**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 632-99-5 |Basic Fuchsin | 0.5 | 211-189-6 |
|----------------|--------------------------------------|----------|-----------|
| 7647-01-0 |Hydrochloric acid | 1.1 | 231-595-7 |
|----------------|--------------------------------------|----------|-----------|
| 7681-57-4 |Sodium metabisulfite | 1.0 | 231-673-0 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 97.5 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 36/37/38 42
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. May cause
sensitization by inhalation.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation. May cause asthmatic attacks
due to allergic sensitization of the respiratory tract.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool.
Extinguishing Media:
Substance is nonflammable; use agent most appropriate to extinguish
surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill using an absorbent, non-combustible material such as
earth, sand, or vermiculite. Do not use combustible materials such
as sawdust.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 632-99-5:
CAS# 7647-01-0:
United Kingdom, WEL - TWA: 1 ppm TWA (aerosol mist and gas); 2 mg
TWA (aerosol mist and gas)
United Kingdom, WEL - STEL: 5 ppm STEL (aerosol mist and gas); 8
mg/m3 STEL (aerosol mist and gas)
United States OSHA: ; 5 ppm Ceiling; 7 mg/m3 Ceiling
Belgium - TWA: 5 ppm VLE; 8 mg/m3 VLE
Belgium - STEL: 10 ppm VLE; 15 mg/m3 VLE
France - VLE: 5 ppm VLE; 7.5 mg/m3 VLE
Germany: 8 mg/m3 TWA
Japan: 5 ppm Ceiling; 7.5 mg/m3 Ceiling
Malaysia: 5 ppm Ceiling; 7.5 mg/m3 Ceiling
Netherlands: 10 ppm STEL; 15 mg/m3 STEL
Netherlands: 5 ppm MAC; 8 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 5 ppm VLA-ED; 7.6 mg/m3 VLA-ED
Spain: 10 ppm VLA-EC; 15 mg/m3 VLA-EC
CAS# 7681-57-4:
United Kingdom, WEL - TWA: 5 mg/m3 TWA
United Kingdom, WEL - STEL: 15 mg/m3 STEL
Belgium - TWA: 5 mg/m3 VLE
France - VME: 5 mg/m3 VME
Malaysia: 5 mg/m3 TWA
Netherlands: 5 mg/m3 MAC
Spain: 5 mg/m3 VLA-ED
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: none reported
pH: Not available.
Vapor Pressure: 14 mm Hg
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 0.7
Molecular Formula: Mixture
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light.
Incompatibilities with Other Materials:
Hydrochloric acid is incompatible with acetate, acetic anhydride,
alcohols + hydrogen cyanide, 2-aminoethanol, ammonium hydroxide,
calcium carbide, calcium phosphide, cesium acetylene carbide, cesium
carbide, chlorosulfonic acid, 1,1-difluoroethylene, ethylene diamine,
ethyleneimine, fluorine, lithium silicide, magnesium boride, mercuric
sulfate, oleum, perchloric acid, potassium permanganate,
b-propiolactone, propylene oxide, rubidum acetylene carbide, rubidum
carbide, silver perchlorate + carbon tetrachloride, sodium, sodium
hydroxide, sulfuric acid, uranium phosphide, vinyl acetate.
Substance polymerizes on contact with aldehydes or epoxides. Sodium
metabisulfite is incompatible with strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, sulfur dioxide, hydrogen gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 632-99-5: CX9850000
CAS# 7647-01-0: MW4025000 MW4031000
CAS# 7681-57-4: UX8225000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 7647-01-0: Inhalation, mouse: LC50 = 1108 ppm/1H; Inhalation,
mouse: LC50 = 20487 mg/m3/5M; Inhalation, mouse: LC50 = 3940
mg/m3/30M; Inhalation, mouse: LC50 = 8300 mg/m3/30M; Inhalation,
rat: LC50 = 3124 ppm/1H; Inhalation, rat: LC50 = 60938 mg/m3/5M;
Inhalation, rat: LC50 = 7004 mg/m3/30M; Inhalation, rat: LC50 =
45000 mg/m3/5M; Inhalation, rat: LC50 = 8300 mg/m3/30M; Oral,
rabbit: LD50 = 900 mg/kg.
CAS# 7681-57-4: Dermal, guinea pig: LD50 = >1 gm/kg; Draize test,
rabbit, eye: 100 mg/24H Mild; Draize test, rabbit, skin: 500 mg;
Oral, rat: LD50 = 1131 mg/kg; Skin, rat: LD50 = >2 gm/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Basic Fuchsin -
IARC: Group 2B carcinogen
Hydrochloric acid -
Not listed by ACGIH, IARC, or NTP.
Sodium metabisulfite -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Hydrochloric acid: Trout LC100=10 mg/L/24H Shrimp LC50=100-330 ppm
Starfish LC50=100-330mg/L/48H Shore crab LC50=240 mg/L/48H Chronic
plant toxicity=100 ppm
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
USA RQ: CAS# 7647-01-0: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 42 May cause sensitization by inhalation.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36 Wear suitable protective clothing.
WGK (Water Danger/Protection)
CAS# 632-99-5: No information available.
CAS# 7647-01-0: 1
CAS# 7681-57-4: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 632-99-5 is listed on Canada's DSL List.
CAS# 7647-01-0 is listed on Canada's DSL List.
CAS# 7681-57-4 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 632-99-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List.
CAS# 7681-57-4 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 632-99-5 is listed on the TSCA inventory.
CAS# 7647-01-0 is listed on the TSCA inventory.
CAS# 7681-57-4 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 36/37/38 Irritating to eyes, respiratory system and
skin.
MSDS Creation Date: 11/08/2001 Revision #2 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|