**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 513-42-8 |Methallyl alcohol | 98 | 208-161-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 10 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause eye burns.
Skin:
Causes skin irritation. May cause skin burns.
Ingestion:
Causes digestive tract irritation.
Inhalation:
Causes respiratory tract irritation. Vapors may cause dizziness or
suffocation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Remove
contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air. Will
burn if involved in a fire. Use water spray to keep fire-exposed
containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor. May be ignited by heat, sparks, and
flame.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors. Water spray may
reduce vapor but may not prevent ignition in closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep away from heat,
sparks and flame. Avoid ingestion and inhalation. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers
to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 513-42-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Clear
Odor: None reported.
pH: Not available.
Vapor Pressure: 10 hPa @ 20 C
Viscosity: 2.24 20 deg C
Boiling Point: 113 - 115 deg C
Freezing/Melting Point: -50 deg C
Autoignition Temperature: 320 deg C ( 608.00 deg F)
Flash Point: 34 deg C ( 93.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: .0857g/cm3
Molecular Formula: C4H8O
Molecular Weight: 72.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 513-42-8: UD5250000
LD50/LC50:
CAS# 513-42-8: Draize test, rabbit, skin: 500 mg Moderate.
Carcinogenicity:
Methallyl alcohol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: METHALLYL ALCOHOL
Hazard Class: 3
UN Number: 2614
Packing Group: III
IMO
Shipping Name: METHALLYL ALCOHOL
Hazard Class: 3.3
UN Number: 2614
Packing Group: III
RID/ADR
Shipping Name: METHALLYL ALCOHOL
Hazard Class: 3
UN Number: 2614
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
S 33 Take precautionary measures against static
discharges.
S 50A Do not mix with acids.
WGK (Water Danger/Protection)
CAS# 513-42-8: 2
Canada
CAS# 513-42-8 is listed on Canada's DSL List.
CAS# 513-42-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 513-42-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/28/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Nitro-1,8-Naphthalic Anhydride, 99%
| 3027-38-1 |
|
Poly(4-vinylpyridine) , cross-linked with 2% dvb, ca. 60 mesh
| 9017-40-7 |
|
Isopropyl disulfide, 96%
| 4253-89-8 |
|
1,4-Dinitrobenzene
| 100-25-4 |
|
Phenylphosphonic acid, 98%
| 1571-33-1 |
|
4,4'-Isopropylidenediphenol, 97%
| 80-05-7 |
|
3-(1,3-Dimethyl-4(s),5(s)-diphenylimidazolidin-2-yl)pyridine
| |
|
Terbium Atomic Absorption Standard Solution, 1 mg/ml Tb in 2% HCl
| 7440-27-9 |
|
4,4'-Difluorobenzhydrol, 98%
| 365-24-2 |
|
Methacryloyl chloride, stabilized
| 920-46-7 |
|
4-Chlorobenzaldehyde, 98.5+%
| 104-88-1 |
|
1-Methyl-1-cyclohexene, 98+% stabilized with 10 ppm Hydroquinone
| 591-49-1 |
|
Tellurium(iv) chloride, 99%
| 10026-07-0 |
|
3-(2-Bromoacetamido)-proxyl,free radical
| 17932-40-0 |
|
alpha-Hydroxyhippuric acid, 98%
| 16555-77-4 |
|
1-(2,4-Dichlorophenyl)-Cyclopropane Carboxylic Acid, 95%
| 84604-70-6 |
|
2-(5-Methoxy-2-Nitrophenyl)Malondialdehyde Monohydrate, 95+% (NMR)
| 0-01-1 |
|
Tris-Maleate, 98%
| 72200-76-1 |
|
1-Adamantanecarbonitrile, 99+%
| 23074-42-2 |
|
1-(3-Chloropropyl)piperazine Dihydro Chloride Monohydrate, 98%
| 34782-06-4 |
|
4-Iodoanisole, 98%
| 696-62-8 |
|
Tris-[3-(heptafluoropropylhydroxymethylene )-d-camphorato],
| 38832-94-9 |
|
2-Methyl-2-propen-1-ol, 98%
| 513-42-8 |
|
L-3-Hydroxyproline
| 4298-08-2 |
|
Acetylsalicylsalicylic Acid, 97%
| 530-75-6 |
|
N-Hydroxynaphthalimide, 97% (uv-vis)
| 7797-81-1 |
|
2-Chloro-1-Fluoro-4-Iodobenzene, 99%
| 0-00-1 |
|
o-Fluorotoluene, 99+%
| 95-52-3 |
|
Heptafluorobutyric Acid, Sequenation Grade 99% (titr.)
| 375-22-4 |
|
[2,5]-Dibenzo-21-Crown-7, 97+%
| 0-00-1 |
|
Gallein, 1-Hydrate
| 2103-64-2 |
|
Tin Atomic Absorption Standard Solution 1 mg/ml Sn in 20% HCl
| 7440-31-5 |
|
2-(Carboxymethylthio)-4-Methylpyrimidine 97% (Titr.)
| 46118-95-0 |
|
4'-Chloroacetanilide, 97%
| 539-03-7 |
|
Aluminum 2-Ethylhexanoate
| 30745-55-2 |
|
2-Bromo-p-xylene, 97+%
| 553-94-6 |
|
Tungsten Carbide, 99%
| 12070-12-1 |
|
2-Methyl-5-nitrobenzoic acid, 99+%
| 1975-52-6 |
|
2',4'-Difluoroacetophenone, 99%
| 364-83-0 |
|
4-Methylsulphonylphenylacetic acid, 95+%
| 90536-66-6 |
|
3,5-Dipropoxyphenol, 97% (GC)
| 28334-99-8 |
|
2-Amino-1-methylbenzimidazole, 99+%
| 1622-57-7 |
|
(+)-1,4-Dithio-D-Threitol, 98+%
| 0-00-1 |
|
3-Amino-4-Carbethoxypyrazole, 99%
| 6994-25-8 |
|
Phenoxy resin, medium molecular weight, av erage m.w.30000,pellets
| 26402-79-9 |
|
Sodium bis(2-methoxyethoxy)aluminumhydride, 70 wt% sol. in toluene
| 108-88-3 |
|
O-Hydroxycinnamic Acid, 97%, Predominantly Trans
| 614-60-8 |
|
3-Chloro-1,2-Propanediol, P.A.
| 96-24-2 |
|
4-Picolyl chloride hydrochloride, 97%
| 1822-51-1 |
|
L(+)-Lyxose, 99%, Mixture of Anomers
| 1949-78-6 |
|
|