UNITED LABORATORIES -- UNITED 477 BEST SHOT
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Material Safety Data Sheet
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MSDS Num: CJGYC
MSDS NAME: UNITED 477 BEST SHOT
Responsible Party
Name: UNITED LABORATORIES
Address: 320 37TH AVENUE
City: ST CHARLES IL 60174
Info Phone: 800-323-2594
Emergency Phone Number: 800-323-2594;800-535-5053
Review Ind: Y
Published: Y
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Contractor Summary
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Name: UNITED LABORATORIES
Address: 320 37TH AVENUE
City: ST CHARLES IL 60174
Phone: 800-323-2594
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Ingredients
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Cas: 7664-93-9
RTECS #: WS5600000
Name: SULFURIC ACID
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3
ACGIH STEL: 3 MG/M3
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 64742-47-8
RTECS #: OA5504000
Name: KEROSENE (PETROLEUM), HYDROTREATED; (PETROLEUM DISTILLATES)
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Cas: 95-49-8
RTECS #: XS9000000
Name: O-CHLOROTOLUENE; (CHLOROTOLUENE)
ACGIH TLV: 259 MG/M3;50 PPM
ACGIH STEL: NOT ESTABLISHED
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: EYES: MAY CAUSE SEVERE BURNS AND BLINDNESS. DO NOT WEAR
CONTACT LENSES. SKIN: MAY CAUSE SEVERE BURNS. INHALATION: MAY CAUSE HEADACHE,
DROWSINESS AND CENTRAL NERVOUS SYSTEM DEPRESSION. INGESTION: MAY C AUSE
SEVERE BURNS TO MOUTH, THROAT AND STOMACH. MAY DAMAGE AND POISON THE LIVER,
KIDNEYS AND CENTRAL NERVOUS SYSTEM. MAY BE FATAL. TARGET ORGANS: LIVER,
KIDNEY, CENTRAL NERVOUS SYSTEM, RESPIRATORY SYS TEM, SKIN AND ANY CONTACTED
TISSUE.
Explanation Of Carcinogenicity: SULFURIC ACID: IARC MONOGRAPHS, VOL 54, PG 41,
1992: GROUP 1.
Signs And Symptions Of Overexposure: CONTACT W/LIQUID, MIST OR VAPOR MAY CAUSE
IMMEDIATE IRRITATION W/SEVERE BURNS TO ALL EXPOSED TISSUE. SEVERITY OF BURN
IS USUALLY DETERMINED BY THE CONCENTRATION OF THE ACID & DURATION OF
EXPOSURE. EYE S: MAY RESULT IN CONJUNCTIVITIS &/OR PERMANENT LOSS OF
VISION. SKIN: REPEATED SKIN CONTACT MAY RESULT IN DERMATITIS & SKIN
LESIONS. INHAL: VAPOR OR MIST MAY RESULT IN EROSION OF TEETH, INFLAMMATION OF
MOUTH, TRACHEA-BRONCHITIS & DAMAGE TO RESPIRATORY SYSTEM. INGEST: MAY
CAUSE SEVERE BURNS & DAMAGE TO LIVER, KIDNEYS & CNS. MAY BE FATAL.
Medical Cond Aggravated By Exposure: DERMATITIS AND DENTAL EROSION.
First Aid: EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 30 MINUTES LIFTING UPPER
& LOWER LIDS TO ENSURE THOROUGH RINSING. CALL PHYSICIAN OR POISON CONTROL
CENTER. SKIN: WASH W/PLENTY OF SOAP & WATER & REMOVE CONTA MINATED
CLOTHING IMMEDIATELY. CALL PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
INHAL: GET PATIENT TO FRESH AIR IMMEDIATELY. IF PATIENT IS NOT BREATHING
APPLY CPR IF NEEDED. CALL PHYSICIAN OR POISO N CONTROL CENTER IMMEDIATELY.
INGEST: IF CONSCIOUS, GIVE LARGE AMOUNTS TO MILK OR WATER AT ONCE. DO NOT
INDUCE VOMITING. CALL PHYSICIAN OR POISON CENTER IMMEDIATELY.
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Handling and Disposal
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Spill Release Procedures: WEAR PROTECTIVE EQUIPMENT AND CLOTHING BEFORE
ENTERING AREA. VENTILATE AREA. AVOID CONTACT WITH SKIN AND EYES. NEUTRALIZE
SPILL WITH SODA ASH. FLUSH AREA WITH WATER USING CARE. UNNEUTRALIZED ACID
WILL GENERATE HEAT WHEN MIXED WITH WATER.
Neutralizing Agent: NEUTRALIZE SPILL WITH SODA ASH.
Waste Disposal Methods: CONSULT LOCAL, STATE, AND FEDERAL AUTHORITIES FOR
PROPER DISPOSAL GUIDELINES.
Handling And Storage Precautions: STORE IN A SECURE AREA OUT OF REACH OF
CHILDREN AND UNAUTHORIZED PERSONS. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN
USE. DO NOT STORE NEAR INCOMPATIBLE MATERIALS, SUCH AS STRONG ALKALIS OR
FLAMMABLES . STORE IN COOL, DRY, WELL-VENTILATED AREA. DO NOT ADD WATER TO
CONCENTRATED ACID.
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point: =51.7C, 125.F
Flash Point Text: UPPER LAYER
Lower Limits: 1%(SUPDAT)
Upper Limits: 8%(SUPDAT)
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL OR FOAM.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). USE WATER SPRAY TO COOL SEALED CONTAINERS EXPOSED TO FIRE.
STAY UPWIND IF PRODUCT IS INVOLVED IN FIRE. WATER APPLIED DIRECTLY TO SUL
FURIC ACID CAUSES EVOLUTION OF HEAT AND SPATTERING.
Unusual Fire/Explosion Hazard: SULFURIC ACID IS HIGHLY REACTIVE AND CAPABLE OF
IGNITING FINELY DIVIDED COMBUSTIBLE MATERIALS ON CONTACT. REACTS VIOLENTLY
WITH WATER AND ORGANIC MATERIAL TO EVOLVE HEAT. MAY REACT WITH METALS TO RELE
ASE HYDROGEN GAS.
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Control Measures
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Respiratory Protection: IF TLV IS EXCEEDED, WEAR NIOSH APPROVED RESPIRATOR FOR
ACIDS MIST.
Ventilation: MECHANICAL (GENERAL): MAINTAIN ADEQUATE VENTILATION. LOCAL
EXHAUST: HOOD OR FAN IS RECOMMENDED.
Protective Gloves: RUBBER OR NEOPRENE GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH FACESHIELD
(FP N).
Other Protective Equipment: ANSI APPROVED EYE WASH AND DELUGE SHOWER (FP N).
IMPERVIOUS CLOTHING, LONG-SLEEVED SHIRTS, RUBBER APRON AND SHOES ARE
RECOMMENDED.
Work Hygienic Practices: WASH HANDS AND FACE WITH SOAP AND WATER AFTER USING
THIS PRODUCT. REMOVE CONTAMINATED CLOTHING IMMEDIATELY; WASH THOROUGHLY WITH
SOAP AND WATER BEFORE REUSING.
Supplemental Safety and Health: LEL & UEL: FOR UPPER LAYER. VOC: 0.086
POUNDS PER PINT OF PRODUCT. SOL IN H*2O: LOWER PHASE COMPLETELY MISCIBLE;
UPPER PHASE IMMICIBLE.
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Physical/Chemical Properties
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Boiling Point: =160.C, 320.F
M.P/F.P Text: NOT DETERMINED
Vapor Pres: <1 MM HG @77F
Vapor Density: >1(AIR=1)
Spec Gravity: 1.85 (H2O=1)
PH: 1
Solubility in Water: SUPDAT
Appearance and Odor: TWO PHASES:UPPER LAYER CLEAR WITH AROMATIC ODOR; LOWER
LAYER DARK RED
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: KEEP AWAY FROM HEAT OR OPEN FLAME.
Materials To Avoid: AVOID CONTACT WITH ORGANIC CHLORATES, CARBIDES, FULMINATES,
PICRATES, NITRATES, POWDERED METALS, OTHER COMBUSTIBLE MATERIALS AND STRONG
ALKALIS.
Hazardous Decomposition Products: OXIDES OF SULFUR AND CARBON MAY BE FORMED
UPON SEVERE HEATING.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Sara Title III Information: SARA TITLE III QUANTITIES: SULFURIC ACID: 1.60
POUNDS OF REPORTABLE MATERIAL PER PINT BOTTLE OF UNITED PRODUCT.
State Regulatory Information: NO INGREDIENTS LISTED ON CALIFORNIA PROPOSITION
65.
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Other Information
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HAZCOM Label
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MSDS NAME: UNITED 477 BEST SHOT
Company: UNITED LABORATORIES
Street: 320 37TH AVENUE
City: ST CHARLES IL
Zipcode: 60174
Health Emergency Phone: 800-323-2594;800-535-5053
Label Required IND: Y
Date Of Label Review: 06/29/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Moderate
Reactivity Hazard: Slight
Hazard And Precautions: CORROSIVE. ACUTE: EYES: MAY CAUSE SEVERE BURNS AND
BLINDNESS. DO NOT WEAR CONTACT LENSES. SKIN: MAY CAUSE SEVERE BURNS.
INHALATION: MAY CAUSE HEADACHE, DROWSINESS AND CENTRAL NERVOUS SYSTEM
DEPRESSION . INGESTION: MAY CAUSE SEVERE BURNS TO MOUTH, THROAT AND STOMACH.
MAY DAMAGE AND POISON THE LIVER, KIDNEYS AND CENTRAL NERVOUS SYSTEM. MAY BE
FATAL. TARGET ORGANS: LIVER, KIDNEY, CENTRAL NERVOUS SYSTE M, RESPIRATORY
SYSTEM, SKIN AND ANY CONTACTED TISSUE. CHRONIC: CANCER HAZARD. CONTAINS
SULFURIC ACID WHICH IS LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N).
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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