**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 67-56-1 |Methyl alcohol | 92.5-99. | 200-659-6 |
|----------------|--------------------------------------|----------|-----------|
| 1310-58-3 |Potassium hydroxide | 0.75-7.5 | 215-181-3 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 0.6-6 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: F C
Risk Phrases: 10 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Causes severe burns.Corrosive.
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Contact may cause ulceration of the conjunctiva and cornea. Eye
damage may be delayed. May cause painful sensitization to light.
Vapors may cause eye irritation.
Skin:
Causes skin burns. May be absorbed through the skin in harmful
amounts.
Ingestion:
May be fatal or cause blindness if swallowed. May cause systemic
toxicity with acidosis. May cause liver and kidney damage. May cause
central nervous system depression, characterized by excitement,
followed by headache, dizziness, drowsiness, and nausea. Advanced
stages may cause collapse, unconsciousness, coma and possible death
due to respiratory failure. May cause perforation of the digestive
tract. Causes severe digestive tract burns with abdominal pain,
vomiting, and possible death.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema.
Causes severe irritation of upper respiratory tract with coughing,
burns, breathing difficulty, and possible coma. May cause visual
impairment and possible permanent blindness. May cause drowsiness,
unconsciousness, and central nervous system depression.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic
inhalation and ingestion may cause effects similar to those of acute
inhalation and ingestion.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Effects may be delayed. Ethanol may inhibit methanol metabolism.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire.
Vapors can travel to a source of ignition and flash back. Flammable
Liquid. Can release vapors that form explosive mixtures at
temperatures above the flashpoint. Use water spray to keep
fire-exposed containers cool. Wear appropriate protective clothing to
prevent contact with skin and eyes. Wear a self-contained breathing
apparatus (SCBA) to prevent contact with thermal decomposition
products. Vapors may be heavier than air. They can spread along the
ground and collect in low or confined areas. Vapors may form an
explosive mixture with air. Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water. For large fires, use dry chemical, carbon dioxide,
alcohol-resistant foam, or water spray. Cool containers with
flooding quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Absorb spill using an absorbent, non-combustible material such as
earth, sand, or vermiculite. Do not use combustible materials such
as sawdust. A vapor suppressing foam may be used to reduce vapors.
Use water spray to reduce vapors, do not put water directly on leak,
spill area or inside container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Take precautionary measures against static discharges.
Keep container tightly closed. Keep away from heat, sparks and flame.
Do not ingest or inhale. Use only in a chemical fume hood. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits. Use only under a chemical fume hood.
Exposure Limits
CAS# 67-56-1:
United Kingdom, WEL - TWA: 200 ppm TWA; 266 mg/m3 TWA
United Kingdom, WEL - STEL: 250 ppm STEL; 333 mg/m3 STEL
United States OSHA: 200 ppm TWA; 260 mg/m3 TWA
Belgium - TWA: 200 ppm VLE; 266 mg/m3 VLE
Belgium - STEL: 250 ppm VLE; 333 mg/m3 VLE
France - VME: 200 ppm VME; 260 mg/m3 VME
France - VLE: 1000 ppm VLE; 1300 mg/m3 VLE
Germany: 200 ppm TWA; 270 mg/m3 TWA
Germany: Skin absorber
Japan: 200 ppm OEL; 260 mg/m3 OEL
Malaysia: 200 ppm TWA; 262 mg/m3 TWA
Netherlands: 200 ppm MAC; 260 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 200 ppm VLA-ED; 266 mg/m3 VLA-ED
Spain: 250 ppm VLA-EC; 333 mg/m3 VLA-EC
CAS# 1310-58-3:
United Kingdom, WEL - STEL: 2 mg/m3 STEL
Belgium - STEL: 2 mg/m3 VLE
France - VLE: 2 mg/m3 VLE
Japan: 2 mg/m3 Ceiling
Malaysia: 2 mg/m3 Ceiling
Spain: 2 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: alcohol-like - weak odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 151 deg F
Freezing/Melting Point: -148 deg F
Autoignition Temperature: Not applicable.
Flash Point: 52 deg F ( 11.11 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Completely soluble in water.
Specific Gravity/Density: 0.8
Molecular Formula: Mixture
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, acids,
metals.
Incompatibilities with Other Materials:
Acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric
acid, muriatic acid, phosphoric acid), acids (mineral, oxidizing,
e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid),
acids (organic, e.g. acetic acid, benzoic acid, formic acid,
methanoic acid, oxalic acid), aldehydes (e.g. acetaldehyde, acrolein,
chloral hydrate, formaldehyde), azo, diazo, and hydrazines (e.g.
dimethyl hydrazine, hydrazine, methyl hydrazine), carbamates (e.g.
carbanolate, carbofuran), esters (e.g. butyl acetate, ethyl acetate,
propyl formate), halogenated organics (e.g. dibromoethane,
hexachlorobenzene, methyl chloride, trichloroethylene), isocyanates
(e.g. methyl isocyanate), ketones (e.g. acetone, acetophenone, MEK,
MIBK), metals (alkali and alkaline, e.g. cesium, potassium, sodium),
metals as powders (e.g. hafnium, raney nickel), metals and metal
compounds (toxic, e.g. beryllium, lead acetate, nickel carbonyl,
tetraethyl lead), nitrides (e.g. potassium nitride, sodium nitride),
nitri.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, oxides of potassium, formaldehyde.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-56-1: PC1400000
CAS# 1310-58-3: TT2100000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test,
rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20
mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H;
Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300
mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600
mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 1310-58-3: Draize test, rabbit, skin: 50 mg/24H Severe; Oral,
rat: LD50 = 273 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Methyl alcohol -
Not listed by ACGIH, IARC, or NTP.
Potassium hydroxide -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50 = 13-68 mg/L; 96 Hr.; 12 degrees CFish:
Fathead Minnow: LC50 = 29400 mg/L; 96 Hr.; 25 degrees C, pH 7.63Fish:
Rainbow trout: LC50 = 8000 mg/L; 48 Hr.; UnspecifiedBacteria:
Phytobacterium phosphoreum: EC50 = 51,000-320,000 mg/L; 30 minutes;
Microtox testMethyl alcohol: Goldfish (fresh water), 250 ppm/11H,
death. Aquatic toxicity rating: TLm 96 >1000 ppm.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
USA RQ: CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ
USA RQ: CAS# 1310-58-3: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 10 Flammable.
R 35 Causes severe burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 28B After contact with skin, wash immediately with
plenty of water and soap.
WGK (Water Danger/Protection)
CAS# 67-56-1: 1
CAS# 1310-58-3: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 67-56-1 is listed on Canada's DSL List.
CAS# 1310-58-3 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 67-56-1 is listed on Canada's Ingredient Disclosure List.
CAS# 1310-58-3 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 1310-58-3 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin and
if swallowed.
R 39/23/24/25 Toxic : danger of very serious irreversible
effects through inhalation, in contact with skin and if swallowed.
MSDS Creation Date: 11/08/2001 Revision #2 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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