**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7775-11-3 |Sodium chromate | 100 | 231-889-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+ O N
Risk Phrases: 21 25 26 34 42/43 45 46 8 48/23 60 61 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin. Toxic if swallowed. Very toxic by
inhalation. Causes burns. May cause sensitization by inhalation and
skin contact. May cause cancer. May cause heritable genetic damage.
Contact with combustible material may cause fire. Toxic : danger of
serious damage to health by prolonged exposure through inhalation.
May impair fertility. May cause harm to the unborn child. Very toxic
to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. May cause deep,
penetrating ulcers of the skin. May be absorbed through the skin. May
cause severe irritation and possible burns.
Ingestion:
Harmful if swallowed. May cause liver and kidney damage. May cause
perforation of the digestive tract. May cause hemorrhaging of the
digestive tract. Causes digestive tract irritation with possible
burns.
Inhalation:
Causes respiratory tract irritation. May cause asthmatic attacks due
to allergic sensitization of the respiratory tract. May cause
ulceration and perforation of the nasal septum if inhaled in
excessive quantities. Causes chemical burns to the respiratory
tract.
Chronic:
Prolonged or repeated eye contact may cause conjunctivitis.
Prolonged or repeated skin contact may cause sensitization
dermatitis and possible destruction and/or ulceration. Prolonged or
repeated exposure may lead to asthma and perforation of the nasal
septum. Prolonged or repeated contact may cause skin necrosis and/or
ulceration of the skin. May cause cancer in humans. May cause
reproductive and fetal effects. Chronic exposure may cause acute
hepatitis with jaundice.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Approach spill from upwind. Do not let this
chemical enter the environment.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not get in
eyes, on skin, or on clothing. Do not ingest or inhale. Discard
contaminated shoes. Inform laundry personnel of contaminant's
hazards.
Storage:
Do not store near combustible materials. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 7775-11-3:
United Kingdom, WEL - TWA: (listed as chromium (vi) compounds): 0
mg/m3 TWA (as Cr)
United Kingdom, WEL - STEL: (listed as chromium (vi) compounds):
mg/m3 STEL (as Cr)
United States OSHA: 0.1 mg/m3 Ceiling (listed under Chromates).
Belgium - TWA: (listed as chromium (vi) compounds- water soluble)
0.05 mg/m3 VLE (as Cr)
France - VME: (listed as chromium (vi) compounds): 0.05 mg/m3 VME
Cr)
Germany: (listed as chromium (vi) compounds): 0.05 mg/m3 VME (as
Japan: (listed as chromium (vi) compounds): 0.05 mg/m3 OEL (as Cr
0.01 mg/m3 OEL (certain compounds, as Cr)
Malaysia: (listed as chromium (vi) compounds- water soluble): 0.0
mg/m3 TWA (as Cr)
Netherlands: (listed as chromium (vi) compounds- water soluble):
mg/m3 STEL
Netherlands: (listed as chromium (vi) compounds- water soluble):
0.025 mg/m3 MAC
Spain: 0.05 mg/m3 VLA-ED (as Cr)
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: yellow
Odor: odorless
pH: Alkaline in solution
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Decomposes
Freezing/Melting Point: 792 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 87 % in water
Specific Gravity/Density: 2.71-2.736
Molecular Formula: Na2CrO4
Molecular Weight: 161.97
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong reducing agents, organic materials, combustible materials,
easily oxidizable materials.
Hazardous Decomposition Products:
Toxic fumes of sodium oxide, toxic chromium oxide fumes.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7775-11-3: GB2955000
LD50/LC50:
CAS# 7775-11-3: Oral, rat: LD50 = 136 mg/kg.
Dermal LDLo guinea pig: 206 mg/kg.
Carcinogenicity:
Sodium chromate -
California: carcinogen, initial date 2/27/87 (listed as Chromium (VI)
NTP: Known carcinogen (listed as Chromium (VI) compounds).
IARC: Group 1 carcinogen (listed as Chromium (VI) compounds).
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Oxidizing Solid, Toxic, N.O.S.
Hazard Class: 5.1
UN Number: 3087
Packing Group: III
IMO
Shipping Name: Oxidizing Solid, Toxic, N.O.S.
Hazard Class: 5.1
UN Number: 3087
Packing Group: III
RID/ADR
Shipping Name: Oxidizing Solid, Toxic, N.O.S.
Hazard Class: 5.1
UN Number: 3087
Packing group: III
USA RQ: CAS# 7775-11-3: 10 lb final RQ; 4.54 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ O N
Risk Phrases:
R 45 May cause cancer.
R 46 May cause heritable genetic damage.
R 61 May cause harm to the unborn child.
R 21 Harmful in contact with skin.
R 25 Toxic if swallowed.
R 26 Very toxic by inhalation.
R 34 Causes burns.
R 42/43 May cause sensitization by inhalation and
skin contact.
R 48/23 Toxic : danger of serious damage to health
by prolonged exposure through inhalation.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 60 May impair fertility.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7775-11-3: 3
Canada
CAS# 7775-11-3 is listed on Canada's DSL List.
CAS# 7775-11-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7775-11-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/23/1998 Revision #8 Date: 5/20/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Sodium Chlorate
| 7775-09-9 |
|
Sodium chloride
| 7647-14-5 |
|
Glycyl-L-glutamine monohydrate, 99%
| 13115-71-4 |
|
2-Bromoethyl Ethyl Ether, Tech., 94% (GC)
| 592-55-2 |
|
Sodium chromate, anhydrous
| 7775-11-3 |
|
(R,S)-2-Amino-3-hydroxy-3-methylbutanoic acid, 99+%
| 2280-28-6 |
|
Sodium Citrate Dihydrate
| 6132-04-3 |
|
Sodium Cobaltinitrite
| 13600-98-1 |
|
Triphenyl phosphite, 99+%
| 101-02-0 |
|
4-Butylphenol, 99% (gc)
| 1638-22-8 |
|
2,2,2-Triphenylacetophenone, 99+%(TLC)
| 466-37-5 |
|
Sodium Cyanide
| 143-33-9 |
|
Sodium Chloranilate Trihydrate, 95% (UV-Vis)
| 36275-66-8 |
|
2,3,4,5-Tetrachloronitrobenzene, 99%
| 879-39-0 |
|
Dimethyl Malonate, 99+%
| 108-59-8 |
|
2-(Methacryloyloxy)ethyltrimethylammonium methyl sulfate, 80% in
| 6891-44-7 |
|
Sodium dichromate dihydrate
| 7789-12-0 |
|
2-Phenyl-1-propanol, 97%
| 1123-85-9 |
|
N-Carbobenzyloxy-L-Serine, 99+%
| 1145-80-8 |
|
Sodium fluoride
| 7681-49-4 |
|
Triphenylantimony, 97%
| 603-36-1 |
|
Sodium Formate
| 141-53-7 |
|
Sodium Metaphosphate
| 10124-56-8 |
|
trans-2-Pentenoic acid, 97%
| 13991-37-2 |
|
3-Acetylindole, 97%
| 703-80-0 |
|
Sodium hydroxide, solid
| 497-19-8 |
|
3,5-Dimethyl-2-cyclohexen-1-one, 99%
| 1123-09-7 |
|
Sodium hypophosphite monohydrate
| 7681-53-0 |
|
Sodium iodate
| 7681-55-2 |
|
Sodium Iodide, Anhydrous, 99+%
| 7681-82-5 |
|
1,1'-(4-Chlorobutylidene)bis-(4-fluorobenzene) tech. 90+%
| 3312-04-7 |
|
Sodium Lactate
| 72-17-3 |
|
Sodium arsenite, powder, certified
| 7784-46-5 |
|
Sodium metabisulfite
| 7446-09-5 |
|
2,6-Dichloropyrazine, 99+%
| 4774-14-5 |
|
Sodium meta-Silicate Nonahydrate
| 6834-92-0 |
|
Sodium meta-Silicate Pentahydrate
| 6834-92-0 |
|
Sodium Methoxide
| 124-41-4 |
|
Sodium Nitrate
| 7631-99-4 |
|
Octanoic Acid, 99.5+%
| 124-07-2 |
|
Sodium nitrite
| 7632-00-0 |
|
4-Hydroxy-2-mercapto-6-propylpyrimidine, 98%
| 51-52-5 |
|
1-Phenyl-1-cyclopropanecarboxylic acid, 97%
| 6120-95-2 |
|
4,4'-Dimethoxybenzhydrol, 98+%
| 728-87-0 |
|
1,1-Dimethylpropargylamine, 90% ( remainder water)
| 2978-58-7 |
|
Diethyldithiocarbamic Acid, Sodium Salt Trihydrate, Reagent ACS
| |
|
Vinyltriphenylphosphonium bromide, 97%
| 5044-52-0 |
|
Mucic Acid, 98%
| 526-99-8 |
|
Sodium oxalate
| 62-76-0 |
|
2-Hydroxyethylhydrazine, 90%
| 109-84-2 |
|
|