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MSDS 
:
 Sodium Cobaltinitrite
CAS 
:
 13600-98-1
SYNONYMS 
:
 Sodium Hexanitrocobaltate(III), pa.
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13600-98-1 |Sodium Cobaltinitrite | >99 | 237-077-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: O
Risk Phrases: 8

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Contact with combustible material may cause fire.

Potential Health Effects
Eye:
May cause eye irritation. May cause conjunctivitis. May cause
permanent corneal opacification.
Skin:
May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. May cause severe
irritation and possible burns.
Ingestion:
May cause liver damage. Can cause nervous system damage. Exposure
may cause anemia and other blood abnormalities. May cause burns to
the gastrointestinal tract. May cause nausea, vomiting, and diarrhea,
possibly with blood.
Inhalation:
May cause allergic respiratory reaction. May cause severe irritation
of the respiratory tract with sore throat, coughing, shortness of
breath and delayed lung edema. May cause effects similar to those
described for ingestion. May cause acute pulmonary edema, asphyxia,
chemical pneumonitis, and upper airway obstruction caused by edema.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion. May cause fetal effects.
Prolonged inhalation can cause a sharp drop in blood pressure,
throbbing, headache, nausea, and weakness. Cobalt compounds may cause
cancer based upon animal studies. Damage to kidney tubules or
glomeruli may occur. May cause cyanosis - a blue-gray coloring of the
skin and lips caused by a lack of oxygen.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with combustible materials
may cause a fire. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
with caution and in flooding amounts.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam. Contact professional fire-fighters immediately.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Remove all sources of
ignition. Provide ventilation.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. Keep container tightly closed. Avoid
contact with clothing and other combustible materials. Do not get on
skin or in eyes. Do not ingest or inhale.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a cool, dry, well-ventilated area
away from incompatible substances. Keep containers tightly closed.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Solid
Color: yellow to brown-red
Odor: none reported
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not applicable.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: Not available.
Molecular Formula: CoN6Na3O12
Molecular Weight: 403.9356

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, dust
generation, combustible materials, reducing agents.
Incompatibilities with Other Materials:
Reducing agents, strong acids, amines, mineral acids, organic
materials.
Hazardous Decomposition Products:
Nitrogen oxides, cobalt/cobalt oxides.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 13600-98-1: GF9480000
LD50/LC50:
Not available.
Carcinogenicity:
Sodium Cobaltinitrite -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing Group: III
IMO
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing Group: III
RID/ADR
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing group: II

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O
Risk Phrases:
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
WGK (Water Danger/Protection)
CAS# 13600-98-1: 2
United Kingdom Occupational Exposure Limits

United Kingdom Maximum Exposure Limits

Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13600-98-1 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 13600-98-1: Not available.
US FEDERAL
TSCA
CAS# 13600-98-1 is not listed on the TSCA inventory.
It is for research and development use only.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 12/12/1997 Revision #7 Date: 3/04/2004

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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