**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 16940-66-2 |Sodiumborohydride, granulous | 98+% | 241-004-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F
Risk Phrases: 15 18 25 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with water liberates extremely flammable gases. In use, may
form flammable/explosive vapour-air mixture. Toxic if swallowed.
Causes burns.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Poison by ingestion. Causes gastrointestinal tract burns. Causes
cough, sore throat, chest pain, and lightheadedness.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract. May
cause abdominal pain, nausea, vomiting, and inflammation of the gums
and mouth.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Reacts violently with water giving off flammable
gas which may explode. Can burn in a fire, releasing toxic vapors.
Extinguishing Media:
Do NOT use halogenated agents. Use approved class D extinguishing
agents or smother with dry sand, clay, or sodium bicarbonate. Do NOT
use water, carbon dioxide, or foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Do not flush into a sewer. Remove all sources of ignition.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Do not breathe dust, vapor, mist, or
gas. Do not get in eyes, on skin, or on clothing. Handle under an
inert atmosphere. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep under a nitrogen blanket.
Keep from contact with oxidizing materials. Water free area. Keep
away from acids. Do not store in metal or glass containers. Do not
store in aluminum containers.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Granules
Color: white
Odor: amine-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 36 - 37 deg C
Autoignition Temperature: 250 deg C ( 482.00 deg F)
Flash Point: Not applicable.
Explosion Limits, lower: 3.02 vol %
Explosion Limits, upper: .00 vol %
Decomposition Temperature: 400 deg C
Solubility in water: Not available.
Specific Gravity/Density: 1.0740g/cm3
Molecular Formula: NaBH4
Molecular Weight: 37.82
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, exposure
to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, active metals, alcohols, metal
salts.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, oxides of boron, borane, hydrogen
gas, sodium oxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 16940-66-2: ED3325000
LD50/LC50:
CAS# 16940-66-2: Inhalation, rat: LC50 = 36 mg/m3; Oral, mouse: LD50
= 50 mg/kg; Oral, rabbit: LD50 = 50 mg/kg; Oral, rat: LD50 = 162
mg/kg; Skin, rabbit: LD50 = 230 mg/kg.
Carcinogenicity:
Sodiumborohydride, granulous -
Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Zebrabarbel (brachydanio rerio) LCo:133 mg/l (96h) Acute
bacteriatoxicity: Active-sludge bacteria EC50:1961 mg/l Method: ISO
8192-1986(E)/B (ETAD 103/OECD 209)
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Sodium borohydride
Hazard Class: 4.3
UN Number: 1426
Packing Group: 1
IMO
Shipping Name: Sodium borohydride
Hazard Class: 4.3
UN Number: 1426
Packing Group: 1
RID/ADR
Shipping Name: SODIUM BOROHYDRIDE
Hazard Class: 4.3
UN Number: 1426
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 15 Contact with water liberates extremely
flammable gases.
R 18 In use, may form flammable/explosive vapour-air
mixture.
R 25 Toxic if swallowed.
R 34 Causes burns.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 16940-66-2: 2
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 16940-66-2 is listed on Canada's DSL List.
CAS# 16940-66-2 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 16940-66-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/13/1999 Revision #2 Date: 4/03/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Venfloc 2000, polyaluminium chloride solution, Morton material
| 0-01-1 |
|
Venfloc 1143, polyacrylamide powder, Morton material
| 9003-05-8 |
|
Sodium Chloride, Reagent ACS (Crystals), 99+% (Titr.)
| 7647-14-5 |
|
(1S)-1-(2,5-Dimethoxy-2,5-dihydrofuran-2-yl)ethanol, 98%
| 33647-67-5 |
|
Sodiumborohydride, powder, 98+%, Morton material - 250 gm !!!Bulk
| 16940-66-2 |
|
Propyl formate, 96+%
| 110-74-7 |
|
2,6-Dichloro-5-Fluoro-3-Pyridinecarbonitrile, 95%
| 0-01-1 |
|
3-Methyl-1-Pentanol
| 589-35-5 |
|
Citric acid, trisodium salt dihydrate, 99%
| 6132-04-3 |
|
Sodium hexanitrocobaltate(III)
| 13600-98-1 |
|
(S)-(-)-Indoline-2-carboxylic acid, 98%
| 79815-20-6 |
|
Triallyl-s-triazine-2,4,6(1H,3H,5H)-trione, 98%
| 1025-15-6 |
|
Sodium Cyanide, Reagent ACS (Granular), 95+% (Titr.)
| 143-33-9 |
|
Tetramethylene-d8 sulfone, 99+ atom% D
| 0-01-1 |
|
4-Bromo-1-butene, 98+% (GC)
| 5162-44-7 |
|
2-Bromo-4,5-dimethoxybenzyl alcohol, 98%
| 54370-00-2 |
|
Bisphenol A Dimethylether, 98%
| 1568-83-8 |
|
Sodium dichromate dihydrate, 99%
| 7789-12-0 |
|
2-Bromo-5-Nitrobenzoic Acid
| 943-14-6 |
|
Sodium fluoride, p.a.
| 7681-49-4 |
|
2-Methylformanilide, 98%
| 94-69-9 |
|
Formic acid, sodium salt
| 141-53-7 |
|
Sodium hydrosulfide hydrate, flakes, 68-72%
| 7732-18-5 |
|
Benzophenone Oxime, 98%
| 574-66-3 |
|
Sodium Hydrosulfite
| 7775-14-6 |
|
(+)-cis, trans-Abscisic acid, 99%
| 21293-29-8 |
|
Sodium Hypophosphite Monohydrate, 99%
| 10039-56-2 |
|
Sodium Iodate, Reagent (Powder), 99% (Titr.)
| 7681-55-2 |
|
(S)-N-Carbobenzyloxy-4-Amino-2-Hydroxybutyric Acid, 96%
| 40371-50-4 |
|
Ipriflavone, 99%
| 35212-22-7 |
|
Methyl-6-O-(N-Heptylcarbamoyl)-alpha-D-Glucopyranoside, 99%
| 115457-83-5 |
|
Egg Yolk IgY purification kit
| 0-01-1 |
|
Sodium Iodide, U.S.P./N.F. (Granular), 99% (Titr.)
| 7681-82-5 |
|
Sodium D,L-Lactate,60 wt% Solution in Water
| 72-17-3 |
|
Ampicillin Sodium Salt
| 69-52-3 |
|
Sodium metabisulfite, reagent ACS, 97+%
| 7446-09-5 |
|
Sodium metasilicate, nonahydrate
| 6834-92-0 |
|
Sheep IgG purification kit
| 0-01-1 |
|
Sodium Methoxide, Anhydrous Powder
| 124-41-4 |
|
Methyl 2-Bromo-5-Nitrobenzoic Acid
| 6942-36-5 |
|
1,1,3,5,5-Pentaphenyl-1,3,5-Trimethyltrisiloxane
| 3390-61-2 |
|
2-Amino-2-Indanecarboxylic Acid
| 27473-62-7 |
|
Sodium Nitrite, reagent ACS (crystals), 97+% (titr.)
| 7632-00-0 |
|
Sodium orthovanadate, 99%, - 60 mesh
| 13721-39-6 |
|
3-(2-Naphthyl)-D-Alanine, 99%
| 76985-09-6 |
|
3-[2-(2-Aminoethylamino)ethylamino]propyl-trimethoxysilane, tech.
| 35141-30-1 |
|
Sodium oxalate, p.a.
| 62-76-0 |
|
Sodium periodate, reagent acs
| 7790-28-5 |
|
(-)-(1R,2S)-2-Amino-1-Cyclopentanecarboxylic Acid
| 0-01-1 |
|
Aniline
| 62-53-3 |
|
|