**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 12125-02-9 |Ammonium chloride | >99.0 | 235-186-4
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. May cause systemic
toxicity with acidosis. May be harmful if swallowed.
Inhalation:
If heated, dust or fume may cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Substance is
noncombustible. Containers may explode in the heat of a fire. May
polymerize explosively when involved in a fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Substance is noncombustible; use agent most
appropriate to extinguish surrounding fire. For large fires, use
water spray, fog or alcohol-resistant foam. Cool containers with
flooding quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Store below 40C.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear impervious gloves.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: colorless or white
Odor: odorless
pH: 5.0 (10% sol at 25C)
Vapor Pressure: 1 mm Hg @ 160.4C
Viscosity: Not available.
Boiling Point: 520 deg C(sublimes)
Freezing/Melting Point: 328 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 39.6% at 176F.
Specific Gravity/Density: 1.53 (Water=1)
Molecular Formula: NH4Cl
Molecular Weight: 53.4877
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Boron trifluoride, iodine heptafluoride, potassium chlorates, acids,
alkalies, silver salts, lead salts.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, ammonia and hydrochloric acid
fumes.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 12125-02-9: BP4550000
LD50/LC50:
CAS# 12125-02-9: Draize test, rabbit, eye: 500 mg/24H Mild; Draize
test, rabbit, eye: 100 mg Severe; Oral, mouse: LD50 = 1300 mg/kg;
Oral, rat: LD50 = 1650 mg/kg.
Carcinogenicity:
Ammonium chloride -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: LC50 = 109.0 mg/L; 48 Hr.; Static conditionsSunfish (fresh
water) TLm=6 ppm/96H
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36 Irritating to eyes.
Safety Phrases:
S 22 Do not breathe dust.
WGK (Water Danger/Protection)
CAS# 12125-02-9: 1
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 12125-02-9 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 12125-02-9: OEL-ARAB Republic of Egypt:TWA 10 mg/m3 (fume)
OEL-AUSTRALIA:TWA 10 mg/m3;STEL 20 mg/m3 (fume)
OEL-BELGIUM:TWA 10 mg/m3;STEL 20 mg/m3 (fume)
OEL-DENMARK:TWA 10 mg/m3 (fume)
OEL-FRANCE:TWA 10 mg/m3 (fume)
OEL-THE NETHERLANDS:TWA 10 mg/m3 (fume)
OEL-RUSSIA:STEL 10 mg/m3 (fume)
OEL-SWITZERLAND:TWA 6 mg/m3 (fume)
OEL-UNITED KINGDOM:TWA 10 mg/m3;STEL 20 mg/m3 (fume)
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 12125-02-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/15/1999 Revision #3 Date: 12/03/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
alpha-Bromo-3-iodo-4-nitrotoluene, 97%
| 214279-41-1 |
|
Aluminum, rods, 99.999%
| 7429-90-5 |
|
Triphenylarsine, 97%
| 603-32-7 |
|
2-Nitrophenylacetylene, 97%
| 16433-96-8 |
|
Ethyl 3,5-Bis(Trifluoromethyl)Benzoate, 97%
| 96617-71-9 |
|
Pentafluorophenoxyacetic Acid, 97%
| 14892-14-9 |
|
Acetonitrile
| 75-05-8 |
|
Pentafluorophenoxyacetyl Chloride, 97%
| 55502-53-9 |
|
Methyl 4-Amino-3-Chlorobenzoate, 97%
| 84228-44-4 |
|
Acetic acid, ammonium salt, anhydrous, p.a.
| 631-61-8 |
|
1-Iodo-2-methylpropane, 97%, stabilized with copper
| 513-38-2 |
|
4-Chloro-2-Methyl-6-Nitroaniline, 97%
| 62790-50-5 |
|
Ammonium hydrogen difluoride, technical grade, crystalline
| 1341-49-7 |
|
Ammonium Bromide, P.A.
| 12124-97-9 |
|
Ammonium Carbonate, P.A.
| 506-87-6 |
|
3,3'-Diethyloxatricarbocyanine Iodide, Laser Grade, 99% (UV-Vis)
| 15185-43-0 |
|
(3R-cis)-7a-Methyl-3-phenyltetrahydropyrrolo-[2,1-b]oxazol-5(6H)-one
| 137869-70-6 |
|
(3R-cis)-3,7a-Diphenyltetrahydropyrrolo-[2,1-b]oxazol-5(6H)-one
| 132959-39-8 |
|
Ammonium Chloride, P.A.
| 12125-02-9 |
|
(3S-Cis)-(-)-3-Phenyltetrahydropyrrolo-[2,1-B]Oxazol-5(6H)-One
| 122383-34-0 |
|
(3R-Cis)-(-)-3-Phenyltetrahydropyrrolo-[2,1-B]Oxazol-5(6H)-One, 97%
| 133007-27-9 |
|
Ammonium dichromate, 99%
| 7789-09-5 |
|
Acetophenone
| 98-86-2 |
|
Ammonium Fluoride, Reagent ACS
| 12125-01-8 |
|
Ammonium Formate, 99% (titr.)
| 540-69-2 |
|
Copper (II) Ethyl Acetoacetate, 99% (Titr.)
| 14284-06-1 |
|
Ethyl Acetate, ECD Tested for Pesticide Analysis
| 141-78-6 |
|
Methyl alcohol, ECD tested for pesticide analysis
| 67-56-1 |
|
n-Pentane, ECD tested for pesticide analysis
| 109-66-0 |
|
Water
| 7732-18-5 |
|
N-Hexane, ECD Tested for Pesticide Analysis, Residue <0.0003%
| 110-54-3 |
|
n-Heptane, ECD tested for pesticide analysis, sulfur low, 99.4+%
| 108-87-2 |
|
epsilon-Caprolactone monomer
| 502-44-3 |
|
Acetone, ECD Tested Halocarbons Free Grade
| 67-64-1 |
|
Petroleum Ether 40-60, ECD Tested Halocarbons Free Grade
| 8032-32-4 |
|
Petroleum Ether 40-60, ECD Tested Lindane/ DDT < 5 ng/l, Residue
| 8032-32-4 |
|
N-Acetyl-DL-Penicillamine, 98%
| 59-53-0 |
|
2-Bromophenylhydrazine Hydrochloride, 95%
| 50709-33-6 |
|
Acetone, Tested for Trace Analysis of Polyaromatic Hydrocarbons
| 67-64-1 |
|
Dichloromethane, Tested for Trace Analysis of Polyaromatic
| 75-09-2 |
|
n-Heptane, tested for trace analysis of polyaromatic hydrocarbons
| 108-87-2 |
|
Ammonium hydroxide water solution, >14N NH4OH (>25% as ammonia, NH3)
| 1336-21-6 |
|
N-Hexane, Tested for Trace Analysis of Polyaromatic Hydrocarbons
| 110-54-3 |
|
Petroleum Ether 40-60, Tested for Trace Analysis of Polyaromatic
| 8032-32-4 |
|
Ammonium Persulfate, Reagent ACS, (Crystals), 98+% (Titr.)
| 7727-54-0 |
|
Ammonium Dihydrogen Phosphate, P.A.
| 7722-76-1 |
|
Acetone, Extra Dry, Water <50 ppm
| 67-64-1 |
|
sec-Butyllithium, 1.3m solution in cyclohexane/hexane (92/8)
| 598-30-1 |
|
Chloroform, Extra Dry, Water <50 ppm
| 67-66-3 |
|
Ammonium Phosphate, Dibasic, Reagent ACS (Powder)
| 7783-28-0 |
|
|