**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7681-52-9 |Sodium hypochlorite | aq.soln. | 231-668-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: O C
Risk Phrases: 31 34 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with acids liberates toxic gas. Causes burns. Contact with
combustible material may cause fire.Corrosive.Light
sensitive.Oxidizer.Toxic.
Potential Health Effects
Eye:
Causes eye burns. Causes redness and pain.
Skin:
Causes skin burns. Causes redness and pain.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. Causes gastrointestinal tract burns. Overexposure may cause
methemoglobinemia.
Inhalation:
Harmful if inhaled. May cause severe irritation of the respiratory
tract with sore throat, coughing, shortness of breath and delayed
lung edema. Causes chemical burns to the respiratory tract.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Do NOT induce
vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls
of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Substance is noncombustible. Oxidizer. Greatly
increases the burning rate of combustible materials. Containers may
explode in the heat of a fire.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Do NOT get water inside containers. For small fires, use dry
chemical, carbon dioxide, or water spray. For large fires, use dry
chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after
fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Remove all sources of ignition. Use
a spark-proof tool. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood. Discard
contaminated shoes.
Storage:
Do not store in direct sunlight. Store in a tightly closed
container. Store in a dry area. Corrosives area. Keep refrigerated.
(Store below 4C/39F.) Do not get water inside containers.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
Exposure Limits
CAS# 7681-52-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: Disagreeable, sweetish odor
pH: Not available.
Vapor Pressure: 17.5 mm Hg @ 20
Viscosity: mPas 20 deg C
Boiling Point: Not available.
Freezing/Melting Point: -16 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density: 1.2090g/cm3
Molecular Formula: ClNaO
Molecular Weight: 74.44
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Light, combustible materials, strong acids, temperatures above 40C.
Incompatibilities with Other Materials:
Strong acids, amines, ammonia, ammonium salts, reducing agents,
metals, formic acid, methanol, formic acid, and phenylacetonitrile.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, irritating and toxic fumes and gases,
sodium oxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7681-52-9: NH3486300
LD50/LC50:
CAS# 7681-52-9: Draize test, rabbit, eye: 10 mg Moderate; Draize
test, rabbit, eye: 1.31 mg Mild; Oral, mouse: LD50 = 5800 mg/kg.
Carcinogenicity:
Sodium hypochlorite -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
LC50 (48 hr) rainbow trout: 0.07 mg/l [Nikunen, E. Ecotoxicol.
Environ. Saf. 1985, 9, 84-91] LC50 (96 hr) fathead minnow: 5.9 mg/l
[Curtis, M. W. et al J. Hydrol. 1981,51,359]
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: HYPOCHLORITE SOLUTION
Hazard Class: 8
UN Number: 1791
Packing Group: III
IMO
Shipping Name: HYPOCHLORITE SOLUTION
Hazard Class: 8
UN Number: 1791
Packing Group: III
RID/ADR
Shipping Name: HYPOCHLORITE SOLUTION
Hazard Class: 8
UN Number: 1791
Packing group: III
USA RQ: CAS# 7681-52-9: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O C
Risk Phrases:
R 31 Contact with acids liberates toxic gas.
R 34 Causes burns.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 50 Do not mix with ... (to be specified by the
manufacturer).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7681-52-9: 2
Canada
CAS# 7681-52-9 is listed on Canada's DSL List.
CAS# 7681-52-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7681-52-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/27/1998 Revision #4 Date: 10/29/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(1-Amino-2,2-dimethylpropyl)phosphonic acid, 97%
| 125078-15-1 |
|
Yttrium(iii)-oxide, 99.99%
| 1314-36-9 |
|
Tetracycline Hydrochloride,"Can be Used as Secondary Standard"
| 64-75-5 |
|
Erythromycin
| 114-07-8 |
|
Glyoxal, 40 wt. % solution in water
| 107-22-2 |
|
4-Chloro-1-Naphthol, 99% (Titr.)
| 604-44-4 |
|
Dextran (Low Fraction)
| 9004-54-0 |
|
(1-Amino-1-methylethyl)phosphonic acid, 97%
| 5035-79-0 |
|
Murexide
| 3051-09-0 |
|
(1-Amino-1-methylpropyl)phosphonic acid, 97%
| 62879-51-0 |
|
DL-Aspartic Acid, 99+%
| 617-45-8 |
|
o-Xylene
| 95-47-6 |
|
p-Toluenesulfonic Acid Monohydrate
| 104-15-4 |
|
Copper (II) Bromide, Anhydrous, 99+%
| 7789-45-9 |
|
Pancreatin (Powder)
| 8049-47-6 |
|
(1-Amino-1-methylbutyl)phosphonic acid, 97%
| 125078-17-3 |
|
(1-Amino-1,2-dimethylpropyl)phosphonic acid, 97%
| 101804-01-7 |
|
Tin (II) Chloride Dihydrate, P.A.
| 10025-69-1 |
|
(1-Amino-1,3-dimethylbutyl)phosphonic acid, 97%
| 125078-18-4 |
|
Poly(vinyl alcohol), 88% Hydrolyzed Average M.W. 88.000
| 9002-89-5 |
|
(1-Amino-1-cyclopentyl)phosphonic acid, 97%
| 67550-64-5 |
|
Zinc acetate dihydrate, 98+%
| 5970-45-6 |
|
Ammonia, solution in methanol, ca. 7N
| 67-56-1 |
|
2-Amino-5-Chloropyridine, 98%
| 1072-98-6 |
|
Kinetin, 99%
| 525-79-1 |
|
FMOC-L-Leucine, 98%
| 35661-60-0 |
|
(1-Amino-1-cyclohexyl)phosphonic acid, 97%
| 67398-11-2 |
|
Cottonseed Oil, U.S.P.N.F.
| 8001-29-4 |
|
FMOC-L-Valine, 98%
| 68858-20-8 |
|
FMOC-L-Asparagine, 98%
| 71989-16-7 |
|
Brucine sulfate heptahydrate, reagent ACS
| 4845-99-2 |
|
(1-Aminopropyl)phosphonic acid, 97%
| 14047-23-5 |
|
Sodium phosphate monobasic, dihydrate, p.a.
| 7558-80-7 |
|
Kaolin, Monohydrate
| 1332-58-7 |
|
FMOC-L-Glutamic Acid-O-T-Butylester, Monohydrate, 98%
| 71989-18-9 |
|
Litmus, indicator grade
| 1393-92-6 |
|
Tween 20
| 9005-64-5 |
|
Sodium Hypochlorite, 13% Active Chlorine
| 7681-52-9 |
|
FMOC-O-T-Butyl-L-Threonine, 98%
| 71989-35-0 |
|
Boc-L-Asparagine, 99+%
| 7536-55-2 |
|
Manganese (II) chloride, 98%
| 7773-01-5 |
|
N,N'-Methylenebisacrylamide, for electrophoresis, 99+%
| 110-26-9 |
|
Cyanocobalamin, 96%
| 68-19-9 |
|
Sodium phosphate dibasic dihydrate, HPLC grade, 99+%
| 7558-79-4 |
|
2,5-Disulfoaniline, 95%
| 98-44-2 |
|
2,3,4,5,6-Pentabromotoluene, 99%
| 87-83-2 |
|
2,4-Dibromo-6-nitroaniline, 98%
| 827-23-6 |
|
2,3-Dimethylthiophene, 97%
| 0-01-1 |
|
Tin, Mossy, 99.8%
| 7440-31-5 |
|
FMOC-O-T-Butyl-L-Serine, 98%
| 71989-33-8 |
|
|