**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 8032-32-4 |Petroleum ether 40-60 | ca 100 | 232-453-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Prolonged and/or repeated contact may cause irritation and/or
dermatitis. Exposure may cause irritation characterized by redness,
dryness, and inflammation.
Ingestion:
Harmful if swallowed. Aspiration hazard. Causes gastrointestinal
irritation with nausea, vomiting and diarrhea. May cause central
nervous system depression, characterized by excitement, followed by
headache, dizziness, drowsiness, and nausea. Advanced stages may
cause collapse, unconsciousness, coma and possible death due to
respiratory failure. Aspiration of material into the lungs may cause
chemical pneumonitis, which may be fatal.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. High vapor concentrations may cause drowsiness. May cause
hemorrhage of vital organs and coma.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Extremely
flammable liquid and vapor. Vapor may cause flash fire. Vapors may
be heavier than air. They can spread along the ground and collect in
low or confined areas.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. Water may be ineffective.
This material is lighter than water and insoluble in water. The fire
could easily be spread by the use of water in an area where the
water cannot be contained.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Remove all sources of ignition. Use
a spark-proof tool. Provide ventilation. A vapor suppressing foam
may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Do not get in
eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep away from
heat, sparks and flame. Do not ingest or inhale. Prevent build up of
vapors to explosive concentration. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 8032-32-4:
Belgium - TWA: 300 ppm VLE; 1390 mg/m3 VLE
Malaysia: 300 ppm TWA; 1370 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: APHA: 5 max
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 40 - 60 deg C @ 760
Freezing/Melting Point: -40 deg C
Autoignition Temperature: 250 deg C ( 482.00 deg F)
Flash Point: -30 deg C ( -22.00 deg F)
Explosion Limits, lower: .60 vol %
Explosion Limits, upper: 8.00 vol %
Decomposition Temperature:
Solubility in water: Not available.
Specific Gravity/Density: .6530g/cm3
Molecular Formula:
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxygen and strong oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Not available.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 8032-32-4: OI6180000
LD50/LC50:
CAS# 8032-32-4: Inhalation, rat: LC50 = 3400 ppm/4H.
Carcinogenicity:
Petroleum ether 40-60 -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Not available low potential to affect aquatic organisms, secondary
waste treatment microorganisms and the germination of some plants.
It has a moderate potential to affect the germination and growth of
some plants.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 8032-32-4: 1
Canada
CAS# 8032-32-4 is listed on Canada's DSL List.
CAS# 8032-32-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 8032-32-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/14/1999 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
alpha-Bromo-3-iodo-4-nitrotoluene, 97%
| 214279-41-1 |
|
Aluminum, rods, 99.999%
| 7429-90-5 |
|
Triphenylarsine, 97%
| 603-32-7 |
|
2-Nitrophenylacetylene, 97%
| 16433-96-8 |
|
Ethyl 3,5-Bis(Trifluoromethyl)Benzoate, 97%
| 96617-71-9 |
|
Pentafluorophenoxyacetic Acid, 97%
| 14892-14-9 |
|
Acetonitrile
| 75-05-8 |
|
Pentafluorophenoxyacetyl Chloride, 97%
| 55502-53-9 |
|
Methyl 4-Amino-3-Chlorobenzoate, 97%
| 84228-44-4 |
|
Acetic acid, ammonium salt, anhydrous, p.a.
| 631-61-8 |
|
1-Iodo-2-methylpropane, 97%, stabilized with copper
| 513-38-2 |
|
4-Chloro-2-Methyl-6-Nitroaniline, 97%
| 62790-50-5 |
|
Ammonium hydrogen difluoride, technical grade, crystalline
| 1341-49-7 |
|
Ammonium Bromide, P.A.
| 12124-97-9 |
|
Ammonium Carbonate, P.A.
| 506-87-6 |
|
3,3'-Diethyloxatricarbocyanine Iodide, Laser Grade, 99% (UV-Vis)
| 15185-43-0 |
|
(3R-cis)-7a-Methyl-3-phenyltetrahydropyrrolo-[2,1-b]oxazol-5(6H)-one
| 137869-70-6 |
|
(3R-cis)-3,7a-Diphenyltetrahydropyrrolo-[2,1-b]oxazol-5(6H)-one
| 132959-39-8 |
|
Ammonium Chloride, P.A.
| 12125-02-9 |
|
(3S-Cis)-(-)-3-Phenyltetrahydropyrrolo-[2,1-B]Oxazol-5(6H)-One
| 122383-34-0 |
|
(3R-Cis)-(-)-3-Phenyltetrahydropyrrolo-[2,1-B]Oxazol-5(6H)-One, 97%
| 133007-27-9 |
|
Ammonium dichromate, 99%
| 7789-09-5 |
|
Acetophenone
| 98-86-2 |
|
Ammonium Fluoride, Reagent ACS
| 12125-01-8 |
|
Ammonium Formate, 99% (titr.)
| 540-69-2 |
|
Copper (II) Ethyl Acetoacetate, 99% (Titr.)
| 14284-06-1 |
|
Ethyl Acetate, ECD Tested for Pesticide Analysis
| 141-78-6 |
|
Methyl alcohol, ECD tested for pesticide analysis
| 67-56-1 |
|
n-Pentane, ECD tested for pesticide analysis
| 109-66-0 |
|
Water
| 7732-18-5 |
|
N-Hexane, ECD Tested for Pesticide Analysis, Residue <0.0003%
| 110-54-3 |
|
n-Heptane, ECD tested for pesticide analysis, sulfur low, 99.4+%
| 108-87-2 |
|
epsilon-Caprolactone monomer
| 502-44-3 |
|
Acetone, ECD Tested Halocarbons Free Grade
| 67-64-1 |
|
Petroleum Ether 40-60, ECD Tested Halocarbons Free Grade
| 8032-32-4 |
|
Petroleum Ether 40-60, ECD Tested Lindane/ DDT < 5 ng/l, Residue
| 8032-32-4 |
|
N-Acetyl-DL-Penicillamine, 98%
| 59-53-0 |
|
2-Bromophenylhydrazine Hydrochloride, 95%
| 50709-33-6 |
|
Acetone, Tested for Trace Analysis of Polyaromatic Hydrocarbons
| 67-64-1 |
|
Dichloromethane, Tested for Trace Analysis of Polyaromatic
| 75-09-2 |
|
n-Heptane, tested for trace analysis of polyaromatic hydrocarbons
| 108-87-2 |
|
Ammonium hydroxide water solution, >14N NH4OH (>25% as ammonia, NH3)
| 1336-21-6 |
|
N-Hexane, Tested for Trace Analysis of Polyaromatic Hydrocarbons
| 110-54-3 |
|
Petroleum Ether 40-60, Tested for Trace Analysis of Polyaromatic
| 8032-32-4 |
|
Ammonium Persulfate, Reagent ACS, (Crystals), 98+% (Titr.)
| 7727-54-0 |
|
Ammonium Dihydrogen Phosphate, P.A.
| 7722-76-1 |
|
Acetone, Extra Dry, Water <50 ppm
| 67-64-1 |
|
sec-Butyllithium, 1.3m solution in cyclohexane/hexane (92/8)
| 598-30-1 |
|
Chloroform, Extra Dry, Water <50 ppm
| 67-66-3 |
|
Ammonium Phosphate, Dibasic, Reagent ACS (Powder)
| 7783-28-0 |
|
|