MINOLTA CORPORATION -- MT TONER, EP8603
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Material Safety Data Sheet
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MSDS Num: CJGVM
MSDS NAME: MT TONER, EP8603
Responsible Party
Name: MINOLTA CORPORATION
Address: 101 WILLIAMS DRIVE
City: RAMSEY NJ 07446-1217
Info Phone: 201-825-4000
Emergency Phone Number: LOC POIS CTL CTR
Resp. Party Other MSDS No.: PPC-025
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: MINOLTA CORPORATION
Address: 101 WILLIAMS DRIVE
City: RAMSEY NJ 07446
Phone: 201-825-4000
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Item Description Information
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: LD50:(ORAL,RAT) >5 G/KG.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: FOR HUMAN HLTH:THIS TONER IS NOT CLASSIFIED AS HUMAN
CARCIN. NO SYMPS EXPECTED UNDER INTENDED USE. TOX DATA: ACUTE TOX:
LC50:(INHAL,RAT) >1.79 G/M3/4H) (THIS WAS HIGHEST ATTAINABLE CONC). LD50:
(DERMA L) NO DATA AVAIL. EYE IRRIT:MILD CONJ IRRIT (RABBITS). SKIN IRRIT:NOT
IRRIT (RABBITS). SKIN SENSITIZER:NO SIGNS (GUINEA-PIG). MUTAGENICITY:NEG
(AMES TEST). LOC EFTS:NO DATA AVAIL. CHRONIC/ LONG TERM T OX:PRLNG INHAL OF
EXCESSIVE DUST MAY CAUSE LUNG DMG. IT IS ATTRIBUTED TO "LUNG OVERLOADING",
GENERIC RESPONSE TO EXCESSIVE AMTS OF ANY DUST RETAINED IN LUNGS FOR PRLNG
INTERVAL. USE OF THIS PROD, AS I NTENDED, DOES NOT RSLT (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: CARBON BLACK: IARC MONOGRAPHS ON EVALUATION OF
CARCIONGENIC RISK OF CHEMICALS TO MAN, VOL 65, PG 149, 1996: GROUP 2B.
Signs And Symptions Of Overexposure: HLTH HAZ:IN INHAL OF EXCESSIVE DUST. IN
STUDY IN RATS BY CHRONIC INHAL EXPOS TO TYPICAL TONER, MILD TO MOD DEGREE OF
LUNG FIBROSIS WAS OBSERVED IN 92% OF RATS IN HIGH CONC (16 MG/M3) EXPOS GRP,
MIN TO MILD DEGREE OF FIBROSIS WAS NOTED IN 22% OF ANIMALS IN MIDDLE (4
MG/M3) EXPOSURE GRP. BUT NO PULM CHANGE WAS REPORTED IN LOWEST (1 MG/M3)
EXPOS GRP, MOST RELEVANT LEVEL TO POTNTL HUMAN EXPOS. CARCINO GENICITY: IARC
MONOGRAPHS; NTP (USA); OSHA REGULATED (USA): NOT LISTED BY MFR. IN 1996 IARC
REEVALUATED CARBON BLACK AS GRP 2B CARCIN (POSS HUMAN CARCIN). THIS EVAL IS
GIVEN TO CARBON BLACK FOR WHICH THERE IS (TOX INFO)
First Aid: INHAL:IF SYMPS ARE EXPERIENCED, REMOVE SOURCE OF CONTAM OR MOVE
VICTIM TO FRESH AIR & OBTAIN MED ADVICE. SKIN:FLUSH W/GENTLY FLOWING
WATER (LUKEWARM PREFERABLE) & SOAP FOR 15 MINS OR UNTIL PARTICLE IS
REMOVED. IF IRRIT DOES OCCUR, OBTAIN MED ADVICE. EYES:DO NOT ALLOW VICTIM TO
RUB EYE(S). FLUSH W/GENTLY FLOWING WATER (LUKEWARM PREFERABLE) FOR AT LST 15
MINS OR UNTIL PARTICLE IS REMOVED. HAVE VICTI M LOOK RIGHT & LEFT, AND,
THEN UP & DOWN. IF IRRIT DOES OCCUR, OBTAIN MED ATTN. DO NOT ATTEMPT TO
MANUALLY REMOVE ANYTHING STUCK TO EYE(S). INGEST: IF IRRIT OR DISCOMFORT
OCCUR, OBTAIN MED ATTN IMMED. NOTE TO MD:NONE.
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Handling and Disposal
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Spill Release Procedures: PERSONAL PRECAUTIONS & ENVIRONMENTAL PRECAUTIONS:
NONE. METHODS FOR CLEANING UP: WIPE OFF WITH PAPER OR CLOTH. DO NOT USE
VACUUM CLEANER WHEN RELEASED A LARGE AMOUNT. IT, LIKE MOST FINELY DIVIDED
ORGA NIC POWDERS, MAY CREATE A DUST EXPLOSION.
Waste Disposal Methods: PREPARATION (COMMUNITY PROVISIONS) & CONTAMINATED
PACKAGING: WASTE MAY BE DISPOSED OR INCINERATED UNDER CONDITIONS WHICH MEET
ALL FEDERAL, STATE & LOCAL ENVIRONMENTAL REGULATIONS.
Handling And Storage Precautions: SAFE HANDLING ADVICE: TRY NOT TO DISPERSE THE
PARTICLES WHEN HANDLING A LARGE AMOUNT. STORAGE CONDITIONS: KEEP CONTAINER
CLOSED. STORE IN A COOL & DRY PLACE. PACKING MATERIALS: BOTTLES OR
CARTRIDGE DE SIGNATED BY MINOLTA. TECHNICAL MEASURES, PRECAUTIONS &
INCOMPATIBLE PRODUCTS: NONE.
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Fire and Explosion Hazard Information
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Autoignition Temp: =450.C, 842.F
Lower Limits: NOT AVAIL
Upper Limits: NOT AVAIL
Extinguishing Media: CO*2, WATER SPRAY, FOAM & DRY CHEMICAL. EXTINGUISHING
MEDIA TO AVOID: FULL WATER JET.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). NO SPECIAL FIREFIGHTING PROCEDURES.
Unusual Fire/Explosion Hazard: IF DISPERSED IN AIR, LIKE MOST FINELY DIVIDED
ORGANIC POWDERS, MAY FORM AN EXPLOSIVE MIXTURE. FLAMMABILITY: NO DATA
AVAILABLE. OXIDIZING PROPERTIES: NO DATA AVAILABLE. RATING: HEALTH: 0.
FLAMMABI LITY: 1. REACTIVITY: 1.
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Control Measures
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Respiratory Protection: NONE REQUIRED WHEN USED AS INTENDED IN MINOLTA
EQUIPMENT. FOR USE OTHER THAN NORMAL CUSTOMER-OPERATING PROCEDURES (SUCH AS
IN BULK TONER PROCESSING FACILITIES), NIOSH APPROVED RESPIRATORS MAY BE REQUI
RED.
Ventilation: NONE REQUIRED UNDER INTENDED USE.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: EMERGENCY EYE WASH & DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). SKIN PROTECTION: NONE REQUIRED WHEN USED AS INTENDED
IN MINOLTA EQUIPMENT.
Work Hygienic Practices: WASH HANDS AFTER HANDLING.
Supplemental Safety and Health: CONTROL PARAMETERS (AS TDUST): OSHA-PEL
(USA):15 MG/M3. ACGIH-TLV (USA):10 MG/M3. DFG-MAK (EC):6 MG/M3. WORKSAFE-TWA
(AUSTL):10 MG/M3. PHYSICAL DATA: SOFTENING POINT:120-125C. PARTITION
COEFFICIENT, N -OCTAGONAL/WATER:N/A. OTHER INFO:R. KILPPER, J. C. MACKENZIE,
P. MORROW, U. MOHR, S. TAKENAKA, & MERMELSTEIN (1991).
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Physical/Chemical Properties
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M.P/F.P Text: NO DATA AVAILABLE
Decomp Temp: >280.C, 536.F
Spec Gravity: 1.15; (BULK) 0.42.
Solubility in Water: NEGLIGIBLE
Appearance and Odor: SOLID, BLACK POWDER; FAINT ODOR. PARTICLE SIZE (U M):
10-20.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: ELECTRONIC DISCHARGE, THROWING INTO FIRE.
HAZARDOUS REACTIONS: DUST EXPLOSION, LIKE MOST FINELY DIVIDED ORGANIC
POWDERS.
Materials To Avoid: OXIDIZING MATERIALS.
Hazardous Decomposition Products: CO, CO*2.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: EFTS OF OVEREXP:INADEQUATE HUMAN EVIDENCE, BUT
SUFFICIENT ANIMAL EVIDENCE. THE LATTER IS BASED UPON DEVELOPMENT OF LUNG
TUMORS IN RATS RECEIVING CHRONIC INHALATION EXPOSURES TO FREE CARBON BLACK AT
LE VELS THAT INDUCE PARTICLE OVERLOAD OF LUNG. STUDIES PERFORMED IN ANIMAL
MODELS OTHER THAN RATS HAVE NOT DEMONSTRATED AN ASSOCIATION BETWEEN CARBON
BLACK & LUNG TUMORS. MOREOVER, A TWO-YEAR CANCER BIOA SSAY USING A
TYPICAL TONER PREPARATION CONTAINING CARBON BLACK DEMONSTRATED NO ASSOCIATION
BETWEEN TONER EXPOSURE AND TUMOR DEVELOPMENT IN RATS.
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Ecological Information
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MSDS Transport Information
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Transport Information: SPECIAL PRECAUTIONS: NONE. INFORMATION ON CODE AND
CLASSIFICATIONS ACCORDING TO INTERNATIONAL REGULATIONS: UN CLASSIFICATION:
NONE. LAND: RID (EC): NONE. ADR (EC): NONE. DOT (USA): NONE. INLAND WATERW
AYS: ADNR (RHINE R): NONE. SEA: IMDG: NONE. AIR: ICAO-TI: NONE. IATA-DGR:
NONE.
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Regulatory Information
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Sara Title III Information: 302 EXTREME HAZARDOUS SUBSTANCE: NONE. 311/312
HAZARD CATEGORIES: NONE. 313 REPORTABLE INGREDIENTS: NONE.
Federal Regulatory Information: U.S. INFORMATION: INFORMATION ON LABEL: NOT
REQUIRED. TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL CHEMICAL SUBSTANCES IN
THIS PRODUCT COMPLY WITH ALL APPLICABLE RULES OR ORDER UNDER TSCA. EU
INFORMATION: INFORMATION ON LABEL (88/379/EEC & 67/548/EEC): SYMBOL
& INDICATION: NOT REQUIRED. R-PHRASE: NOT REQUIRED. S-PHRASE: NOT
REQUIRED. 76/769/EEC: ALL CHEMICAL SUBSTANCES IN THIS PRODUCT COMPLY WITH ALL
APPLICABLE RULES OR ORDER UNDER 76/769/EEC.
State Regulatory Information: CALIFORNIA PROPOSITION 65: THIS PRODUCT CONTAINS
NO CHEMICAL SUBSTANCES SUBJECT TO CALIFORNIA PROPOSITION 65.
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Other Information
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Other Information: LITERATURE REFERENCES: ANSI Z400.1-1993. TRGS
220:SINCGERHEITSDATENBLATT FUR GEFAHRLICHE STOFFE UND ZUBEREITUNGEN. ISO
11014-1. COMMISSION DIRECTIVE 93/112/EC. MSDS:PRACTICAL GUIDE TO FIRST
AID:CANADI AN CENTRE FOR OSHA'S PUBLICATION. IMPLEMENTATION MANUAL:NATL PAINT
& COATINGS ASSOCN. IARC(1996):IARC MONOGRAPHS ON EVAL OF CARCIN RISK OF
CHEMS TO HUMANS, VOL 65, PRINTING PROCESS & PRINTING INKS , CARBON BLACK
& SOME NITRO CMPDS, LYON, PP.149-261. PULM RESPONSE TO TONER UPON CHRONIC
INHAL EXPOS TO RATS: FUNDAMENTAL & APPLIED TOX 17, PP.280-299. H. MUHLE,
B. BELLMANN, O. CREUTZENBERG, C. DASEN BROCK, H. ERNST, (SUPP DATA)
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HAZCOM Label
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MSDS NAME: MT TONER, EP8603
Company: MINOLTA CORPORATION
Street: 101 WILLIAMS DRIVE
City: RAMSEY NJ
Zipcode: 07446
Health Emergency Phone: LOC POIS CTL CTR
Label Required IND: Y
Date Of Label Review: 03/30/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EYE: MILD CONJUNCTIVITIS, IRRITATION.
CHRONIC: CANCER HAZARD. CONTAINS MATERIAL WHICH IS LISTED AS AN ANIMAL LUNG
CARCINOGEN (FP N). PROLONGED INHALATION OF EXCESSIVE DUST MAY CAUSE LUNG
DAMAGE. IT IS ATTRIBUTED TO "LUNG OVERLOADING", A GENERIC RESPONSE TO
EXCESSIVE AMOUNTS OF ANY DUST RETAINED IN LUNGS FOR PROLONGED INTERVAL.
POSSIBLE LUNG FIBROSIS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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