**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 591-49-1 |1-Methyl-1-cyclohexene | 98+ | 209-718-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Vapors may cause dizziness or
suffocation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may
be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. Remove contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Water may be
ineffective. Material is lighter than water and a fire may be spread
by the use of water. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They
can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Water may be ineffective. This material is lighter than water and
insoluble in water. The fire could easily be spread by the use of
water in an area where the water cannot be contained. Do NOT use
straight streams of water. Use water spray, dry chemical, carbon
dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 591-49-1:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 110 - 111 deg C @ 760.00 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: -3 deg C ( 26.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 0.8130 g/cm3
Molecular Formula: C7H12
Molecular Weight: 96.17
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 591-49-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Methyl-1-cyclohexene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: HYDROCARBONS, LIQUID, N.O.S.
Hazard Class: 3
UN Number: 3295
Packing Group: II
IMO
Shipping Name: HYDROCARBONS, LIQUID, N.O.S.
Hazard Class: 3
UN Number: 3295
Packing Group: II
RID/ADR
Shipping Name: HYDROCARBONS, LIQUID, N.O.S.
Hazard Class: 3
UN Number: 3295
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 591-49-1: No information available.
Canada
CAS# 591-49-1 is listed on Canada's NDSL List.
CAS# 591-49-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 591-49-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 4/07/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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3-Nitro-1,8-Naphthalic Anhydride, 99%
| 3027-38-1 |
|
Poly(4-vinylpyridine) , cross-linked with 2% dvb, ca. 60 mesh
| 9017-40-7 |
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Isopropyl disulfide, 96%
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|
1,4-Dinitrobenzene
| 100-25-4 |
|
Phenylphosphonic acid, 98%
| 1571-33-1 |
|
4,4'-Isopropylidenediphenol, 97%
| 80-05-7 |
|
3-(1,3-Dimethyl-4(s),5(s)-diphenylimidazolidin-2-yl)pyridine
| |
|
Terbium Atomic Absorption Standard Solution, 1 mg/ml Tb in 2% HCl
| 7440-27-9 |
|
4,4'-Difluorobenzhydrol, 98%
| 365-24-2 |
|
Methacryloyl chloride, stabilized
| 920-46-7 |
|
4-Chlorobenzaldehyde, 98.5+%
| 104-88-1 |
|
1-Methyl-1-cyclohexene, 98+% stabilized with 10 ppm Hydroquinone
| 591-49-1 |
|
Tellurium(iv) chloride, 99%
| 10026-07-0 |
|
3-(2-Bromoacetamido)-proxyl,free radical
| 17932-40-0 |
|
alpha-Hydroxyhippuric acid, 98%
| 16555-77-4 |
|
1-(2,4-Dichlorophenyl)-Cyclopropane Carboxylic Acid, 95%
| 84604-70-6 |
|
2-(5-Methoxy-2-Nitrophenyl)Malondialdehyde Monohydrate, 95+% (NMR)
| 0-01-1 |
|
Tris-Maleate, 98%
| 72200-76-1 |
|
1-Adamantanecarbonitrile, 99+%
| 23074-42-2 |
|
1-(3-Chloropropyl)piperazine Dihydro Chloride Monohydrate, 98%
| 34782-06-4 |
|
4-Iodoanisole, 98%
| 696-62-8 |
|
Tris-[3-(heptafluoropropylhydroxymethylene )-d-camphorato],
| 38832-94-9 |
|
2-Methyl-2-propen-1-ol, 98%
| 513-42-8 |
|
L-3-Hydroxyproline
| 4298-08-2 |
|
Acetylsalicylsalicylic Acid, 97%
| 530-75-6 |
|
N-Hydroxynaphthalimide, 97% (uv-vis)
| 7797-81-1 |
|
2-Chloro-1-Fluoro-4-Iodobenzene, 99%
| 0-00-1 |
|
o-Fluorotoluene, 99+%
| 95-52-3 |
|
Heptafluorobutyric Acid, Sequenation Grade 99% (titr.)
| 375-22-4 |
|
[2,5]-Dibenzo-21-Crown-7, 97+%
| 0-00-1 |
|
Gallein, 1-Hydrate
| 2103-64-2 |
|
Tin Atomic Absorption Standard Solution 1 mg/ml Sn in 20% HCl
| 7440-31-5 |
|
2-(Carboxymethylthio)-4-Methylpyrimidine 97% (Titr.)
| 46118-95-0 |
|
4'-Chloroacetanilide, 97%
| 539-03-7 |
|
Aluminum 2-Ethylhexanoate
| 30745-55-2 |
|
2-Bromo-p-xylene, 97+%
| 553-94-6 |
|
Tungsten Carbide, 99%
| 12070-12-1 |
|
2-Methyl-5-nitrobenzoic acid, 99+%
| 1975-52-6 |
|
2',4'-Difluoroacetophenone, 99%
| 364-83-0 |
|
4-Methylsulphonylphenylacetic acid, 95+%
| 90536-66-6 |
|
3,5-Dipropoxyphenol, 97% (GC)
| 28334-99-8 |
|
2-Amino-1-methylbenzimidazole, 99+%
| 1622-57-7 |
|
(+)-1,4-Dithio-D-Threitol, 98+%
| 0-00-1 |
|
3-Amino-4-Carbethoxypyrazole, 99%
| 6994-25-8 |
|
Phenoxy resin, medium molecular weight, av erage m.w.30000,pellets
| 26402-79-9 |
|
Sodium bis(2-methoxyethoxy)aluminumhydride, 70 wt% sol. in toluene
| 108-88-3 |
|
O-Hydroxycinnamic Acid, 97%, Predominantly Trans
| 614-60-8 |
|
3-Chloro-1,2-Propanediol, P.A.
| 96-24-2 |
|
4-Picolyl chloride hydrochloride, 97%
| 1822-51-1 |
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L(+)-Lyxose, 99%, Mixture of Anomers
| 1949-78-6 |
|
|