**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1571-33-1 |Phenylphosphonic acid | 98.0 | 216-388-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May be harmful if swallowed.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Discard contaminated clothing in a manner
which limits further exposure. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Keep
container tightly closed. Do not get on skin or in eyes. Do not
ingest or inhale. Use with adequate ventilation. Discard
contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1571-33-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: white to off-white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 163 - 166 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: >165 deg C
Solubility in water: Soluble.
Specific Gravity/Density: 1.475
Molecular Formula: C6H7O3P
Molecular Weight: 158.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Phosphine, carbon monoxide, oxides of phosphorus, irritating and
toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1571-33-1: TA0350000
LD50/LC50:
CAS# 1571-33-1: Draize test, rabbit, skin: 500 uL Moderate; Oral,
rat: LD50 = 2 gm/kg.
Carcinogenicity:
Phenylphosphonic acid -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3261
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1571-33-1: 2
Canada
CAS# 1571-33-1 is listed on Canada's DSL List.
CAS# 1571-33-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1571-33-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/30/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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ALL MSDS PAGES IN THIS GROUP
| NAME | CAS |
3-Nitro-1,8-Naphthalic Anhydride, 99%
| 3027-38-1 |
Poly(4-vinylpyridine) , cross-linked with 2% dvb, ca. 60 mesh
| 9017-40-7 |
Isopropyl disulfide, 96%
| 4253-89-8 |
1,4-Dinitrobenzene
| 100-25-4 |
Phenylphosphonic acid, 98%
| 1571-33-1 |
4,4'-Isopropylidenediphenol, 97%
| 80-05-7 |
3-(1,3-Dimethyl-4(s),5(s)-diphenylimidazolidin-2-yl)pyridine
| |
Terbium Atomic Absorption Standard Solution, 1 mg/ml Tb in 2% HCl
| 7440-27-9 |
4,4'-Difluorobenzhydrol, 98%
| 365-24-2 |
Methacryloyl chloride, stabilized
| 920-46-7 |
4-Chlorobenzaldehyde, 98.5+%
| 104-88-1 |
1-Methyl-1-cyclohexene, 98+% stabilized with 10 ppm Hydroquinone
| 591-49-1 |
Tellurium(iv) chloride, 99%
| 10026-07-0 |
3-(2-Bromoacetamido)-proxyl,free radical
| 17932-40-0 |
alpha-Hydroxyhippuric acid, 98%
| 16555-77-4 |
1-(2,4-Dichlorophenyl)-Cyclopropane Carboxylic Acid, 95%
| 84604-70-6 |
2-(5-Methoxy-2-Nitrophenyl)Malondialdehyde Monohydrate, 95+% (NMR)
| 0-01-1 |
Tris-Maleate, 98%
| 72200-76-1 |
1-Adamantanecarbonitrile, 99+%
| 23074-42-2 |
1-(3-Chloropropyl)piperazine Dihydro Chloride Monohydrate, 98%
| 34782-06-4 |
4-Iodoanisole, 98%
| 696-62-8 |
Tris-[3-(heptafluoropropylhydroxymethylene )-d-camphorato],
| 38832-94-9 |
2-Methyl-2-propen-1-ol, 98%
| 513-42-8 |
L-3-Hydroxyproline
| 4298-08-2 |
Acetylsalicylsalicylic Acid, 97%
| 530-75-6 |
N-Hydroxynaphthalimide, 97% (uv-vis)
| 7797-81-1 |
2-Chloro-1-Fluoro-4-Iodobenzene, 99%
| 0-00-1 |
o-Fluorotoluene, 99+%
| 95-52-3 |
Heptafluorobutyric Acid, Sequenation Grade 99% (titr.)
| 375-22-4 |
[2,5]-Dibenzo-21-Crown-7, 97+%
| 0-00-1 |
Gallein, 1-Hydrate
| 2103-64-2 |
Tin Atomic Absorption Standard Solution 1 mg/ml Sn in 20% HCl
| 7440-31-5 |
2-(Carboxymethylthio)-4-Methylpyrimidine 97% (Titr.)
| 46118-95-0 |
4'-Chloroacetanilide, 97%
| 539-03-7 |
Aluminum 2-Ethylhexanoate
| 30745-55-2 |
2-Bromo-p-xylene, 97+%
| 553-94-6 |
Tungsten Carbide, 99%
| 12070-12-1 |
2-Methyl-5-nitrobenzoic acid, 99+%
| 1975-52-6 |
2',4'-Difluoroacetophenone, 99%
| 364-83-0 |
4-Methylsulphonylphenylacetic acid, 95+%
| 90536-66-6 |
3,5-Dipropoxyphenol, 97% (GC)
| 28334-99-8 |
2-Amino-1-methylbenzimidazole, 99+%
| 1622-57-7 |
(+)-1,4-Dithio-D-Threitol, 98+%
| 0-00-1 |
3-Amino-4-Carbethoxypyrazole, 99%
| 6994-25-8 |
Phenoxy resin, medium molecular weight, av erage m.w.30000,pellets
| 26402-79-9 |
Sodium bis(2-methoxyethoxy)aluminumhydride, 70 wt% sol. in toluene
| 108-88-3 |
O-Hydroxycinnamic Acid, 97%, Predominantly Trans
| 614-60-8 |
3-Chloro-1,2-Propanediol, P.A.
| 96-24-2 |
4-Picolyl chloride hydrochloride, 97%
| 1822-51-1 |
L(+)-Lyxose, 99%, Mixture of Anomers
| 1949-78-6 |
|
|