**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7647-01-0 |Hydrochloric acid | 0.45 | 231-595-7 |
|----------------|--------------------------------------|----------|-----------|
| 7647-10-1 |Palladium chloride | 5.0 | 231-596-2 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 98.3 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes severe eye burns.
Skin:
Causes severe burns.
Ingestion:
Causes gastrointestinal tract burns. May cause liver damage. May
cause corrosion and permanent tissue destruction of the esophagus and
digestive tract.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Discard contaminated clothing in a manner which
limits further exposure. Destroy contaminated shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure to fresh air immediately. If breathing is
difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get in eyes,
on skin, or on clothing. Do not ingest or inhale.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR ??1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Appearance: yellow
Odor: none reported
pH: <1.0
Vapor Pressure: 14 mm Hg @20C
Viscosity: Not available.
Boiling Point: 212 deg F
Freezing/Melting Point: 32 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 1.0
Molecular Formula: Mixture
Molecular Weight: Not available
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene
glycol), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate,
formaldehyde), amides (e.g. butyramide, diethyltoluamide, dimethyl
formamide), amines (aliphatic and aromatic, e.g. dimethyl amine,
propylamine, pyridine, triethylamine), azo, diazo, and hydrazines
(e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), carbamates
(e.g. carbanolate, carbofuran), caustics (e.g. ammonia, ammonium
hydrozide, calcium hydroxide, potassium hydroxide, sodium hydroxide),
cyanides (e.g. potassium cyanide, sodium cyanide), dithiocarbamates
(e.g. ferbam, maneb, metham, thiram), esters (e.g. butyl acetate,
ethyl acetate, propyl formate), ethers (e.g. dioxane, furfuran,
tetrahydrofuran (THF)), fluorides (inorganic, e.g. ammonium fluoride,
calcium fluoride, cesium fluoride), halogenated organics (e.g.
dibromoethane, hexachlorobenzene, methyl chloride,
trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones
(e.g. acetone, acetophenone, MEK, MIBK), mercaptans and other organic
sulfides (e.g. butyl mercaptan, carbon disulfide, methanethiol),
metals (alkali and alkaline, e.g. cesium, potassium, sodium), metals
as powders (e.g. hafnium, raney nickel), metals as non-powders (e.g.
brass, bronze, iron), metals and metal compounds (toxic, e.g.
beryllium, lead acetate, nickel carbonyl, tetraethyl lead), nitrides
(e.g. potassium nitride, sodium nitride), nitriles (e.g.
acetonitrile, methyl cyanide), hydrocarbons (aliphatic, unsaturated,
e.g. cyclopentene, ethylene, heptene), peroxides and hydroperoxides
(organic, e.g. acetyl peroxide, benzoyl peroxide, butyl peroxide,
methyl ethyl ketone peroxide), phenols and cresols (e.g. carbolic
acid, creosote, cresol, phenol, resorcinol), organophosphates,
phosphothioates (e.g. methylparathion, parathion, phorate,
thionazin), sulfides (inorganic, e.g. ferric sulfide, lead sulfide,
sodium sulfide), epoxides (e.g. butyl glycidyl ether), combustible
and flammable materials (e.g..
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, palladium.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7647-01-0: MW4025000
CAS# 7647-10-1: RT3500000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 7647-01-0: Inhalation, mouse: LC50 = 1108 ppm/1H; Inhalation,
rat: LC50 = 3124 ppm/1H; Oral, rabbit: LD50 = 900 mg/kg.
CAS# 7647-10-1: Draize test, rabbit, skin: 100 mg/24H Mild; Oral,
mouse: LD50 = >1 gm/kg; Oral, rat: LD50 = 2704 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Hydrochloric acid -
IARC: Group 3 carcinogen
Palladium chloride -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Water -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Dangerous Goods Code:
UN Number:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7647-01-0: 1
CAS# 7647-10-1: 1
CAS# 7732-18-5: No information available.
United Kingdom Occupational Exposure Limits
CAS# 7647-01-0: OES-United Kingdom, TWA 1 ppm TWA; 2 mg/m3 TWA
CAS# 7647-01-0: OES-United Kingdom, STEL 5 ppm STEL; 8 mg/m3 STEL
CAS# 7647-01-0: OES-United Kingdom, STEL 5 ppm STEL; 8 mg/m3 STEL
Canada
CAS# 7647-01-0 is listed on Canada's DSL List.
CAS# 7647-10-1 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List.
CAS# 7647-10-1 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7647-01-0: OEL-AUSTRALIA:TWA 5 ppm (7 mg/m3)
OEL-AUSTRIA:TWA 5 ppm (7 mg/m3)
OEL-BELGIUM:STEL 5 ppm (7.7 mg/m3)
OEL-DENMARK:STEL 5 ppm (7 mg/m3)
OEL-FINLAND:STEL 5 ppm (7 mg/m3);Skin
OEL-FRANCE:STEL 5 ppm (7.5 mg/m3)
OEL-GERMANY:TWA 5 ppm (7 mg/m3)
OEL-HUNGARY:STEL 5 mg/m3
OEL-JAPAN:STEL 5 ppm (7.5 mg/m3)
OEL-THE NETHERLANDS:TWA 5 ppm (7 mg/m3)
OEL-THE PHILIPPINES:TWA 5 ppm (7 mg/m3)
OEL-POLAND:TWA 5 mg/m3
OEL-RUSSIA:STEL 5 ppm (5 mg/m3)
OEL-SWEDEN:STEL 5 ppm (8 mg/m3)
OEL-SWITZERLAND:TWA 5 ppm (7.5 mg/m3);STEL 10 ppm (15 mg/m3)
OEL-THAILAND:TWA 5 ppm (7 mg/m3)
OEL-TURKEY:TWA 5 ppm (7 mg/m3)
OEL-UNITED KINGDOM:TWA 5 ppm (7 mg/m3);STEL 5 ppm (7 mg/m3)
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 7647-01-0 is listed on the TSCA inventory.
CAS# 7647-10-1 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/07/2001 Revision #1 Date: 11/07/2001
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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