**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 68-19-9 |Cyanobalamine | 96 | 200-680-0
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Light sensitive.Hygroscopic.
Potential Health Effects
Eye:
Contact may cause transient eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Ingestion of large amounts may cause convulsions, tremors,
muscular contractions or spasticity, diarrhea, or fever.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Avoid breathing dust.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Store protected from moisture. Store protected from
light. Refrigeration has been recommended.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: dark red
Odor: odorless
pH: aq solns are neutral
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: > 300 deg C
Freezing/Melting Point: > 300 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Moderately soluble in water.
Specific Gravity/Density: Not available.
Molecular Formula: C63H88CoN14O14P
Molecular Weight: 1355.38
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose when
exposed to light. Darkens at 210 - 220C.
Conditions to Avoid:
Light, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizers, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of phosphorus, carbon
dioxide, oxides of cobalt.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 68-19-9: GG3750000
LD50/LC50:
Not available.
Carcinogenicity:
Cyanobalamine -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 68-19-9: No information available.
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 68-19-9 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 68-19-9 (listed as ** undefined **): OEL-ARAB Republic of Egypt:T
WA 0.1 mg/m3
OEL-AUSTRALIA:TWA 0.05 mg/m3
OEL-BELGIUM:TWA 0.05 mg/m3
OEL-CZECHOSLOVAKIA:TWA 0.05 mg/m3;STEL 0.1 mg/m3
OEL-DENMARK:TWA 0.05 mg/m3
OEL-FINLAND:TWA 0.05 mg/m3;Skin
OEL-GERMANY;Carcinogen
OEL-HUNGARY:TWA 0.1 mg/m3;STEL 0.2 mg/m3
OEL-THE NETHERLANDS:TWA 0.1 mg/m3
OEL-THE PHILIPPINES:TWA 0.1 mg/m3
OEL-POLAND:TWA 0.05 mg/m3
OEL-RUSSIA:STEL 0.5 mg/m3
OEL-SWEDEN:TWA 0.05 mg/m3
OEL-SWITZERLAND:TWA 0.1 mg/m3;Carcinogen
OEL-UNITED KINGDOM:TWA 0.1 mg/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 68-19-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/08/1998 Revision #3 Date: 9/23/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(1-Amino-2,2-dimethylpropyl)phosphonic acid, 97%
| 125078-15-1 |
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Yttrium(iii)-oxide, 99.99%
| 1314-36-9 |
|
Tetracycline Hydrochloride,"Can be Used as Secondary Standard"
| 64-75-5 |
|
Erythromycin
| 114-07-8 |
|
Glyoxal, 40 wt. % solution in water
| 107-22-2 |
|
4-Chloro-1-Naphthol, 99% (Titr.)
| 604-44-4 |
|
Dextran (Low Fraction)
| 9004-54-0 |
|
(1-Amino-1-methylethyl)phosphonic acid, 97%
| 5035-79-0 |
|
Murexide
| 3051-09-0 |
|
(1-Amino-1-methylpropyl)phosphonic acid, 97%
| 62879-51-0 |
|
DL-Aspartic Acid, 99+%
| 617-45-8 |
|
o-Xylene
| 95-47-6 |
|
p-Toluenesulfonic Acid Monohydrate
| 104-15-4 |
|
Copper (II) Bromide, Anhydrous, 99+%
| 7789-45-9 |
|
Pancreatin (Powder)
| 8049-47-6 |
|
(1-Amino-1-methylbutyl)phosphonic acid, 97%
| 125078-17-3 |
|
(1-Amino-1,2-dimethylpropyl)phosphonic acid, 97%
| 101804-01-7 |
|
Tin (II) Chloride Dihydrate, P.A.
| 10025-69-1 |
|
(1-Amino-1,3-dimethylbutyl)phosphonic acid, 97%
| 125078-18-4 |
|
Poly(vinyl alcohol), 88% Hydrolyzed Average M.W. 88.000
| 9002-89-5 |
|
(1-Amino-1-cyclopentyl)phosphonic acid, 97%
| 67550-64-5 |
|
Zinc acetate dihydrate, 98+%
| 5970-45-6 |
|
Ammonia, solution in methanol, ca. 7N
| 67-56-1 |
|
2-Amino-5-Chloropyridine, 98%
| 1072-98-6 |
|
Kinetin, 99%
| 525-79-1 |
|
FMOC-L-Leucine, 98%
| 35661-60-0 |
|
(1-Amino-1-cyclohexyl)phosphonic acid, 97%
| 67398-11-2 |
|
Cottonseed Oil, U.S.P.N.F.
| 8001-29-4 |
|
FMOC-L-Valine, 98%
| 68858-20-8 |
|
FMOC-L-Asparagine, 98%
| 71989-16-7 |
|
Brucine sulfate heptahydrate, reagent ACS
| 4845-99-2 |
|
(1-Aminopropyl)phosphonic acid, 97%
| 14047-23-5 |
|
Sodium phosphate monobasic, dihydrate, p.a.
| 7558-80-7 |
|
Kaolin, Monohydrate
| 1332-58-7 |
|
FMOC-L-Glutamic Acid-O-T-Butylester, Monohydrate, 98%
| 71989-18-9 |
|
Litmus, indicator grade
| 1393-92-6 |
|
Tween 20
| 9005-64-5 |
|
Sodium Hypochlorite, 13% Active Chlorine
| 7681-52-9 |
|
FMOC-O-T-Butyl-L-Threonine, 98%
| 71989-35-0 |
|
Boc-L-Asparagine, 99+%
| 7536-55-2 |
|
Manganese (II) chloride, 98%
| 7773-01-5 |
|
N,N'-Methylenebisacrylamide, for electrophoresis, 99+%
| 110-26-9 |
|
Cyanocobalamin, 96%
| 68-19-9 |
|
Sodium phosphate dibasic dihydrate, HPLC grade, 99+%
| 7558-79-4 |
|
2,5-Disulfoaniline, 95%
| 98-44-2 |
|
2,3,4,5,6-Pentabromotoluene, 99%
| 87-83-2 |
|
2,4-Dibromo-6-nitroaniline, 98%
| 827-23-6 |
|
2,3-Dimethylthiophene, 97%
| 0-01-1 |
|
Tin, Mossy, 99.8%
| 7440-31-5 |
|
FMOC-O-T-Butyl-L-Serine, 98%
| 71989-33-8 |
|
|