyl Oxamate, 99%
| 617-36-7 |
|
Terbium Trifluoride, 99.5%
| 13708-63-9 |
|
1-Hexadecanol, 90% (gc)
| 36653-82-4 |
|
1-Naphthol >98%
| 90-15-3 |
|
Iron(iii) acetylacetonate, 99+%
| 14024-18-1 |
|
Ethyl (methylthio)acetate, 95%
| 4455-13-4 |
|
3,4-Dihydroxy-1,5-hexadiene, 98%, mixture of DL and Meso, stab. with
| 1069-23-4 |
|
4-Tert.-butylcyclohexanone, 99%
| 98-53-3 |
|
Montmorillonite ksf
| 1318-93-0 |
|
Ethyl 2-(bromomethyl)acrylate, 97%
| 17435-72-2 |
|
2-Chloro-5-Nitrobenzophenone, 99%
| 34052-37-4 |
|
3-Chloro-6-methoxypyridazine, 97%
| 1722-10-7 |
|
Diethyl Cyanomethylphosphonate, 96%
| 2537-48-6 |
|
(Chloromethyl)-Triphenylphosphonium Chloride, Tech., 95%(Titr.)
| 5293-84-5 |
|
3,3-Dimethylacryloyl Chloride, 97%
| 3350-78-5 |
|
1-Pentanesulfonic Acid Sodium Salt
| 22767-49-3 |
|
2,2-Difluorotetrachloroethane, 97%
| 76-11-9 |
|
4-Chloro-3-methylanisole, 99%
| 13334-71-9 |
|
Poly(ethylenimine), 50wt% aq. solution, average m.w. 50-60.000
| 7732-18-5 |
|
Mesitaldehyde, 98%
| 487-68-3 |
|
Poly(caprolactone) triol
| 54735-63-6 |
|
D,l-Arabinose, 98%
| 20235-19-2 |
|
|