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MSDS 
:
 Sodium hexanitrocobaltate(III)
CAS 
:
 13600-98-1
SYNONYMS 
:
 Cobaltate(3-), hexakis(nitrito-N)-, trisodium (OC-6-11)-; Sodium     cobaltinitrite; Sodium nitrocobaltate(III); Trisodium     hexanitritocobaltate; Trisodium hexanitritocobaltate(3-); Trisodium     hexanitrocobaltate; Trisodium hexanitrocobaltate(3-); Cobaltate(3-),     hexanitro-, trisodium.
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13600-98-1 |Sodium cobaltinitrate | >99 | 237-077-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN O
Risk Phrases: 42/43 8

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
May cause sensitization by inhalation and skin contact. Contact with
combustible material may cause fire.

Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material.
Ingestion:
Methemoglobinemia is characterized by dizziness, drowsiness,
headache, shortness of breath, cyanosis (bluish discoloration of skin
due to deficient oxygenation of the blood), rapid heart rate and
chocolate-brown colored blood. This product contains nitrite which
may cause methemoglobinemia.
Inhalation:
May cause allergic respiratory reaction. May cause effects similar
to those described for ingestion. Numerous studies have linked
pulmonary effects with exposure to cobalt and its compounds.
Exposure at 0.1 mg/m3 or less of cobalt metal and inorganic compounds
of cobalt caused asthma and changes in pulmonary function.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion. Cobalt compounds may cause cancer
based upon animal studies. May cause cyanosis - a blue-gray coloring
of the skin and lips caused by a lack of oxygen.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
Treat symptomatically and supportively.

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid
generating dusty conditions. Provide ventilation. Do not use
combustible materials such as paper towels to clean up spill. Keep
combustibles (wood, paper, oil, etc.,) away from spilled material.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Keep from contact with
clothing and other combustible materials. Do not breathe dust. Use
only with adequate ventilation. Inform laundry personnel of
contaminant's hazards.
Storage:
Do not store near combustible materials. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Avoid storage on wood floors.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 13600-98-1:
United Kingdom, WEL - TWA: (listed as cobalt compounds): 0.1 mg/m
TWA (as Co)
United Kingdom, WEL - STEL: (listed as cobalt compounds): 0.3 mg/
STEL (as Co)

Japan: (listed as cobalt compounds): 0.05 mg/m3 OEL (as Co)
Malaysia: (listed as cobalt, inorganic compounds): 0.02 mg/m3 TWA
Co)
Spain: (listed as cobalt, inorganic compounds): 0.02 mg/m3 VLA-ED
Co)

Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Crystalline powder
Color: yellow-brown
Odor: weakly of nitric acid
pH: ~5 (100g/L H2O)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: Not available.
Molecular Formula: CoN6Na3O12
Molecular Weight: 403.94

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Reducing agents, amines, mineral acids, organic materials,
combustible materials.
Hazardous Decomposition Products:
Nitrogen oxides, cobalt/cobalt oxides.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 13600-98-1: GF9480000
LD50/LC50:
Not available.
Carcinogenicity:
Sodium cobaltinitrate -
IARC: Group 2B carcinogen (listed as Soluble cobalt (II) salts).
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: OXIDIZING SOLID, N.O.S.*
Hazard Class: 5.1
UN Number: 1479
Packing Group: III
IMO
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing Group: III
RID/ADR
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing group: III

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN O
Risk Phrases:
R 42/43 May cause sensitization by inhalation and
skin contact.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
WGK (Water Danger/Protection)
CAS# 13600-98-1: 2
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13600-98-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13600-98-1 is not listed on the TSCA inventory.
It is for research and development use only.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 8/24/1997 Revision #5 Date: 6/17/2004

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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