**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1809-19-4 |Dibutyl Phosphite | 96 | 217-316-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 10 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Causes burns.Corrosive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. May be harmful if absorbed through the skin.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract. May
cause abdominal pain, nausea, vomiting, and inflammation of the gums
and mouth. Vapors may cause dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT get water inside
containers. Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers. A vapor suppressing foam may be
used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep away from heat,
sparks and flame. Do not get on skin or in eyes. Do not ingest or
inhale. Use with adequate ventilation. Do not allow contact with
water. Discard contaminated shoes. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames. Keep from contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Flammables-area.
Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1809-19-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 1 mm Hg @ 20 C
Viscosity: Not available.
Boiling Point: 118 - 119 deg C @ 11.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 49 deg C ( 120.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9950g/cm3
Molecular Formula: C8H19O3P
Molecular Weight: 194.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Mechanical shock, incompatible materials, ignition sources, moisture,
excess heat, temperatures above 50C (122F), exposure to moist air
or water.
Incompatibilities with Other Materials:
Strong acids, strong bases, strong oxidizing agents, strong reducing
agents.
Hazardous Decomposition Products:
Phosphine, carbon monoxide, oxides of phosphorus, irritating and
toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1809-19-4: HS6475000
LD50/LC50:
CAS# 1809-19-4: Inhalation, rat: LC50 = >20 gm/m3; Oral, rat: LD50 =
3200 mg/kg; Skin, rabbit: LD50 = 1990 mg/kg.
Carcinogenicity:
Dibutyl Phosphite -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 34 Causes burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 33 Take precautionary measures against static
discharges.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1809-19-4: No information available.
Canada
CAS# 1809-19-4 is listed on Canada's DSL List.
CAS# 1809-19-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1809-19-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/11/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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| 6970-57-6 |
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2-Aminonicotinic Acid, 98%
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4,4'-Bis(Dimethylamino)Thiobenzophenone, 98% (UV-VIS)
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Benzoyl chloride-d5, 99+ atom% d
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1-Propanethiol, 98%
| 107-03-9 |
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Diethyl Ethoxymethylenemalonate, 99+%
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1,2-O-Isopropylidene-D-glucofuranose, 98%
| 18549-40-1 |
|
Podophyllotoxin, 95%(tlc)
| 518-28-5 |
|
S-Acetylthiocholine Bromide, 99%
| 25025-59-6 |
|
Ethyl p-dimethylaminobenzoate, 99+%
| 10287-53-3 |
|
1,7-Octadiyne, 99%
| 871-84-1 |
|
2,3-Dichlorobenzoic acid, 98%
| 50-45-3 |
|
1,2-O-Cyclohexylidene-Alpha-D-Xylopentodi- Aldo-1,4-Furanose, 98%
| 15356-27-1 |
|
Ethylenediaminetetraacetic acid, tetrasodium salt dihydrate
| 64-02-8 |
|
2,3,5-Trichlorophenol, 99%
| 933-78-8 |
|
(2S)-(+)-Glycidyl tosylate, 99+%
| 70987-78-9 |
|
(-)-alpha-Amino-gamma-butyrolactone hydroiodide, 98%
| 171736-85-9 |
|
alpha-Methylbenzyl cyanide, tech.
| 1823-91-2 |
|
Vinylidene chloride, 99.9%, stabilized with 200 ppm MEHQ
| 75-35-4 |
|
Dibutyl Phosphite, 96%
| 1809-19-4 |
|
Sodium phosphate monobasic dihydrate
| 7558-80-7 |
|
5-Chloro-2,4-Dimethoxyaniline, 99+%
| 97-50-7 |
|
Ascarite (II)-,CO2 Absorbent, 20-to 30 Mesh
| 81133-20-2 |
|
Tri-M-Tolyl Phosphate (Pract), 93% (GC)
| 563-04-2 |
|
2,3-Epoxypropyl 4'-methoxyphenyl ether, 99%
| 2211-94-1 |
|
O-Anisoyl Chloride, 99% (Titr.)
| 21615-34-9 |
|
1-Tridecene, 99%
| 2437-56-1 |
|
Benzoylferrocene 98%
| 1272-44-2 |
|
4-Bromophenylacetic acid, 99%
| 1878-68-8 |
|
Triphenylarsine Oxide
| 1153-05-5 |
|
Copper(i) oxide, 97%
| 1317-39-1 |
|
2-Iodopropane, 98+% stabilized over copper
| 75-30-9 |
|
Glycyrrhizic Acid, Monoammonium Salt Tri-Hydrate, 98%
| 53956-04-0 |
|
Methyl (s)-(-)-4-bromo-3-tert- butyldimethylsilyloxybutanoate
| 101703-35-9 |
|
2-Fluorobenzonitrile, 99%
| 394-47-8 |
|
3-Aminophenyl-Sulfone, 97%(TLC)
| 599-61-1 |
|
Ammonium Hexafluorophosphate, 99.5%
| 16941-11-0 |
|
2-Methyl-1-phenyl-2-propanol
| 100-86-7 |
|
Aluminum Phthalocyanine Chloride, 99% (UV-Vis)
| 14154-42-8 |
|
2-Amino-6-chloro-4-pyrimidinol hydrate, 95%
| 1194-21-4 |
|
Phenyl acetate, 97%
| 122-79-2 |
|
Oligomycin, Mixture of A, B and C
| 1404-19-9 |
|
Sodium atomic absorption standard solution, 1 mg/ml Na in 0.5N HNO3
| 7440-23-5 |
|
Bromodichloromethane, 98+%, stabilized with potassium carbonate
| 75-27-4 |
|
2,2,5-Trichloropentanal, 96%
| |
|
BOC-L-Glutamic Acid-5-Benzylester DCHA, 99.5+%
| 13574-84-0 |
|
3-Nitrophenylhydrazine hydrochloride, 98%
| 636-95-3 |
|
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| 59-52-9 |
|
4,6-Dimethyl-2-Mercaptopyrimidine, 99%
| 22325-27-5 |
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| 445-28-3 |
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|