**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 140-67-0 |4-Allylanisole | 98.0 | 205-427-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May cause dermatitis. May cause cyanosis of
the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Aspiration may lead to
pulmonary edema. Can produce delayed pulmonary edema. Inhalation at
high concentrations may cause CNS depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Wash clothing before reuse. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 140-67-0:
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Follow the OSHA
respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or
European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or
other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: anise odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 215.0 - 216.0 deg C @ 760.00m
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 81 deg C ( 177.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: .9650g/cm3
Molecular Formula: H2C=CHCH2C6H4OCH3
Molecular Weight: 148.20
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 140-67-0: BZ8225000
LD50/LC50:
CAS# 140-67-0: Draize test, rabbit, skin: 500 mg/24H Moderate; Oral,
mouse: LD50 = 1250 mg/kg; Oral, rat: LD50 = 1230 mg/kg; Skin, rabbit:
LD50 = >5 gm/kg.
Carcinogenicity:
4-Allylanisole -
California: carcinogen, initial date 10/29/99
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 0.36-0.46 mg/L; 5,15,30
minutes; Microtox test, 15 degrees C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 140-67-0: No information available.
Canada
CAS# 140-67-0 is listed on Canada's DSL List.
CAS# 140-67-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 140-67-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/23/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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|
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| 25038-54-4 |
|
l(+)-Tartaric acid, diammonium salt, 99%
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Benzyldimethylphenylammonium chloride, monohydrate, 98% (titr.)
| 3204-68-0 |
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5-Azacytosine
| 931-86-2 |
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3-Ethylthio-1,2-Propanediol, 97%
| 60763-78-2 |
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3-Isopropoxypropylamine, 98+%
| 2906-12-9 |
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Potassium Tetrafluoroborate, C.P.
| 14075-53-7 |
|
Dl-methylsuccinic acid, 99%
| 498-21-5 |
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Tetrachloro-1,4-Benzoquinone (Pract.)
| 118-75-2 |
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3-(4-Methoxyphenoxy)Benzaldehyde, 95%
| 62373-80-2 |
|
Ethyl Oxamate, 99%
| 617-36-7 |
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Terbium Trifluoride, 99.5%
| 13708-63-9 |
|
1-Hexadecanol, 90% (gc)
| 36653-82-4 |
|
1-Naphthol >98%
| 90-15-3 |
|
Iron(iii) acetylacetonate, 99+%
| 14024-18-1 |
|
Ethyl (methylthio)acetate, 95%
| 4455-13-4 |
|
3,4-Dihydroxy-1,5-hexadiene, 98%, mixture of DL and Meso, stab. with
| 1069-23-4 |
|
4-Tert.-butylcyclohexanone, 99%
| 98-53-3 |
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Montmorillonite ksf
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2-Chloro-5-Nitrobenzophenone, 99%
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3-Chloro-6-methoxypyridazine, 97%
| 1722-10-7 |
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| 2537-48-6 |
|
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| 5293-84-5 |
|
3,3-Dimethylacryloyl Chloride, 97%
| 3350-78-5 |
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| 22767-49-3 |
|
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| 7732-18-5 |
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| 487-68-3 |
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| 54735-63-6 |
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| 20235-19-2 |
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