**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3694-57-3 |4-Methoxybenzylisothiocyanate | ca 100 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears). May cause chemical conjunctivitis.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation. The
toxicological properties of this substance have not been fully
investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation. Wash clothing before reuse.
Storage:
Keep refrigerated. (Store below 4C/39F.) Store in a tightly closed
container. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 3694-57-3:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 170-175 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.087
Molecular Formula: C9H9NOS
Molecular Weight: 179.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Moisture sensitive.
Conditions to Avoid:
Moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3694-57-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Methoxybenzylisothiocyanate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 3694-57-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 3694-57-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3694-57-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/15/1999 Revision #5 Date: 11/09/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tropylium Hexafluorophosphate
| 29663-54-5 |
|
3-(4-Cyanobenzoyl)-5,7-Dimethoxycoumarin
| 83179-55-9 |
|
Adenine-9-Beta-D-Arabinofuranoside- 5'-Monophosphate, 98%
| 29984-33-6 |
|
4-Tert-Butylaniline, 99%
| 769-92-6 |
|
4,4'-Dicyanobibenzyl
| |
|
Isoquinoline, 99% (GC)
| 119-65-3 |
|
(2-Naphthoxy)Acetic Acid, N-Hydroxysuccinimide Ester, 98%
| 81012-92-2 |
|
Pentafluorophenylhydrazine, 97%
| 828-73-9 |
|
Diphenyl Phosphate, 99%
| 838-85-7 |
|
Manganese(II) bromide tetrahydrate, 98%
| 10031-20-6 |
|
Sulfur trioxide, stabilized, 99%
| 7446-11-9 |
|
epsilon-Caprolactam
| 105-60-2 |
|
2-Bromo-1-Phenylpropane, 98%
| 2114-39-8 |
|
1,1-Bis(Methylseleno)-Ethane
| 56051-04-8 |
|
4-Chloro-2-methylthiopyrimidine, 98%
| 49844-90-8 |
|
4-Cyanobenzoic Acid, 99%
| 619-65-8 |
|
2,2'-Diaminobibenzyl, 96%
| 0-00-1 |
|
(-)-Dihydrocarvyl acetate, mixture of isomers, 99%
| 20777-49-5 |
|
Cyclobutanecarboxylic Acid Chloride, 99%
| 5006-22-4 |
|
4-Methoxybenzylisothiocyanate
| 3694-57-3 |
|
Bis(MSB), scintillation grade, 99.5%
| 13280-61-0 |
|
1-Octene, 97%
| 111-66-0 |
|
Bromoacetaldehyde dimethyl acetal, 97%, stabilized with 0.2%
| 7252-83-7 |
|
d-Histidine hydrochloride monohydrate 99%
| 6341-24-8 |
|
Pimelic acid, 98%
| 111-16-0 |
|
Trans-Beta-Hydromuconic Acid, 98%
| 4436-74-2 |
|
Nickel(ii) acetylacetonate dihydrate, 99+% (titr.)
| 3264-82-2 |
|
Ethyl Allophanate
| 626-36-8 |
|
2,6-Dimethylpyrazine, ca 96% (nmr), balanc e 2,5-isomer
| 108-50-9 |
|
(1,3-Dioxolan-2-ylmethyl)triphenyl phosphonium bromide, 98%
| 52509-14-5 |
|
3,3'-Thiodipropanol, 98%
| 10595-09-2 |
|
2-Imidazolidinethione, paraffinic oil coated powder
| 96-45-7 |
|
Coumarin 7, Laser Grade, 99% (UV-Vis)
| 27425-55-4 |
|
Bemegride, 99+%
| 64-65-3 |
|
DL-3(Methylthio)-2-Butanone 99%
| 53475-15-3 |
|
Methyl (trimethylsilyl)acetate, 98%
| 2916-76-9 |
|
3-Methylindole, 98%
| 83-34-1 |
|
Titanium(IV) isopropoxide, 98+%
| 546-68-9 |
|
2-Hydroxy-4,5-Dimethylacetophenone, 98%
| 36436-65-4 |
|
Allyl sulfide, 97%
| 592-88-1 |
|
Dehydroacetic acid, 98%
| 520-26-3 |
|
Lactulose, 50 Wt% Solution in Water
| 4618-18-2 |
|
Ethylene/propylene copolymer, low molecular weight
| 9010-79-1 |
|
D-(+)-Altrose, 99%
| 1990-29-0 |
|
Ftorafur, 99%
| 17902-23-7 |
|
L(-)-Perillaldehyde, 90% (Titr.)
| 18031-40-8 |
|
3-Amino-5-Methylisoxazole, 98+%
| 1072-67-9 |
|
Yttrium atomic absorption standard solution, 1 mg/ml Y in 2% HNO3
| 7440-65-5 |
|
1,6-Dibromo-2-Naphthol, 99%
| 16239-18-2 |
|
4,4'-Dimethoxytrityl chloride 98%
| 40615-36-9 |
|
|