**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 75-27-4 |Dichlorobromomethane | >98 | 200-856-7 |
|----------------|--------------------------------------|----------|-----------|
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 22 40
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Limited evidence of a carcinogenic
effect.Cancer suspect agent.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
Prolonged exposure may result in dizziness and general weakness.
Causes severe irritation of upper respiratory tract with coughing,
burns, breathing difficulty, and possible coma. May cause narcotic
effects in high concentration. May be harmful if inhaled.
Chronic:
May cause cancer according to animal studies.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Substance is noncombustible.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Wash area with soap and water.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation. Use only in a chemical fume
hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 75-27-4:
CAS# 584-08-7:
Russia: 2 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: chloroform-like
pH: Not available.
Vapor Pressure: 50 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 87 deg C @ 760 mm Hg
Freezing/Melting Point: -55 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: in water: 4700 mg/l
Specific Gravity/Density: 1.9800g/cm3
Molecular Formula: CHBrCl2
Molecular Weight: 163.83
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong bases, strong oxidizing agents, magnesium.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-27-4: PA5310000
CAS# 584-08-7: TS7750000
LD50/LC50:
CAS# 75-27-4: Oral, mouse: LD50 = 450 mg/kg; Oral, rat: LD50 = 430
mg/kg.
CAS# 584-08-7: Oral, mouse: LD50 = 2570 mg/kg; Oral, rat: LD50 =
1870 mg/kg.
Carcinogenicity:
Dichlorobromomethane -
California: carcinogen, initial date 1/1/90
NTP: Suspect carcinogen
IARC: Group 2B carcinogen
Potassium carbonate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
log Pow: 2.10
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
USA RQ: CAS# 75-27-4: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 75-27-4: No information available.
CAS# 584-08-7: 1
Canada
CAS# 75-27-4 is listed on Canada's NDSL List.
CAS# 584-08-7 is listed on Canada's DSL List.
CAS# 75-27-4 is listed on Canada's Ingredient Disclosure List.
CAS# 584-08-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-27-4 is listed on the TSCA inventory.
CAS# 584-08-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 35 Causes severe burns.
R 8 Contact with combustible material may cause fire.
MSDS Creation Date: 9/02/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Ethyl-3-methylglutaric anhydride, 97%
| 6970-57-6 |
|
2-Aminonicotinic Acid, 98%
| 5345-47-1 |
|
4,4'-Bis(Dimethylamino)Thiobenzophenone, 98% (UV-VIS)
| 1226-46-6 |
|
Benzoyl chloride-d5, 99+ atom% d
| 43019-90-5 |
|
1-Propanethiol, 98%
| 107-03-9 |
|
Diethyl Ethoxymethylenemalonate, 99+%
| 87-13-8 |
|
1,2-O-Isopropylidene-D-glucofuranose, 98%
| 18549-40-1 |
|
Podophyllotoxin, 95%(tlc)
| 518-28-5 |
|
S-Acetylthiocholine Bromide, 99%
| 25025-59-6 |
|
Ethyl p-dimethylaminobenzoate, 99+%
| 10287-53-3 |
|
1,7-Octadiyne, 99%
| 871-84-1 |
|
2,3-Dichlorobenzoic acid, 98%
| 50-45-3 |
|
1,2-O-Cyclohexylidene-Alpha-D-Xylopentodi- Aldo-1,4-Furanose, 98%
| 15356-27-1 |
|
Ethylenediaminetetraacetic acid, tetrasodium salt dihydrate
| 64-02-8 |
|
2,3,5-Trichlorophenol, 99%
| 933-78-8 |
|
(2S)-(+)-Glycidyl tosylate, 99+%
| 70987-78-9 |
|
(-)-alpha-Amino-gamma-butyrolactone hydroiodide, 98%
| 171736-85-9 |
|
alpha-Methylbenzyl cyanide, tech.
| 1823-91-2 |
|
Vinylidene chloride, 99.9%, stabilized with 200 ppm MEHQ
| 75-35-4 |
|
Dibutyl Phosphite, 96%
| 1809-19-4 |
|
Sodium phosphate monobasic dihydrate
| 7558-80-7 |
|
5-Chloro-2,4-Dimethoxyaniline, 99+%
| 97-50-7 |
|
Ascarite (II)-,CO2 Absorbent, 20-to 30 Mesh
| 81133-20-2 |
|
Tri-M-Tolyl Phosphate (Pract), 93% (GC)
| 563-04-2 |
|
2,3-Epoxypropyl 4'-methoxyphenyl ether, 99%
| 2211-94-1 |
|
O-Anisoyl Chloride, 99% (Titr.)
| 21615-34-9 |
|
1-Tridecene, 99%
| 2437-56-1 |
|
Benzoylferrocene 98%
| 1272-44-2 |
|
4-Bromophenylacetic acid, 99%
| 1878-68-8 |
|
Triphenylarsine Oxide
| 1153-05-5 |
|
Copper(i) oxide, 97%
| 1317-39-1 |
|
2-Iodopropane, 98+% stabilized over copper
| 75-30-9 |
|
Glycyrrhizic Acid, Monoammonium Salt Tri-Hydrate, 98%
| 53956-04-0 |
|
Methyl (s)-(-)-4-bromo-3-tert- butyldimethylsilyloxybutanoate
| 101703-35-9 |
|
2-Fluorobenzonitrile, 99%
| 394-47-8 |
|
3-Aminophenyl-Sulfone, 97%(TLC)
| 599-61-1 |
|
Ammonium Hexafluorophosphate, 99.5%
| 16941-11-0 |
|
2-Methyl-1-phenyl-2-propanol
| 100-86-7 |
|
Aluminum Phthalocyanine Chloride, 99% (UV-Vis)
| 14154-42-8 |
|
2-Amino-6-chloro-4-pyrimidinol hydrate, 95%
| 1194-21-4 |
|
Phenyl acetate, 97%
| 122-79-2 |
|
Oligomycin, Mixture of A, B and C
| 1404-19-9 |
|
Sodium atomic absorption standard solution, 1 mg/ml Na in 0.5N HNO3
| 7440-23-5 |
|
Bromodichloromethane, 98+%, stabilized with potassium carbonate
| 75-27-4 |
|
2,2,5-Trichloropentanal, 96%
| |
|
BOC-L-Glutamic Acid-5-Benzylester DCHA, 99.5+%
| 13574-84-0 |
|
3-Nitrophenylhydrazine hydrochloride, 98%
| 636-95-3 |
|
2,3-Dimercapto-1-propanol, 93% (GC)
| 59-52-9 |
|
4,6-Dimethyl-2-Mercaptopyrimidine, 99%
| 22325-27-5 |
|
2-Fluorobenzamide, 98%
| 445-28-3 |
|
|