**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 769-92-6 |4-Tert-Butylaniline | 99% | 212-215-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. May cause cardiac
disturbances. May cause methemoglobinemia, cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood),
convulsions, and death. May cause central nervous system depression.
Inhalation:
May cause respiratory tract irritation. May cause methemoglobinemia,
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), convulsions, tachycardia, dyspnea (labored breathing),
and death. May cause cardiac abnormalities. Inhalation at high
concentrations may cause CNS depression and asphixiation.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas. Containers may explode when heated. Runoff
from fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with
flooding quantities of water until well after fire is out. Use water
spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 769-92-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear slight brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 90.0 - 93.0 deg C @ 3.00mmHg
Freezing/Melting Point: 15.00 - 16.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: 101 deg C ( 213.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9370g/cm3
Molecular Formula: C10H15N
Molecular Weight: 149.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, strong acids, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, acid anhydrides,
chloroformates, acid chlorides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 769-92-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Tert-Butylaniline -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 769-92-6: 1
Canada
CAS# 769-92-6 is listed on Canada's DSL List.
CAS# 769-92-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 769-92-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tropylium Hexafluorophosphate
| 29663-54-5 |
|
3-(4-Cyanobenzoyl)-5,7-Dimethoxycoumarin
| 83179-55-9 |
|
Adenine-9-Beta-D-Arabinofuranoside- 5'-Monophosphate, 98%
| 29984-33-6 |
|
4-Tert-Butylaniline, 99%
| 769-92-6 |
|
4,4'-Dicyanobibenzyl
| |
|
Isoquinoline, 99% (GC)
| 119-65-3 |
|
(2-Naphthoxy)Acetic Acid, N-Hydroxysuccinimide Ester, 98%
| 81012-92-2 |
|
Pentafluorophenylhydrazine, 97%
| 828-73-9 |
|
Diphenyl Phosphate, 99%
| 838-85-7 |
|
Manganese(II) bromide tetrahydrate, 98%
| 10031-20-6 |
|
Sulfur trioxide, stabilized, 99%
| 7446-11-9 |
|
epsilon-Caprolactam
| 105-60-2 |
|
2-Bromo-1-Phenylpropane, 98%
| 2114-39-8 |
|
1,1-Bis(Methylseleno)-Ethane
| 56051-04-8 |
|
4-Chloro-2-methylthiopyrimidine, 98%
| 49844-90-8 |
|
4-Cyanobenzoic Acid, 99%
| 619-65-8 |
|
2,2'-Diaminobibenzyl, 96%
| 0-00-1 |
|
(-)-Dihydrocarvyl acetate, mixture of isomers, 99%
| 20777-49-5 |
|
Cyclobutanecarboxylic Acid Chloride, 99%
| 5006-22-4 |
|
4-Methoxybenzylisothiocyanate
| 3694-57-3 |
|
Bis(MSB), scintillation grade, 99.5%
| 13280-61-0 |
|
1-Octene, 97%
| 111-66-0 |
|
Bromoacetaldehyde dimethyl acetal, 97%, stabilized with 0.2%
| 7252-83-7 |
|
d-Histidine hydrochloride monohydrate 99%
| 6341-24-8 |
|
Pimelic acid, 98%
| 111-16-0 |
|
Trans-Beta-Hydromuconic Acid, 98%
| 4436-74-2 |
|
Nickel(ii) acetylacetonate dihydrate, 99+% (titr.)
| 3264-82-2 |
|
Ethyl Allophanate
| 626-36-8 |
|
2,6-Dimethylpyrazine, ca 96% (nmr), balanc e 2,5-isomer
| 108-50-9 |
|
(1,3-Dioxolan-2-ylmethyl)triphenyl phosphonium bromide, 98%
| 52509-14-5 |
|
3,3'-Thiodipropanol, 98%
| 10595-09-2 |
|
2-Imidazolidinethione, paraffinic oil coated powder
| 96-45-7 |
|
Coumarin 7, Laser Grade, 99% (UV-Vis)
| 27425-55-4 |
|
Bemegride, 99+%
| 64-65-3 |
|
DL-3(Methylthio)-2-Butanone 99%
| 53475-15-3 |
|
Methyl (trimethylsilyl)acetate, 98%
| 2916-76-9 |
|
3-Methylindole, 98%
| 83-34-1 |
|
Titanium(IV) isopropoxide, 98+%
| 546-68-9 |
|
2-Hydroxy-4,5-Dimethylacetophenone, 98%
| 36436-65-4 |
|
Allyl sulfide, 97%
| 592-88-1 |
|
Dehydroacetic acid, 98%
| 520-26-3 |
|
Lactulose, 50 Wt% Solution in Water
| 4618-18-2 |
|
Ethylene/propylene copolymer, low molecular weight
| 9010-79-1 |
|
D-(+)-Altrose, 99%
| 1990-29-0 |
|
Ftorafur, 99%
| 17902-23-7 |
|
L(-)-Perillaldehyde, 90% (Titr.)
| 18031-40-8 |
|
3-Amino-5-Methylisoxazole, 98+%
| 1072-67-9 |
|
Yttrium atomic absorption standard solution, 1 mg/ml Y in 2% HNO3
| 7440-65-5 |
|
1,6-Dibromo-2-Naphthol, 99%
| 16239-18-2 |
|
4,4'-Dimethoxytrityl chloride 98%
| 40615-36-9 |
|
|