**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 375-22-4 |Heptafluorobutyric Acid | 99 | 206-786-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Water-reactive.
Potential Health Effects
Eye:
Causes eye burns. May result in corneal injury.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode in
the heat of a fire. Will react with water to form toxic and corrosive
fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. If water is the only media available,
use in flooding amounts. DO NOT USE WATER! Do NOT get water inside
containers. Cool containers with flooding quantities of water until
well after fire is out. Use water spray, dry chemical, carbon
dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Do not get water on spilled substances or inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Do not get in eyes, on skin, or on clothing.
Do not ingest or inhale. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Store in a tightly closed container. Corrosives area. Water free
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Local exhaust ventilation may be necessary to control any air
contaminants to within their TLVs during the use of this product.
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colourless
Odor: none reported
pH: Not available.
Vapor Pressure: 10 mm Hg @ 25C
Viscosity: Not available.
Boiling Point: 120-121 deg C
Freezing/Melting Point: -18 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Miscible with water.
Specific Gravity/Density: 1.65
Molecular Formula: C4HF7O2
Molecular Weight: 213.9946
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidants and reducing agents. Will react with water or steam
to produce corrosive fumes.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 375-22-4: ET4025000
LD50/LC50:
Not available.
Carcinogenicity:
Heptafluorobutyric Acid -
Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24 Avoid contact with skin.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
with...
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 375-22-4: 2
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 375-22-4 is listed on Canada's NDSL List.
CAS# 375-22-4 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 375-22-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/25/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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Poly(4-vinylpyridine) , cross-linked with 2% dvb, ca. 60 mesh
| 9017-40-7 |
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Isopropyl disulfide, 96%
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Phenylphosphonic acid, 98%
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|
4,4'-Isopropylidenediphenol, 97%
| 80-05-7 |
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3-(1,3-Dimethyl-4(s),5(s)-diphenylimidazolidin-2-yl)pyridine
| |
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Terbium Atomic Absorption Standard Solution, 1 mg/ml Tb in 2% HCl
| 7440-27-9 |
|
4,4'-Difluorobenzhydrol, 98%
| 365-24-2 |
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Methacryloyl chloride, stabilized
| 920-46-7 |
|
4-Chlorobenzaldehyde, 98.5+%
| 104-88-1 |
|
1-Methyl-1-cyclohexene, 98+% stabilized with 10 ppm Hydroquinone
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Tellurium(iv) chloride, 99%
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|
alpha-Hydroxyhippuric acid, 98%
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|
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| 84604-70-6 |
|
2-(5-Methoxy-2-Nitrophenyl)Malondialdehyde Monohydrate, 95+% (NMR)
| 0-01-1 |
|
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| 72200-76-1 |
|
1-Adamantanecarbonitrile, 99+%
| 23074-42-2 |
|
1-(3-Chloropropyl)piperazine Dihydro Chloride Monohydrate, 98%
| 34782-06-4 |
|
4-Iodoanisole, 98%
| 696-62-8 |
|
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| 38832-94-9 |
|
2-Methyl-2-propen-1-ol, 98%
| 513-42-8 |
|
L-3-Hydroxyproline
| 4298-08-2 |
|
Acetylsalicylsalicylic Acid, 97%
| 530-75-6 |
|
N-Hydroxynaphthalimide, 97% (uv-vis)
| 7797-81-1 |
|
2-Chloro-1-Fluoro-4-Iodobenzene, 99%
| 0-00-1 |
|
o-Fluorotoluene, 99+%
| 95-52-3 |
|
Heptafluorobutyric Acid, Sequenation Grade 99% (titr.)
| 375-22-4 |
|
[2,5]-Dibenzo-21-Crown-7, 97+%
| 0-00-1 |
|
Gallein, 1-Hydrate
| 2103-64-2 |
|
Tin Atomic Absorption Standard Solution 1 mg/ml Sn in 20% HCl
| 7440-31-5 |
|
2-(Carboxymethylthio)-4-Methylpyrimidine 97% (Titr.)
| 46118-95-0 |
|
4'-Chloroacetanilide, 97%
| 539-03-7 |
|
Aluminum 2-Ethylhexanoate
| 30745-55-2 |
|
2-Bromo-p-xylene, 97+%
| 553-94-6 |
|
Tungsten Carbide, 99%
| 12070-12-1 |
|
2-Methyl-5-nitrobenzoic acid, 99+%
| 1975-52-6 |
|
2',4'-Difluoroacetophenone, 99%
| 364-83-0 |
|
4-Methylsulphonylphenylacetic acid, 95+%
| 90536-66-6 |
|
3,5-Dipropoxyphenol, 97% (GC)
| 28334-99-8 |
|
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| 1622-57-7 |
|
(+)-1,4-Dithio-D-Threitol, 98+%
| 0-00-1 |
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| 6994-25-8 |
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| 108-88-3 |
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| 614-60-8 |
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| 96-24-2 |
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| 1949-78-6 |
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