MSDS | : | 4,4'-Isopropylidenediphenol, 97% | CAS | : | 80-05-7 | SYNONYMS | : | Bisphenol A; p,p'-Dihydroxydiphenyl-dimethylmethane; 2,2-Bis(4-hydroxyphenyl)- propane; 2,2-(4,4'-Dihydroxydiphenyl)propane; 4,4'-Dihydroxy-2,2-diphenylpropane; 4,4'-Dihydroxydiphenyldimethylmethane; 4,4'-Isopropylidenebisphenol; Bisphenol, 4,4'-(1-methylethylidene)-; Dimethylmethylene-p,p'-diphenol; Phenol, 4,4'-(1-methylethylidene)bis- |
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**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 80-05-7 |4,4'-Isopropylidenediphenol | 97 | 201-245-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. May cause
sensitization by skin contact.
Potential Health Effects
Eye:
May result in corneal injury. Causes severe eye irritation and
possible injury.
Skin:
Causes mild skin irritation. May cause skin sensitization, an
allergic reaction, which becomes evident upon re-exposure to this
material.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Ingestion of large amounts may produce central nervous
system depression, headache, dizziness, diarrhea, and possible
hemorrhagic gastroenteritis.
Inhalation:
Causes upper respiratory tract irritation. Causes irritation of the
mucous membrane. Inhalation of dust may cause irritation of the nose
and throat. Inhalation may cause liver, kidney, and bladder effects.
Chronic:
Animal studies have reported that fetal effects/abnormalities may
occur when maternal toxicity is seen. Laboratory experiments have
resulted in mutagenic effects. Repeated skin exposure may produce
photoallergic contact dermatitis with persistent light reactivitiy.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively. Individuals with chronic
respiratory disorders may be more susceptible to the effects of this
product. Persons with pre-existing skin disorders may be more
susceptible to dermatitis. To treat corneal damage, careful
ophthalmologic evaluation is recommended and the possibility of
local corticosteroid therapy should be considered.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Dusts may
be combustible when exposed to heat, flame, or oxidizing agents.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 80-05-7:
Germany: 5 mg/m3 TWA (inhalable fraction)
Netherlands: 5 mg/m3 MAC (respirable dust); 10 mg/m3 MAC (inhalab
dust)
Russia: 5 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white
Odor: phenol-like - mild odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 220 deg C @ 4.00mm Hg
Freezing/Melting Point: 150 - 159 deg C
Autoignition Temperature: 510 deg C ( 950.00 deg F)
Flash Point: 227 deg C ( 440.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 1.195 @ 25C
Molecular Formula: C15H16O2
Molecular Weight: 228.29
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, bases, acid anhydrides, acid chlorides.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, aldehydes.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 80-05-7: SL6300000
LD50/LC50:
CAS# 80-05-7: Draize test, rabbit, eye: 250 ug/24H Severe; Draize
test, rabbit, skin: 500 mg/24H Mild; Oral, mouse: LD50 = 2400 mg/kg;
Oral, mouse: LD50 = 2500 mg/kg; Oral, rabbit: LD50 = 2230 mg/kg;
Oral, rat: LD50 = 3250 mg/kg; Oral, rat: LD50 = 1200 mg/kg; Skin,
rabbit: LD50 = 3 mL/kg.
Carcinogenicity:
4,4'-Isopropylidenediphenol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Fathead Minnow: LC50 =4.6 mg/L; 96 Hr; Flow-through
bioassayWater flea Daphnia: EC50 = 10 mg/L; 48 Hr;
Unspecified4,4'-Isopropylidenediphenol is expected to show moderate
to low soil mobility and will biodegrade in soil under aerobic
conditions following acclimation. In acclimated water, biodegradaion
will be the dominate fate process with a half-life of 4 days. In
nonacclimated water, this product may biodegrade after a sufficient
adaptation period and may adsorb extensively to suspended solids and
sediments or it may photolyze. 4,4'-Isopropylidenediphenol is not
expected to bioaccumulate significantly in aquatic organisms,
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 24 Avoid contact with skin.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37 Wear suitable gloves.
WGK (Water Danger/Protection)
CAS# 80-05-7: 2
Canada
CAS# 80-05-7 is listed on Canada's DSL List.
CAS# 80-05-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 80-05-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/06/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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