**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7773-01-5 |Manganese(II) chloride | 98 | 231-869-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and
skin.Hygroscopic.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause central nervous system
effects and/or neurological effects. In high doses, manganese may
increase anemia by interfering with iron absorption.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema. Chronic inhalation hazard.
Chronic:
Effects may be delayed. Chronic manganese toxicity through
inhalation may result in "manganism", which is a disease of the
central nervous system involving psychic and neurological disorders.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Treat symptomatically and supportively. Persons with impaired
respiratory function or anemia may be at increased risk to the
hazards associated with this substance.
Antidote:
No specific antidote exists.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Do not breathe dust, vapor, mist, or gas. Keep container
tightly closed. Do not ingest or inhale.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR ??1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Appearance: pink
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 1190 deg C
Freezing/Melting Point: 650 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 2.977
Molecular Formula: Cl2Mn
Molecular Weight: 125.844
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Zinc, potassium, sodium, moisture, strong reducing agents, hydrogen
peroxides.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases, oxides of
manganese.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7773-01-5: OO9625000
LD50/LC50:
CAS# 7773-01-5: Oral, mouse: LD50 = 1031 mg/kg; Oral, rat: LD50 =
250 mg/kg.
Carcinogenicity:
Manganese(II) chloride -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7773-01-5: 1
United Kingdom Occupational Exposure Limits
CAS# 7773-01-5: OES-United Kingdom, TWA (listed as ** undefined
**): as Mn: 5 mg/m3 TWA
CAS# 7773-01-5: OES-United Kingdom, STEL (listed as ** undefined
**): fume, as Mn: 3 mg/m3 STEL
Canada
CAS# 7773-01-5 is listed on Canada's DSL List.
CAS# 7773-01-5 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7773-01-5: OEL-AUSTRALIA:TWA 5 mg(Mn)/m3 JANUARY 1993
OEL-BELGIUM:TWA 5 mg(Mn)/m3 JANUARY 1993
OEL-CZECHOSLOVAKIA:TWA 2 mg(Mn)/m3;STEL 6 mg(Mn)/m3 JANUARY 1993
OEL-DENMARK:TWA 2.5 mg(Mn)/m3 JANUARY 1993
OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JANUARY 1993
OEL-HUNGARY:TWA 0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JANUARY 1993
OEL-JAPAN:TWA 0.3 mg(Mn)/m3 JANUARY 1993
OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JANUARY 1993
OEL-POLAND:TWA 0.3 mg(Mn)/m3 JANUARY 1993
OEL-SWEDEN:TWA 1 mg(Mn)/m3;STEL 2.5 mg(Mn)/m3 (resp. dust)
OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL 5 mg(Mn)/m3 (total dust)
OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JANUARY 1993
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 7773-01-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/30/1999 Revision #1 Date: 8/02/2000
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
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| ALL MSDS PAGES IN THIS GROUP
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Tetracycline Hydrochloride,"Can be Used as Secondary Standard"
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Erythromycin
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Glyoxal, 40 wt. % solution in water
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4-Chloro-1-Naphthol, 99% (Titr.)
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Dextran (Low Fraction)
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(1-Amino-1-methylethyl)phosphonic acid, 97%
| 5035-79-0 |
|
Murexide
| 3051-09-0 |
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(1-Amino-1-methylpropyl)phosphonic acid, 97%
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DL-Aspartic Acid, 99+%
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| 95-47-6 |
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p-Toluenesulfonic Acid Monohydrate
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Copper (II) Bromide, Anhydrous, 99+%
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Pancreatin (Powder)
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|
(1-Amino-1-methylbutyl)phosphonic acid, 97%
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|
(1-Amino-1,2-dimethylpropyl)phosphonic acid, 97%
| 101804-01-7 |
|
Tin (II) Chloride Dihydrate, P.A.
| 10025-69-1 |
|
(1-Amino-1,3-dimethylbutyl)phosphonic acid, 97%
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|
Poly(vinyl alcohol), 88% Hydrolyzed Average M.W. 88.000
| 9002-89-5 |
|
(1-Amino-1-cyclopentyl)phosphonic acid, 97%
| 67550-64-5 |
|
Zinc acetate dihydrate, 98+%
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|
Ammonia, solution in methanol, ca. 7N
| 67-56-1 |
|
2-Amino-5-Chloropyridine, 98%
| 1072-98-6 |
|
Kinetin, 99%
| 525-79-1 |
|
FMOC-L-Leucine, 98%
| 35661-60-0 |
|
(1-Amino-1-cyclohexyl)phosphonic acid, 97%
| 67398-11-2 |
|
Cottonseed Oil, U.S.P.N.F.
| 8001-29-4 |
|
FMOC-L-Valine, 98%
| 68858-20-8 |
|
FMOC-L-Asparagine, 98%
| 71989-16-7 |
|
Brucine sulfate heptahydrate, reagent ACS
| 4845-99-2 |
|
(1-Aminopropyl)phosphonic acid, 97%
| 14047-23-5 |
|
Sodium phosphate monobasic, dihydrate, p.a.
| 7558-80-7 |
|
Kaolin, Monohydrate
| 1332-58-7 |
|
FMOC-L-Glutamic Acid-O-T-Butylester, Monohydrate, 98%
| 71989-18-9 |
|
Litmus, indicator grade
| 1393-92-6 |
|
Tween 20
| 9005-64-5 |
|
Sodium Hypochlorite, 13% Active Chlorine
| 7681-52-9 |
|
FMOC-O-T-Butyl-L-Threonine, 98%
| 71989-35-0 |
|
Boc-L-Asparagine, 99+%
| 7536-55-2 |
|
Manganese (II) chloride, 98%
| 7773-01-5 |
|
N,N'-Methylenebisacrylamide, for electrophoresis, 99+%
| 110-26-9 |
|
Cyanocobalamin, 96%
| 68-19-9 |
|
Sodium phosphate dibasic dihydrate, HPLC grade, 99+%
| 7558-79-4 |
|
2,5-Disulfoaniline, 95%
| 98-44-2 |
|
2,3,4,5,6-Pentabromotoluene, 99%
| 87-83-2 |
|
2,4-Dibromo-6-nitroaniline, 98%
| 827-23-6 |
|
2,3-Dimethylthiophene, 97%
| 0-01-1 |
|
Tin, Mossy, 99.8%
| 7440-31-5 |
|
FMOC-O-T-Butyl-L-Serine, 98%
| 71989-33-8 |
|
|