**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7664-41-7 |Ammonia | >25-30 | 231-635-3 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C N
Risk Phrases: 34 50
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns. Very toxic to aquatic organisms.
Potential Health Effects
Eye:
Contact with liquid or vapor causes severe burns and possible
irreversible eye damage. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes severe skin irritation. Causes skin burns. May cause deep,
penetrating ulcers of the skin. Contact with the skin may cause
staining, inflammation, and thickening of the skin.
Ingestion:
Harmful if swallowed. May cause severe and permanent damage to the
digestive tract. Causes gastrointestinal tract burns. Causes throat
constriction, vomiting, convulsions, and shock.
Inhalation:
Effects may be delayed. Causes severe irritation of upper
respiratory tract with coughing, burns, breathing difficulty, and
possible coma.
Chronic:
Prolonged inhalation may cause respiratory tract inflammation and
lung damage. Prolonged or repeated exposure may cause corneal damage
and the development of cataracts and glaucoma.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
After inhalation exposure, observe for 24 to 72 hours as pulmonary
edema may be delayed.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Contact with metals may
evolve flammable hydrogen gas. Containers may explode when heated.
Approach fire from upwind to avoid hazardous vapors and toxic
decomposition products. Ammonium hydroxide itself is
non-combustible. However concentrated ammonia solutions may give off
ammonia vapours. Ammonia gas is generally not considered a serious
fire or explosion hazard because ammonia/air mixtures are difficult
to ignite. A relatively high concentration of ammonia gas must be
present in order for ignition to occur. However, a large and intense
energy source may cause ignition and/or explosion in a confined
space.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Neutralize spill with a weak acid
such as vinegar or acetic acid. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Approach spill from upwind.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Do not get in eyes, on skin, or on clothing. Keep
container tightly closed. Discard contaminated shoes. Do not breathe
vapor. Use only with adequate ventilation.
Storage:
Do not store in direct sunlight. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Corrosives area. Isolate from oxidizing
materials and acids. Walls, floors, shelving, fittings, lighting and
ventilation systems in storage area should be made from carbon steel
or stainless steel which do not react with ammonium hydroxide.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 1336-21-6:
CAS# 7664-41-7:
United Kingdom, WEL - TWA: 25 ppm TWA (anhydrous); 18 mg/m3 TWA
(anhydrous)
United Kingdom, WEL - STEL: 35 ppm STEL (anhydrous); 25 mg/m3 STE
(anhydrous)
United States OSHA: 50 ppm TWA; 35 mg/m3 TWA
Belgium - TWA: 20 ppm VLE; 14 mg/m3 VLE
Belgium - STEL: 50 ppm VLE; 36 mg/m3 VLE
France - VME: 25 ppm VME; 18 mg/m3 VME
France - VLE: 50 ppm VLE; 36 mg/m3 VLE
Germany: 50 ppm TWA; 35 mg/m3 TWA
Japan: 25 ppm OEL; 17 mg/m3 OEL
Malaysia: 25 ppm TWA; 17 mg/m3 TWA
Netherlands: 50 ppm STEL; 36 mg/m3 STEL
Netherlands: 20 ppm MAC; 14 mg/m3 MAC
Russia: 20 mg/m3 TWA
Spain: 20 ppm VLA-ED; 14 mg/m3 VLA-ED
Spain: 50 ppm VLA-EC; 36 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: strong odor - ammonia-like
pH: 13.6
Vapor Pressure: 557 mm Hg @ 21 deg C
Viscosity: Not available.
Boiling Point: 27 deg C
Freezing/Melting Point: -69 deg C
Autoignition Temperature: 651 deg C ( 1,203.80 deg F)
Flash Point: Not available.
Explosion Limits, lower: 15%
Explosion Limits, upper: 28%
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: 0.89
Molecular Formula: NH4OH
Molecular Weight: 35.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Ammonium hydroxide
is actually a solution of ammonia in water. Therefore the flammable
properties of ammonia apply.
Conditions to Avoid:
High temperatures, confined spaces, Ammonia solutions are corrosive
to copper, zinc, aluminum and their alloys..
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, acrolein, halogens, mercury,
hypochlorite, silver nitrate, acrylic acid, dimethyl sulfate, silver
oxide.
Hazardous Decomposition Products:
Nitrogen oxides (NOx) and ammonia (NH3).
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1336-21-6: BQ9625000
CAS# 7664-41-7: BO0875000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 1336-21-6: Draize test, rabbit, eye: 250 ug Severe; Draize
test, rabbit, eye: 44 ug Severe; Oral, rat: LD50 = 350 mg/kg.
CAS# 7664-41-7: Inhalation, mouse: LC50 = 4230 ppm/1H; Inhalation,
mouse: LC50 = 4600 mg/m3/2H; Inhalation, rabbit: LC50 = 7 gm/m3/1H;
Inhalation, rat: LC50 = 2000 ppm/4H; Inhalation, rat: LC50 = 18600
mg/m3/5M; Inhalation, rat: LC50 = 7040 mg/m3/30M; Skin, rat: LD50 =
112000 mg/m3/15M; Skin, rat: LD50 = 71900 mg/m3/30M; Skin, rat: LD50
= 4840 mg/m3/60M.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Ammonium hydroxide -
Not listed by ACGIH, IARC, or NTP.
Ammonia -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50 = 0.008 mg/L; 24 Hr.; UnspecifiedFish:
Fathead Minnow: LC50 = 8.2 mg/L; 96 Hr.; UnspecifiedFish:
Bluegill/Sunfish: LC50 = 0.024-0.093 mg/L; 48 Hr.; UnspecifiedWater
flea Daphnia: EC50 =0.66 mg/L; 48 Hr.; 22 degrees C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AMMONIA SOLUTION
Hazard Class: 8
UN Number: 2672
Packing Group: III
IMO
Shipping Name: AMMONIA SOLUTION
Hazard Class: 8
UN Number: 2672
Packing Group: III
RID/ADR
Shipping Name: AMMONIA SOLUTION
Hazard Class: 8
UN Number: 2672
Packing group: III
USA RQ: CAS# 1336-21-6: 1000 lb final RQ; 454 kg final RQ
USA RQ: CAS# 7664-41-7: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C N
Risk Phrases:
R 34 Causes burns.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 1336-21-6: 2
CAS# 7664-41-7: 2
CAS# 7732-18-5: No information available.
Canada
CAS# 1336-21-6 is listed on Canada's DSL List.
CAS# 7664-41-7 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 1336-21-6 is listed on Canada's Ingredient Disclosure List.
CAS# 7664-41-7 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1336-21-6 is listed on the TSCA inventory.
CAS# 7664-41-7 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 6/22/1999 Revision #12 Date: 7/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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