MSDS | : | 4-Chloro-3,5-dimethylphenol, 99% | CAS | : | 88-04-0 | SYNONYMS | : | 3,5-Xylenol, 4-chloro-; Benzytol; 2-Chloro-5-hydroxy-1,3-dimethylbenzene; 4-Chloro-1-hydroxy-3,5-dimethylbenzene; 2-Chloro-5-hydroxy-m-xylene; Chloro-xylenol; p-Chloro-m-xylenol; 2-Chloro-m-xylenol; 4-Chloro-3,5-xylenol; PCMX; Phenol, 4-chloro-3,5-dimethyl-. |
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**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 88-04-0 |4-Chloro-3,5-dimethylphenol | 99 | 201-793-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/38 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes and skin. May cause
sensitization by skin contact.
Potential Health Effects
Eye:
Causes moderate eye irritation.
Skin:
Causes skin irritation. May cause an allergic reaction in certain
individuals.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes irritation of the mucous membrane and upper respiratory
tract.
Chronic:
Animal studies have reported that fetal effects/abnormalities may
occur when maternal toxicity is seen. Laboratory experiments have
resulted in mutagenic effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 88-04-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white to off-white
Odor: phenol-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 246 deg C @ 760 mm Hg
Freezing/Melting Point: 113-116 deg C
Autoignition Temperature: Not applicable.
Flash Point: 132 deg C ( 269.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density:
Molecular Formula: C8H9ClO
Molecular Weight: 156.61
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Volatile in steam.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 88-04-0: ZE6850000
LD50/LC50:
CAS# 88-04-0: Draize test, rabbit, eye: 100 mg Moderate; Oral,
mouse: LD50 = 1 gm/kg; Oral, rat: LD50 = 3830 mg/kg.
Carcinogenicity:
4-Chloro-3,5-dimethylphenol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50 = 0.77 mg/L; 96 Hr; UnspecifiedFish:
Bluegill/Sunfish: LC50 =2.7 mg/L; 96 Hr; UnspecifiedWater flea
Daphnia: EC50 =4.5-7.7 mg/L; 48 Hr; Static bioassayBacteria:
Phytobacterium phosphoreum: EC50 = 1.99 mg/L; 5 min; Microtox test
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 24 Avoid contact with skin.
S 37 Wear suitable gloves.
WGK (Water Danger/Protection)
CAS# 88-04-0: No information available.
Canada
CAS# 88-04-0 is listed on Canada's DSL List.
CAS# 88-04-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 88-04-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/13/1999 Revision #2 Date: 7/15/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
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| ALL MSDS PAGES IN THIS GROUP
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| 5715-02-6 |
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| 578-58-5 |
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4-Bromobenzyl bromide, 98%
| 589-15-1 |
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Rhodium (II) acetate, dimer, anhydrous, ca. 43 % Rh
| 15956-28-2 |
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1-Iodobutane, 98%, stabilized over copper
| 542-69-8 |
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2,5-Dimethyl-p-benzoquinone, 99%
| 137-18-8 |
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N,N-Dimethylacetoacetamide (Contains Approx. 17 Wt.% Water), 83% (GC)
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| 21928-50-7 |
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n-Carbethoxyphthalimide, 98%
| 22509-74-6 |
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Dodecylbenzene sulfonic acid, 97%, mixture of isomers
| 27176-87-0 |
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Squaric acid dibutylester, 97+%
| 2892-62-8 |
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2-(Trimethylsilyl-ethanol, 99%
| 2916-68-9 |
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4-Chloro-3,5-dimethylphenol, 99%
| 88-04-0 |
|
3-O-Methyl-D-Glucopyranose, 99+%
| 3370-81-8 |
|
Tris-(3-(Trifluoromethylhydroxymethylene)-D-Camphorato], Praseodymium
| 38053-99-5 |
|
3-Phenoxybenzaldehyde, 97%
| 39515-51-0 |
|
Sinigrin monohydrate
| 3952-98-5 |
|
alpha-D(+)-Glucose, anhydrous, 99+%
| 492-62-6 |
|
2-Bromo-3'-Methoxyacetophenone, 97%
| 5000-65-7 |
|
3-N-Pentadecylphenol, 90-95%
| 501-24-6 |
|
Hexacosanol 98%
| 506-52-5 |
|
D(-)-Penicillamine, 99+%
| 52-67-5 |
|
Lithium acetate, pure
| 546-89-4 |
|
Cis-Decahydro-1-Naphthol
| 529-32-8 |
|
Sodium Amide, 95%
| 7782-92-5 |
|
1-Benzyl-4-Piperidineacetonitrile, 97%
| 78056-67-4 |
|
2-Ethylphenol, 99%
| 90-00-6 |
|
Poly(dimethylsiloxane)
| 9016-00-6 |
|
2,4-Dichlorobenzylchloride, 99%
| 94-99-5 |
|
Trans-2-Amino-4-Cyclohexene-1-Carboxylic Acid, 98+%
| 97945-19-2 |
|
Lead(II) Bromide, 98+%
| 10031-22-8 |
|
3,7-Dimethyl-Trans-2,6-Octadien-1-yl Acetate, 98%, Mixture of Isomers
| 105-87-3 |
|
Ethyl Laurate, 99+%
| 106-33-2 |
|
Normal-heptyl cyanide, 97%
| 124-12-9 |
|
2-Chloro-1-Methylpyridinium Iodide, 97%
| 14338-32-0 |
|
Fast Violet B Salt, 99% (uv-vis)
| 14726-28-4 |
|
Ethyl Cis-2-Hydroxy-1-Cyclohexanecarboxylate (>98%)
| 16179-44-5 |
|
2-Bromophenylacetic acid, 98% (titr.)
| 18698-97-0 |
|
3-Aminobenzyl alcohol, 97%
| 1877-77-6 |
|
Uridine 5'-Triphosphate, Trisodium Salt Hydrate, 90% (HPLC)
| 19817-92-6 |
|
Platinum on activated carbon, not reduced, 5% Pt
| 7440-06-4 |
|
4-Bromo-3,5-Difluoroanisole, Mixture of Isomers
| |
|
Gelatin Multicomponent Trace Element Reference Material (Teg-50-B)
| 7429-90-5 |
|
Gelatin multicomponent trace element reference material (TEG-50-c)
| |
|
Ion pair sampler kit (low uv)
| |
|
Ion pair sampler kit
| |
|
Ready-to-use i scintillator solution (for nonaqueous samples in
| |
|
Ready-to-use ii scintillator solution (for aqueous samples at
| |
|
Ready-to-use iii scintillator solution (for aqueous samples at
| |
|
Ultraviolet Sensitizing Solution
| |
|
|