**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3012-65-5 |Ammonium Citrate Dibasic | 100 | 221-146-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause cataracts and atrophy of the
retina and iris. May cause severe and immediate pain followed by
conjunctival edema and corneal clouding.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood). Causes respiratory tract irritation.
Inhalation of high concentrations can cause swelling of the lips and
conjunctiva, temporary blindness, chest tightness, rapid and weak
pulse, and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Absorption of this product into the body may cause cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood).
Moderate degrees of cyanosis need to be treated only by supportive
measures: bed rest and oxygen inhalation. For methemoglobinemia,
administer oxygen alone or with Methylene Blue depending on the
methemoglobin concentration in the blood. Cleansing of the entire
contaminated area of the body is of utmost importance.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Runoff from
fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use with adequate ventilation. Minimize dust generation and
accumulation. Avoid contact with skin and eyes. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 3012-65-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: ammonia-like - weak odor
pH: 4.8-5.3 (5% soln)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Decomposes.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 1.5
Molecular Formula: (NH4)2C6H6O7
Molecular Weight: 226.1072
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizers.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, nitrogen oxides (NOx) and ammonia
(NH3).
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3012-65-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ammonium Citrate Dibasic -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
USA RQ: CAS# 3012-65-5: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 3012-65-5: 1
Canada
CAS# 3012-65-5 is listed on Canada's DSL List.
CAS# 3012-65-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3012-65-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/07/2001 Revision #2 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N,N-Dimethylformamide, for HPLC
| 68-12-2 |
|
Water, for HPLC
| 7732-18-5 |
|
Acetone, for HPLC
| 67-64-1 |
|
Acetone, Histological
| 67-64-1 |
|
3-Hydroxy-4-Methoxybenzoic Acid, 99%
| 645-08-9 |
|
Fluorolube Grease, GR-362
| 9002-83-9 |
|
Fluorolube Grease, GR-290
| 9002-83-9 |
|
para-Naphtholbenzein indicator solution
| 67-63-0 |
|
LB Broth, Miller
| |
|
Gelatin, Type A
| 9000-70-8 |
|
Hydrazine, Anhydrous
| 302-01-2 |
|
Lithium Hydroxide, Anhydrous
| 554-13-2 |
|
Bovine Serum Albumin, Lyophilized Powder
| 9048-46-8 |
|
Urease
| 9002-13-5 |
|
Sodium m-arsenite
| 7784-46-5 |
|
Rexyn I-300 (H-OH) Beads
| 69011-49-0 |
|
Silicic Acid
| 7699-41-4 |
|
Cadmium, Granular
| 7440-43-9 |
|
Cytoscint, Scintillation Cocktail
| 92-71-7 |
|
2-Ethylanthraquinone, 97+%
| 84-51-5 |
|
Thioacetanilide, 99+%
| 637-53-6 |
|
Malachite Green
| 569-64-2 |
|
Ammonium Citrate Dibasic, 98%
| 3012-65-5 |
|
Aphidicolin
| 38966-21-1 |
|
Nickel (II) Ammonium Sulfate Hexahydrate
| 7785-20-8 |
|
Bath Wax
| 68334-00-9 |
|
Palladium (II) Chloride Solution 5%
| 7647-01-0 |
|
Universal pH Indicator Solution
| 67-56-1 |
|
Phenylarsine oxide solution, 0.025N
| 637-03-6 |
|
Fluoroboric Acid, 48-50% Solution
| 7732-18-5 |
|
Methyl Orange, 0.1% W/V Solution
| 547-58-0 |
|
Potassium Hydroxide, 0.1N Solution in Isopropanol
| 67-63-0 |
|
Schiff's Reagent Solution
| 632-99-5 |
|
Potassium Hydroxide, 0.1N Solution in Methanol
| 67-56-1 |
|
Casamino acids, powder
| 65072-00-6 |
|
1,4-Pentanediol, 99%
| 626-95-9 |
|
L-Penicillamine
| 1113-41-3 |
|
Manganese(II) acetate tetrahydrate
| 638-38-0 |
|
Potassium Tartrate Hemihydrate
| 6100-19-2 |
|
Carbon, Lampblack
| 1333-86-4 |
|
Geimsa Stain
| 51811-82-6 |
|
Ampicilin Trihydrate
| 7177-48-2 |
|
Chlorine Water
| 7732-18-5 |
|
Denhardt's Solution
| 7732-18-5 |
|
Cobalt powder 300 mesh 98%
| 7440-48-4 |
|
Iron (III) Ammonium Citrate
| 1185-57-5 |
|
2-Hydroxyethyl disulfide, 95%
| 1892-29-1 |
|
Indophenol Sodium Salt, 95% (UV-Vis)
| 5418-32-6 |
|
Potassium Iodide Solution, alkaline
| 1310-73-2 |
|
Lead(II) chromate, granules, 12 to 20 mesh.
| 7758-97-6 |
|
|