**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 60956-26-5 |4-Bromo-2-Nitrotoluene | 99+% | 262-536-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Danger
of cumulative effects.Toxic.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Harmful if
inhaled.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. If breathing has ceased
apply artificial respiration using oxygen and a suitable mechanical
device such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 60956-26-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: yellow to yellow-orange
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 43.00 - 46.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula: C7H6BrNO2
Molecular Weight: 216.03
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 60956-26-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Bromo-2-Nitrotoluene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 60956-26-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 60956-26-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 60956-26-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 12/07/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
L-(-)-3-Phenyllactic acid, 98%
| 20312-36-1 |
|
Gold Star Cocktail
| 0-01-1 |
|
4-Aminopiperidine-1-carboxylic acid methyl amide dihydrochloride
| 0-01-1 |
|
1-Pyridazin-3-yl-piperidin-4-ylamine dihydrochloride
| 0-01-1 |
|
Linoleoyl Chloride (Pract)
| 7459-33-8 |
|
4-Methylsulphonylacetophenone, 95+%
| 10297-73-1 |
|
2-Bromobenzoic Acid, 97%
| 88-65-3 |
|
3,4,5,6-Tetrahydro-2H-[1,3']bipyridinyl-4-ylamine dihydrochloride
| 0-01-1 |
|
6'-Methyl-3,4,5,6-tetrahydro-2H-[1,2']bipyridinyl-4-ylamine
| 0-01-1 |
|
n-Butyl isocyanide 98+%
| 2769-64-4 |
|
4'-Methyl-3,4,5,6-tetrahydro-2H-[1,2']bipyridinyl-4-ylamine
| 0-01-1 |
|
5'-Methyl-3,4,5,6-tetrahydro-2H-[1,2']bipyridinyl-4-ylamine
| 0-01-1 |
|
Cerium(III) nitrate hexahydrate, 99.5%
| 10108-73-3 |
|
Diethyl Tetradecanedioate, 99%
| 19812-63-6 |
|
3-(Thiocarbamoyl)dithiocarbazic acid potassium salt
| 73771-62-7 |
|
4-Bromo-2-Nitrotoluene, 99+%
| 60956-26-5 |
|
Arsenic trichloride
| 7784-34-1 |
|
Zinc Atomic Absorption Standard Solution, 1 mg/ml Zn in 2% HCl
| 7440-66-6 |
|
1-Methoxy-1-buten-3-yne, 50 wt. % solution in methanol-water (4 to
| 2798-73-4 |
|
Electrolyte TC-B
| 7446-70-0 |
|
Quinine sulfate dihydrate, 99%
| 6119-70-6 |
|
Neodisher FLA
| 1310-58-3 |
|
Tris (2-chloroethyl) orthoformate
| 18719-58-9 |
|
Trimethyl 1,2,4-Benzenetricarboxylate, 98%
| 2459-10-1 |
|
D-Arabinose
| 10318-18-0 |
|
Sodium citrate buffer solution
| 77-92-9 |
|
Phosphate Buffer Solution
| 1310-73-2 |
|
Isobornyl methacrylate, 85-90% (stabilized with ~200 ppm MEHQ)
| 150-76-5 |
|
Methyl 1-methylcyclopropyl ketone, 95%
| 1567-75-5 |
|
S-(+)-2-Hexanol, 98%
| 52019-78-0 |
|
Ortho-Nitrobenzonitrile
| 612-23-7 |
|
2-Chloronaphthalene, 99% (GC)
| 91-58-7 |
|
Lovibond Minikit Hardness
| 1310-65-2 |
|
5-Diethylamino-2-Pentanone, 98%
| 105-14-6 |
|
Xylenes, mixed isomers with ethylbenzene (Flashpoint 21C / 69.8F;
| 100-41-4 |
|
Phenol water saturated solution, unstabilized
| 108-95-2 |
|
Buffer Adjuster (pH 8)
| 77-86-1 |
|
Phenol / Chloroform / Isoamyl alcohol mixture (25:24:1)
| 67-66-3 |
|
1-(4-Hydroxyphenyl)-pyrrole-2,5-dione
| 7300-91-6 |
|
Carbon decolorizing powder, activated
| 7440-44-0 |
|
Charcoal powder / granular
| 471-34-1 |
|
Carbon, steam activated / charcoal blocks
| 7440-44-0 |
|
4,5-Dihydro-1,3-benzodioxine-6-amine
| 22791-64-6 |
|
0.2% w/v Ammonium Formate in HPLC Water
| 540-69-2 |
|
0.2% w/v Ammonium formate in HPLC acetonitrile
| 75-05-8 |
|
Ammonia Buffer HPLC Water to pH 10 (Ammonia concentration 0.5%)
| 7664-41-7 |
|
Methyl 2-amino-3-carboxybenzoate
| 0-01-1 |
|
DL-3-Methylvaleric Acid, 97%
| 105-43-1 |
|
(+/-)-Abscisic acid, 98%
| 14375-45-2 |
|
2-Iodoethanol, 99%, stabilized with copper
| 624-76-0 |
|
|