**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2937-50-0 |Allyl chloroformate | 97 | 220-916-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T C
Risk Phrases: 10 22 23 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful if swallowed. Toxic by inhalation. Causes
burns.Moisture sensitive.Corrosive.Lachrymator (substance which
increases the flow of tears).
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause cyanosis of the extremities. May cause
skin rash (in milder cases), and cold and clammy skin with cyanosis
or pale color.
Ingestion:
Harmful if swallowed. May cause severe and permanent damage to the
digestive tract. Causes gastrointestinal tract burns. May cause
perforation of the digestive tract. Ingestion of large amounts may
cause CNS depression.
Inhalation:
May be fatal if inhaled. Causes chemical burns to the respiratory
tract. Inhalation may be fatal as a result of spasm, inflammation,
edema of the larynx and bronchi, chemical pneumonitis and pulmonary
edema. Vapors may cause dizziness or suffocation. May cause burning
sensation, coughing, wheezing, laryngitis, shortness of breath,
headache, nausea, and vomiting.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water. May cause
methemoglobinemia, cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood), convulsions, and death. Induce
vomiting only when instructed to do so by a physician.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. Do not use mouth-to-mouth resuscitation if victim
ingested or inhaled the substance; induce artificial respiration with
the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas. Runoff from fire control or
dilution water may cause pollution.
Extinguishing Media:
Do NOT use water directly on fire. Use water spray to cool
fire-exposed containers. Use foam, dry chemical, or carbon dioxide.
Water may be ineffective. Do NOT get water inside containers. In case
of fire, use carbon dioxide, dry chemical powder or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers. A vapor suppressing foam may be
used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Ground and
bond containers when transferring material. Use spark-proof tools and
explosion proof equipment. Do not get in eyes, on skin, or on
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Do not get on skin or in eyes. Do
not ingest or inhale. Use with adequate ventilation. Do not allow
contact with water. Discard contaminated shoes. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers
to heat, sparks or open flames. Keep from contact with moist air and
steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use.
Refrigerator/flammables. Store protected from moisture. Vent
periodically.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 2937-50-0:
Russia: 0.4 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: clear, colorless
Odor: pungent odor
pH: Not available.
Vapor Pressure: 20 mmHg @ 25 C
Viscosity: 0.71 mPa-s@20 deg C
Boiling Point: 109 - 110 deg C @ 760.00mm Hg
Freezing/Melting Point: -80 deg C
Autoignition Temperature: Not applicable.
Flash Point: 31 deg C ( 87.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: decomposes
Specific Gravity/Density: 1.1360g/cm3
Molecular Formula: C4H5ClO2
Molecular Weight: 120.54
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on
exposure to moist air or water.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, strong bases, alcohols, amines,
moisture, water.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide,
chloride fumes, chloroformic acid, allyl alcohol.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2937-50-0: LQ5775000
LD50/LC50:
CAS# 2937-50-0: Inhalation, mouse: LC50 = 23100 ug/m3; Inhalation,
rat: LC50 = 32400 ug/m3; Oral, mouse: LD50 = 210 mg/kg; Oral, rat:
LD50 = 244 mg/kg.
Carcinogenicity:
Allyl chloroformate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALLYL CHLOROFORMATE
Hazard Class: 6.1 (3)
UN Number: 1722
Packing Group:
IMO
Shipping Name: ALLYL CHLOROFORMATE
Hazard Class: 6.1 (3)
UN Number: 1722
Packing Group: I
RID/ADR
Shipping Name: ALLYL CHLOROFORMATE
Hazard Class: 6.1
UN Number: 1722
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T C
Risk Phrases:
R 10 Flammable.
R 22 Harmful if swallowed.
R 23 Toxic by inhalation.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 2937-50-0: No information available.
Canada
CAS# 2937-50-0 is listed on Canada's NDSL List.
CAS# 2937-50-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2937-50-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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| 120-20-7 |
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2-Bromo-9-Fluorenone, 95%
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|
Potassium trihydrogen dioxalate dihydrate, 99%
| 6100-20-5 |
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2-Chloromethyl-5-(4-Methoxyphenyl)-1,2,4-Oxadiazole, 98%
| 24023-71-0 |
|
2-Chloromethyl-5-(4-Chlorophenyl)-1,2,4-Oxadiazole, 98%
| 24068-15-3 |
|
Tetramethylgermanium, 97%
| 865-52-1 |
|
Phenyltosylate
| 640-60-8 |
|
Tetra-n-butylammonium hexafluorophosphate, 98%
| 3109-63-5 |
|
4-Methyl-2-nitrophenol, 99%
| 119-33-5 |
|
Tetraphenylgermanium, 97%
| 1048-05-1 |
|
2,3-Dibromopropionic Acid, 99%
| 600-05-5 |
|
Magnesium trifluoromethanesulfonate, 98%
| 60871-83-2 |
|
Tetraethyl orthocarbonate, 97%
| 78-09-1 |
|
N-(8-Bromooctyl)phthalimide
| 17702-83-9 |
|
4-Chloro-2-nitrophenol, 98%
| 89-64-5 |
|
cis-N-(4-Chlorobutenyl)Phthalimide, 97%
| 84347-67-1 |
|
4-Fluoro-o-xylene, 98%
| 452-64-2 |
|
2-Phenylglutaric anhydride, 97%
| 2959-96-8 |
|
Methyl tiglate, 98%
| 6622-76-0 |
|
Lobeline sulfate, 99%
| 134-64-5 |
|
Methyl triphenylarsonium iodide, 98%
| 1499-33-8 |
|
Hexa-n-butylditin, 98%
| 813-19-4 |
|
Hydrocortisone, 98%
| 50-23-7 |
|
Benzylurea, 93%
| 538-32-9 |
|
Dichloromethane, peptide synthesis grade, stabilized
| 75-09-2 |
|
N,N-Dicyclohexylcarbodiimide, 0.1M solution in dichloromethane,
| 75-09-2 |
|
N,N'-Dicyclohexylcarbodiimide, 1M solution in N-methylpyrrolidone,
| 538-75-0 |
|
N,N-Dimethylformamide, peptide synthesis grade
| 68-12-2 |
|
1,1,1,3,3,3-Hexafluoro-2-propanol, peptide synthesis grade
| 920-66-1 |
|
alpha,alpha,alpha',alpha',-Tetrachloro-p-xylene
| 7398-82-5 |
|
Bromine Water
| 7726-95-6 |
|
1,1,1,3,3,3-Hexafluoro-2-propanol, 10% in dichloromethane, peptide
| 75-09-2 |
|
1-Methyl-2-pyrrolidone, special automatic peptide synthesizer grade
| 872-50-4 |
|
N-Methylpyrrolidone, peptide synthesis grade
| 872-50-4 |
|
Methylsulfoxide, peptide synthesis grade
| 67-68-5 |
|
Ferrocene, 98%
| 102-54-5 |
|
1,2-Diiodotetrafluoroethane, 98%
| 354-65-4 |
|
5-Chlorothiophene-2-carboxylic acid, 98%
| 24065-33-6 |
|
trans-4-Methoxycinnamaldehyde, 98%
| 24680-50-0 |
|
trans-2-Methyl-2-butenal
| 497-03-0 |
|
Ethyl 3-phenylpropionate, 98%
| 2021-28-5 |
|
Allyl chloroformate, 97%
| 2937-50-0 |
|
2-Amino-3,3-dimethylbutane, 98%
| 3850-30-4 |
|
4-Tert-Butylbenzonitrile, 98%
| 4210-32-6 |
|
3-Aminopropionitrile, stabilized, 98%
| 151-18-8 |
|
4-Chlorophenylsulfonylacetonitrile, 98%
| 1851-09-8 |
|
p-Toluenesulfonylacetonitrile, 98%
| 5697-44-9 |
|
Methyl thiophene-2-carboxylate, 98%
| 5380-42-7 |
|
n-Amylbenzoate, 98%
| 2049-96-9 |
|
Isosorbide, 98%
| 652-67-5 |
|
|