**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 92-71-7 |2,5-diphenyl-oxazole | <0.1 | 202-181-3 |
|----------------|--------------------------------------|----------|-----------|
| 95-63-6 |Pseudocumene | 75-90 | 202-436-9 |
|----------------|--------------------------------------|----------|-----------|
| 111-27-3 |N-hexanol | 2-10 | 203-852-3 |
|----------------|--------------------------------------|----------|-----------|
| Not avai. |Phosphated alkyl ethoxylate | 10-20 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 20/21 38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation and in contact with skin.
Irritating to skin.
Potential Health Effects
Eye:
Causes eye irritation. Causes redness and pain. May cause
irritation of the conjunctiva.
Skin:
Causes skin irritation. May be absorbed through the skin. Causes
redness and pain.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system depression, characterized
by excitement, followed by headache, dizziness, drowsiness, and
nausea. Advanced stages may cause collapse, unconsciousness, coma
and possible death due to respiratory failure.
Inhalation:
Prolonged exposure may result in dizziness and general weakness. May
cause drowsiness, unconsciousness, and central nervous system
depression. Vapors may cause dizziness or suffocation. Causes
irritation of the mucous membrane and upper respiratory tract.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. Repeated inhalation may cause chronic bronchitis. May
cause anemia and other blood cell abnormalities. Prolonged exposure
may produce a narcotic effect. Prolonged or repeated exposure may
cause nausea, dizziness, and headache. Laboratory experiments have
resulted in mutagenic effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Water may be ineffective. Material is lighter than
water and a fire may be spread by the use of water. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. This material is lighter than
water and insoluble in water. The fire could easily be spread by the
use of water in an area where the water cannot be contained. Do NOT
use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Ground and
bond containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid breathing dust, vapor, mist, or gas.
Avoid contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Take
precautionary measures against static discharges. Keep container
tightly closed. Avoid contact with heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from heat and
flame. Keep away from sources of ignition. Store in a tightly closed
container. Keep from contact with oxidizing materials. Store in a
cool, dry, well-ventilated area away from incompatible substances.
Keep away from strong acids. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR ??1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Appearance: clear, colorless
Odor: pleasant odor - aromatic odor
pH: Not available.
Vapor Pressure: 7 mm Hg @112F
Viscosity: Not available.
Boiling Point: 168 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: 514 deg C ( 957.20 deg F)
Flash Point: 48.88 deg C ( 119.98 deg F)
Explosion Limits, lower: 0.90 vol %
Explosion Limits, upper: 6.4 vol %
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: 0.880
Molecular Formula: Mixture
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, nitric acid.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 92-71-7: RP6825000
CAS# 95-63-6: DC3325000
CAS# 111-27-3: MQ4025000
CAS# Not avai. unlisted.
LD50/LC50:
Not available.
CAS# 95-63-6: Inhalation, rat: LC50 = 18 gm/m3/4H; Oral, rat: LD50 =
5 gm/kg.
CAS# 111-27-3: Oral, mouse: LD50 = 1950 mg/kg; Oral, rat: LD50 = 720
mg/kg; Skin, rabbit: LD50 = 3100 uL/kg.
Carcinogenicity:
2,5-diphenyl-oxazole -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Pseudocumene -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
N-hexanol -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Phosphated alkyl ethoxylate -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Fathead Minnow: LC50 = 77.2 mg/L; 96 Hr; CAS# 95-63-6:
Flow-through at 25 C (pH 7.24)CAS# 95-63-6: Estimated Koc value =
720. 1,2,4-trimethylbenzene will have low mobility in soil.
Volatilization from moist and dry soil surfaces is expected to
occur. 1,2,4-Trimethylbenzene is expected to aerobically biodegrade
in both soil and water. Anaerobic aquifer microcosms did not show
significant biodegradation in comparison to poisoned controls. In
water, 1,2,4-trimethylbenzene may adsorb to sediment or particulate
matter.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Dangerous Goods Code:
UN Number:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20/21 Harmful by inhalation and in contact with
skin.
R 38 Irritating to skin.
Safety Phrases:
S50A Do not mix with acids.
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 92-71-7: No information available.
CAS# 95-63-6: 3
CAS# 111-27-3: 1
CAS# Not avai.: No information available.
United Kingdom Occupational Exposure Limits
Canada
CAS# 92-71-7 is listed on Canada's DSL List.
CAS# 95-63-6 is listed on Canada's DSL List.
CAS# 111-27-3 is listed on Canada's DSL List.
CAS# 92-71-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 95-63-6 is listed on Canada's Ingredient Disclosure List.
CAS# 111-27-3 is listed on Canada's Ingredient Disclosure List.
CAS# Not avai. is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 95-63-6: Not available.
US FEDERAL
TSCA
CAS# 92-71-7 is listed on the TSCA inventory.
CAS# 95-63-6 is listed on the TSCA inventory.
CAS# 111-27-3 is listed on the TSCA inventory.
CAS# Not avai. is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/07/2001 Revision #1 Date: 11/07/2001
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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