**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7727-54-0 |Ammonium persulfate | 98.0 | 231-786-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN O
Risk Phrases: 20/22 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Contact with combustible
material may cause fire.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Inhalation may be fatal as a
result of spasm, inflammation, edema of the larynx and bronchi,
chemical pneumonitis and pulmonary edema.
Chronic:
Repeated or prolonged exposure may cause allergic reactions in
sensitive individuals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid if cough or other symptoms
appear. Do NOT use mouth-to-mouth resuscitation. If breathing has
ceased apply artificial respiration using oxygen and a suitable
mechanical device such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Oxidizer. Greatly increases the burning rate of combustible
materials. This material in sufficient quantity and reduced particle
size is capable of creating a dust explosion. May accelerate burning
if involved in a fire. Containers may explode when heated.
Extinguishing Media:
Cool containers with flooding quantities of water until well after
fire is out. For small fires, do NOT use dry chemicals, carbon
dioxide, halon or foams. USE WATER ONLY. For large fires, flood
fire area with water from a distance.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid contact with
clothing and other combustible materials. Avoid ingestion and
inhalation. Wash clothing before reuse.
Storage:
Do not store near combustible materials. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Keep away from metals. Keep away from
reducing agents.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Decomposes.
Freezing/Melting Point: 120 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 120 deg C
Solubility in water: 80g/100ml(25 C) (may decompose)
Specific Gravity/Density: 1.982 (water=1)
Molecular Formula: (NH4)2S2O8
Molecular Weight: 228.1846
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Substance is shock sensitive and thermally unstable. Decomposes when
heated. May decompose on exposure to moist air or water.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, metals,
combustible materials, organic materials, reducing agents.
Incompatibilities with Other Materials:
Reducing agents, powdered aluminum, iron, sodium peroxide.
Hazardous Decomposition Products:
Nitrogen oxides, oxides of sulfur, ammonia and/or derivatives,
nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7727-54-0: SE0350000
LD50/LC50:
CAS# 7727-54-0: Oral, rat: LD50 = 689 mg/kg.
Carcinogenicity:
Ammonium persulfate -
Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AMMONIUM PERSULPHATE
Hazard Class: 5.1
UN Number: 1444
Packing Group: III
IMO
Shipping Name: AMMONIUM PERSULPHATE
Hazard Class: 5.1
UN Number: 1444
Packing Group: III
RID/ADR
Shipping Name: AMMONIUM PERSULPHATE
Hazard Class: 5.1
UN Number: 1444
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN O
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 22 Do not breathe dust.
S 24 Avoid contact with skin.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
WGK (Water Danger/Protection)
CAS# 7727-54-0: 1
United Kingdom Occupational Exposure Limits
CAS# 7727-54-0: OES-United Kingdom, TWA 1 mg/m3 TWA (measured as
S2O8)
United Kingdom Maximum Exposure Limits
Canada
CAS# 7727-54-0 is listed on Canada's DSL List.
CAS# 7727-54-0 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7727-54-0: OEL-DENMARK:TWA 2 mg/m3
OEL-UNITED KINGDOM:TWA 1 mg/m3
US FEDERAL
TSCA
CAS# 7727-54-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/20/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
alpha-Bromo-3-iodo-4-nitrotoluene, 97%
| 214279-41-1 |
|
Aluminum, rods, 99.999%
| 7429-90-5 |
|
Triphenylarsine, 97%
| 603-32-7 |
|
2-Nitrophenylacetylene, 97%
| 16433-96-8 |
|
Ethyl 3,5-Bis(Trifluoromethyl)Benzoate, 97%
| 96617-71-9 |
|
Pentafluorophenoxyacetic Acid, 97%
| 14892-14-9 |
|
Acetonitrile
| 75-05-8 |
|
Pentafluorophenoxyacetyl Chloride, 97%
| 55502-53-9 |
|
Methyl 4-Amino-3-Chlorobenzoate, 97%
| 84228-44-4 |
|
Acetic acid, ammonium salt, anhydrous, p.a.
| 631-61-8 |
|
1-Iodo-2-methylpropane, 97%, stabilized with copper
| 513-38-2 |
|
4-Chloro-2-Methyl-6-Nitroaniline, 97%
| 62790-50-5 |
|
Ammonium hydrogen difluoride, technical grade, crystalline
| 1341-49-7 |
|
Ammonium Bromide, P.A.
| 12124-97-9 |
|
Ammonium Carbonate, P.A.
| 506-87-6 |
|
3,3'-Diethyloxatricarbocyanine Iodide, Laser Grade, 99% (UV-Vis)
| 15185-43-0 |
|
(3R-cis)-7a-Methyl-3-phenyltetrahydropyrrolo-[2,1-b]oxazol-5(6H)-one
| 137869-70-6 |
|
(3R-cis)-3,7a-Diphenyltetrahydropyrrolo-[2,1-b]oxazol-5(6H)-one
| 132959-39-8 |
|
Ammonium Chloride, P.A.
| 12125-02-9 |
|
(3S-Cis)-(-)-3-Phenyltetrahydropyrrolo-[2,1-B]Oxazol-5(6H)-One
| 122383-34-0 |
|
(3R-Cis)-(-)-3-Phenyltetrahydropyrrolo-[2,1-B]Oxazol-5(6H)-One, 97%
| 133007-27-9 |
|
Ammonium dichromate, 99%
| 7789-09-5 |
|
Acetophenone
| 98-86-2 |
|
Ammonium Fluoride, Reagent ACS
| 12125-01-8 |
|
Ammonium Formate, 99% (titr.)
| 540-69-2 |
|
Copper (II) Ethyl Acetoacetate, 99% (Titr.)
| 14284-06-1 |
|
Ethyl Acetate, ECD Tested for Pesticide Analysis
| 141-78-6 |
|
Methyl alcohol, ECD tested for pesticide analysis
| 67-56-1 |
|
n-Pentane, ECD tested for pesticide analysis
| 109-66-0 |
|
Water
| 7732-18-5 |
|
N-Hexane, ECD Tested for Pesticide Analysis, Residue <0.0003%
| 110-54-3 |
|
n-Heptane, ECD tested for pesticide analysis, sulfur low, 99.4+%
| 108-87-2 |
|
epsilon-Caprolactone monomer
| 502-44-3 |
|
Acetone, ECD Tested Halocarbons Free Grade
| 67-64-1 |
|
Petroleum Ether 40-60, ECD Tested Halocarbons Free Grade
| 8032-32-4 |
|
Petroleum Ether 40-60, ECD Tested Lindane/ DDT < 5 ng/l, Residue
| 8032-32-4 |
|
N-Acetyl-DL-Penicillamine, 98%
| 59-53-0 |
|
2-Bromophenylhydrazine Hydrochloride, 95%
| 50709-33-6 |
|
Acetone, Tested for Trace Analysis of Polyaromatic Hydrocarbons
| 67-64-1 |
|
Dichloromethane, Tested for Trace Analysis of Polyaromatic
| 75-09-2 |
|
n-Heptane, tested for trace analysis of polyaromatic hydrocarbons
| 108-87-2 |
|
Ammonium hydroxide water solution, >14N NH4OH (>25% as ammonia, NH3)
| 1336-21-6 |
|
N-Hexane, Tested for Trace Analysis of Polyaromatic Hydrocarbons
| 110-54-3 |
|
Petroleum Ether 40-60, Tested for Trace Analysis of Polyaromatic
| 8032-32-4 |
|
Ammonium Persulfate, Reagent ACS, (Crystals), 98+% (Titr.)
| 7727-54-0 |
|
Ammonium Dihydrogen Phosphate, P.A.
| 7722-76-1 |
|
Acetone, Extra Dry, Water <50 ppm
| 67-64-1 |
|
sec-Butyllithium, 1.3m solution in cyclohexane/hexane (92/8)
| 598-30-1 |
|
Chloroform, Extra Dry, Water <50 ppm
| 67-66-3 |
|
Ammonium Phosphate, Dibasic, Reagent ACS (Powder)
| 7783-28-0 |
|
|