**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 933-78-8 |2,3,5-Trichlorophenol | 99 | 213-272-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause liver and kidney damage. May cause cardiac
disturbances. May cause methemoglobinemia, cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood),
convulsions, and death. May cause central nervous system effects.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation. May cause
methemoglobinemia, cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood), convulsions, tachycardia,
dyspnea (labored breathing), and death. May cause liver and kidney
damage. May cause cardiac abnormalities.
Chronic:
May cause liver and kidney damage. May cause methemoglobinemia,
which is characterized by chocolate-brown colored blood, headache,
weakness, dizziness, breath shortness, cyanosis (bluish skin due to
deficient oxygenation of blood), rapid heart rate, unconsciousness
and possible death.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively. For methemoglobinemia,
administer oxygen alone or with Methylene Blue depending on the
methemoglobin concentration in the blood.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Containers
may explode in the heat of a fire. Runoff from fire control or
dilution water may cause pollution.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, or water spray.
For large fires, use dry chemical, carbon dioxide, alcohol-resistant
foam, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Sweep up, then place into a suitable
container for disposal. Avoid generating dusty conditions. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation. Wash clothing before reuse.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use adequate
general or local exhaust ventilation to keep airborne concentrations
below the permissible exposure limits. Use process enclosure, local
exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 933-78-8:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles. Wear safety glasses and
chemical goggles if splashing is possible. Wear
appropriate protective eyeglasses or chemical safety
goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Wear a NIOSH/MSHA
or European Standard EN 149 approved full-facepiece
airline respirator in the positive pressure mode with
emergency escape provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Chunks
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 248-249 deg C
Freezing/Melting Point: 57-60 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H3Cl3O
Molecular Weight: 197.45
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 933-78-8: SN1295000
LD50/LC50:
Not available.
Carcinogenicity:
2,3,5-Trichlorophenol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CHLOROPHENOLS, SOLID
Hazard Class: 6.1
UN Number: 2020
Packing Group: III
IMO
Shipping Name: CHLOROPHENOLS, SOLID
Hazard Class: 6.1
UN Number: 2020
Packing Group: III
RID/ADR
Shipping Name: CHLOROPHENOLS, SOLID
Hazard Class: 6.1
UN Number: 2020
Packing group: III
USA RQ: CAS# 933-78-8: 10 lb final RQ (Listed under Trichlorophenol); 4.54 kg fi
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/39 Wear suitable protective clothing and
eye/face protection.
WGK (Water Danger/Protection)
CAS# 933-78-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 933-78-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 933-78-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/19/1998 Revision #6 Date: 4/18/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Ethyl-3-methylglutaric anhydride, 97%
| 6970-57-6 |
|
2-Aminonicotinic Acid, 98%
| 5345-47-1 |
|
4,4'-Bis(Dimethylamino)Thiobenzophenone, 98% (UV-VIS)
| 1226-46-6 |
|
Benzoyl chloride-d5, 99+ atom% d
| 43019-90-5 |
|
1-Propanethiol, 98%
| 107-03-9 |
|
Diethyl Ethoxymethylenemalonate, 99+%
| 87-13-8 |
|
1,2-O-Isopropylidene-D-glucofuranose, 98%
| 18549-40-1 |
|
Podophyllotoxin, 95%(tlc)
| 518-28-5 |
|
S-Acetylthiocholine Bromide, 99%
| 25025-59-6 |
|
Ethyl p-dimethylaminobenzoate, 99+%
| 10287-53-3 |
|
1,7-Octadiyne, 99%
| 871-84-1 |
|
2,3-Dichlorobenzoic acid, 98%
| 50-45-3 |
|
1,2-O-Cyclohexylidene-Alpha-D-Xylopentodi- Aldo-1,4-Furanose, 98%
| 15356-27-1 |
|
Ethylenediaminetetraacetic acid, tetrasodium salt dihydrate
| 64-02-8 |
|
2,3,5-Trichlorophenol, 99%
| 933-78-8 |
|
(2S)-(+)-Glycidyl tosylate, 99+%
| 70987-78-9 |
|
(-)-alpha-Amino-gamma-butyrolactone hydroiodide, 98%
| 171736-85-9 |
|
alpha-Methylbenzyl cyanide, tech.
| 1823-91-2 |
|
Vinylidene chloride, 99.9%, stabilized with 200 ppm MEHQ
| 75-35-4 |
|
Dibutyl Phosphite, 96%
| 1809-19-4 |
|
Sodium phosphate monobasic dihydrate
| 7558-80-7 |
|
5-Chloro-2,4-Dimethoxyaniline, 99+%
| 97-50-7 |
|
Ascarite (II)-,CO2 Absorbent, 20-to 30 Mesh
| 81133-20-2 |
|
Tri-M-Tolyl Phosphate (Pract), 93% (GC)
| 563-04-2 |
|
2,3-Epoxypropyl 4'-methoxyphenyl ether, 99%
| 2211-94-1 |
|
O-Anisoyl Chloride, 99% (Titr.)
| 21615-34-9 |
|
1-Tridecene, 99%
| 2437-56-1 |
|
Benzoylferrocene 98%
| 1272-44-2 |
|
4-Bromophenylacetic acid, 99%
| 1878-68-8 |
|
Triphenylarsine Oxide
| 1153-05-5 |
|
Copper(i) oxide, 97%
| 1317-39-1 |
|
2-Iodopropane, 98+% stabilized over copper
| 75-30-9 |
|
Glycyrrhizic Acid, Monoammonium Salt Tri-Hydrate, 98%
| 53956-04-0 |
|
Methyl (s)-(-)-4-bromo-3-tert- butyldimethylsilyloxybutanoate
| 101703-35-9 |
|
2-Fluorobenzonitrile, 99%
| 394-47-8 |
|
3-Aminophenyl-Sulfone, 97%(TLC)
| 599-61-1 |
|
Ammonium Hexafluorophosphate, 99.5%
| 16941-11-0 |
|
2-Methyl-1-phenyl-2-propanol
| 100-86-7 |
|
Aluminum Phthalocyanine Chloride, 99% (UV-Vis)
| 14154-42-8 |
|
2-Amino-6-chloro-4-pyrimidinol hydrate, 95%
| 1194-21-4 |
|
Phenyl acetate, 97%
| 122-79-2 |
|
Oligomycin, Mixture of A, B and C
| 1404-19-9 |
|
Sodium atomic absorption standard solution, 1 mg/ml Na in 0.5N HNO3
| 7440-23-5 |
|
Bromodichloromethane, 98+%, stabilized with potassium carbonate
| 75-27-4 |
|
2,2,5-Trichloropentanal, 96%
| |
|
BOC-L-Glutamic Acid-5-Benzylester DCHA, 99.5+%
| 13574-84-0 |
|
3-Nitrophenylhydrazine hydrochloride, 98%
| 636-95-3 |
|
2,3-Dimercapto-1-propanol, 93% (GC)
| 59-52-9 |
|
4,6-Dimethyl-2-Mercaptopyrimidine, 99%
| 22325-27-5 |
|
2-Fluorobenzamide, 98%
| 445-28-3 |
|
|