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MSDS 
:
 4-Bromobenzyl bromide, 98%
CAS 
:
 589-15-1
SYNONYMS 
:
 alpha,p-Dibromotoluene.
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 589-15-1 |4-Bromobenzyl bromide | 100 % | 209-636-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Causes burns.Corrosive.The toxicological properties of this material
have not been fully investigated.

Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). Lachrymator (substance which increases the flow of
tears).
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
No information found.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Reduce airborne dust and prevent scattering by moistening
with water. Clean up spills immediately, observing precautions in
the Protective Equipment section.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Wash hands before eating. Use only
in a well-ventilated area. Do not breathe dust, vapor, mist, or gas.
Do not get on skin or in eyes. Do not ingest or inhale.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 589-15-1:


Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Solid
Color: light pink
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 115 - 124 deg C @ 12.00mm Hg
Freezing/Melting Point: 59 - 61 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: may decompose
Specific Gravity/Density:
Molecular Formula: C7H6Br2
Molecular Weight: 249.93

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, moisture.
Incompatibilities with Other Materials:
Bases, amines, oxidizing agents, alcohols, and corrodes steel.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 589-15-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Bromobenzyl bromide -
Not listed by ACGIH, IARC, or NTP.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: II

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 589-15-1: No information available.
Canada
CAS# 589-15-1 is listed on Canada's NDSL List.
CAS# 589-15-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 589-15-1 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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NAMECAS
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4-Bromobenzyl bromide, 98% 589-15-1
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1-Iodobutane, 98%, stabilized over copper 542-69-8
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4-??4-chloro-3-(trifluoromethyl)phenyl??-4- piperidinol, 97% 21928-50-7
n-Carbethoxyphthalimide, 98% 22509-74-6
Dodecylbenzene sulfonic acid, 97%, mixture of isomers 27176-87-0
Squaric acid dibutylester, 97+% 2892-62-8
2-(Trimethylsilyl-ethanol, 99% 2916-68-9
4-Chloro-3,5-dimethylphenol, 99% 88-04-0
3-O-Methyl-D-Glucopyranose, 99+% 3370-81-8
Tris-(3-(Trifluoromethylhydroxymethylene)-D-Camphorato], Praseodymium 38053-99-5
3-Phenoxybenzaldehyde, 97% 39515-51-0
Sinigrin monohydrate 3952-98-5
alpha-D(+)-Glucose, anhydrous, 99+% 492-62-6
2-Bromo-3'-Methoxyacetophenone, 97% 5000-65-7
3-N-Pentadecylphenol, 90-95% 501-24-6
Hexacosanol 98% 506-52-5
D(-)-Penicillamine, 99+% 52-67-5
Lithium acetate, pure 546-89-4
Cis-Decahydro-1-Naphthol 529-32-8
Sodium Amide, 95% 7782-92-5
1-Benzyl-4-Piperidineacetonitrile, 97% 78056-67-4
2-Ethylphenol, 99% 90-00-6
Poly(dimethylsiloxane) 9016-00-6
2,4-Dichlorobenzylchloride, 99% 94-99-5
Trans-2-Amino-4-Cyclohexene-1-Carboxylic Acid, 98+% 97945-19-2
Lead(II) Bromide, 98+% 10031-22-8
3,7-Dimethyl-Trans-2,6-Octadien-1-yl Acetate, 98%, Mixture of Isomers 105-87-3
Ethyl Laurate, 99+% 106-33-2
Normal-heptyl cyanide, 97% 124-12-9
2-Chloro-1-Methylpyridinium Iodide, 97% 14338-32-0
Fast Violet B Salt, 99% (uv-vis) 14726-28-4
Ethyl Cis-2-Hydroxy-1-Cyclohexanecarboxylate (>98%) 16179-44-5
2-Bromophenylacetic acid, 98% (titr.) 18698-97-0
3-Aminobenzyl alcohol, 97% 1877-77-6
Uridine 5'-Triphosphate, Trisodium Salt Hydrate, 90% (HPLC) 19817-92-6
Platinum on activated carbon, not reduced, 5% Pt 7440-06-4
4-Bromo-3,5-Difluoroanisole, Mixture of Isomers
Gelatin Multicomponent Trace Element Reference Material (Teg-50-B) 7429-90-5
Gelatin multicomponent trace element reference material (TEG-50-c)
Ion pair sampler kit (low uv)
Ion pair sampler kit
Ready-to-use i scintillator solution (for nonaqueous samples in
Ready-to-use ii scintillator solution (for aqueous samples at
Ready-to-use iii scintillator solution (for aqueous samples at
Ultraviolet Sensitizing Solution

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