**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 77-86-1 |Tris (hydroxymethyl) aminomethane | 60-65 | 201-064-4 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes and skin.The toxicological properties of this
material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns. May cause liver and kidney damage. The
toxicological properties of this substance have not been fully
investigated. May cause metabolic changes including hypoglycemia, and
hyperkalemia. May depress respiratory center.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause
liver and kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from acids.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 77-86-1:
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: Solution
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Oxidizing agents, bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 77-86-1: TY2900000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 77-86-1: Oral, rat: LD50 = 5900 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Tris (hydroxymethyl) aminomethane -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 77-86-1: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 77-86-1 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 77-86-1 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 77-86-1 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 11/18/2004 Revision #1 Date: 11/18/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
L-(-)-3-Phenyllactic acid, 98%
| 20312-36-1 |
|
Gold Star Cocktail
| 0-01-1 |
|
4-Aminopiperidine-1-carboxylic acid methyl amide dihydrochloride
| 0-01-1 |
|
1-Pyridazin-3-yl-piperidin-4-ylamine dihydrochloride
| 0-01-1 |
|
Linoleoyl Chloride (Pract)
| 7459-33-8 |
|
4-Methylsulphonylacetophenone, 95+%
| 10297-73-1 |
|
2-Bromobenzoic Acid, 97%
| 88-65-3 |
|
3,4,5,6-Tetrahydro-2H-[1,3']bipyridinyl-4-ylamine dihydrochloride
| 0-01-1 |
|
6'-Methyl-3,4,5,6-tetrahydro-2H-[1,2']bipyridinyl-4-ylamine
| 0-01-1 |
|
n-Butyl isocyanide 98+%
| 2769-64-4 |
|
4'-Methyl-3,4,5,6-tetrahydro-2H-[1,2']bipyridinyl-4-ylamine
| 0-01-1 |
|
5'-Methyl-3,4,5,6-tetrahydro-2H-[1,2']bipyridinyl-4-ylamine
| 0-01-1 |
|
Cerium(III) nitrate hexahydrate, 99.5%
| 10108-73-3 |
|
Diethyl Tetradecanedioate, 99%
| 19812-63-6 |
|
3-(Thiocarbamoyl)dithiocarbazic acid potassium salt
| 73771-62-7 |
|
4-Bromo-2-Nitrotoluene, 99+%
| 60956-26-5 |
|
Arsenic trichloride
| 7784-34-1 |
|
Zinc Atomic Absorption Standard Solution, 1 mg/ml Zn in 2% HCl
| 7440-66-6 |
|
1-Methoxy-1-buten-3-yne, 50 wt. % solution in methanol-water (4 to
| 2798-73-4 |
|
Electrolyte TC-B
| 7446-70-0 |
|
Quinine sulfate dihydrate, 99%
| 6119-70-6 |
|
Neodisher FLA
| 1310-58-3 |
|
Tris (2-chloroethyl) orthoformate
| 18719-58-9 |
|
Trimethyl 1,2,4-Benzenetricarboxylate, 98%
| 2459-10-1 |
|
D-Arabinose
| 10318-18-0 |
|
Sodium citrate buffer solution
| 77-92-9 |
|
Phosphate Buffer Solution
| 1310-73-2 |
|
Isobornyl methacrylate, 85-90% (stabilized with ~200 ppm MEHQ)
| 150-76-5 |
|
Methyl 1-methylcyclopropyl ketone, 95%
| 1567-75-5 |
|
S-(+)-2-Hexanol, 98%
| 52019-78-0 |
|
Ortho-Nitrobenzonitrile
| 612-23-7 |
|
2-Chloronaphthalene, 99% (GC)
| 91-58-7 |
|
Lovibond Minikit Hardness
| 1310-65-2 |
|
5-Diethylamino-2-Pentanone, 98%
| 105-14-6 |
|
Xylenes, mixed isomers with ethylbenzene (Flashpoint 21C / 69.8F;
| 100-41-4 |
|
Phenol water saturated solution, unstabilized
| 108-95-2 |
|
Buffer Adjuster (pH 8)
| 77-86-1 |
|
Phenol / Chloroform / Isoamyl alcohol mixture (25:24:1)
| 67-66-3 |
|
1-(4-Hydroxyphenyl)-pyrrole-2,5-dione
| 7300-91-6 |
|
Carbon decolorizing powder, activated
| 7440-44-0 |
|
Charcoal powder / granular
| 471-34-1 |
|
Carbon, steam activated / charcoal blocks
| 7440-44-0 |
|
4,5-Dihydro-1,3-benzodioxine-6-amine
| 22791-64-6 |
|
0.2% w/v Ammonium Formate in HPLC Water
| 540-69-2 |
|
0.2% w/v Ammonium formate in HPLC acetonitrile
| 75-05-8 |
|
Ammonia Buffer HPLC Water to pH 10 (Ammonia concentration 0.5%)
| 7664-41-7 |
|
Methyl 2-amino-3-carboxybenzoate
| 0-01-1 |
|
DL-3-Methylvaleric Acid, 97%
| 105-43-1 |
|
(+/-)-Abscisic acid, 98%
| 14375-45-2 |
|
2-Iodoethanol, 99%, stabilized with copper
| 624-76-0 |
|
|