===================== Product Identification =====================
MSDS NAME:SULFURIC ACID, 52-100%
NIIN:01-432-0063
Status Code:A
MSDS Number: CJFYH
=== Responsible Party ===
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:(800)424-9300
Resp. Party Other MSDS Num.:S8234
Preparer's Name:STRATEGIC SVC DIV
Chemtrec Ind/Phone:(800)424-9300
CAGE:70829
=== Contractor Identification ===
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
Company:PHOENIX INDUSTRIES INC
Address:1519 CHAMBERLAYNE PARKWAY
Box:City:RICHMOND
State:VA
ZIP:23222
Country:US
Phone:804-264-5183/FAX: 264-5535
Contract Num:SP045099MC721
CAGE:0YED2
============= Composition/Information on Ingredients =============
Name:SULFURIC ACID
CAS:7664-93-9
RTECS #:WS5600000
Minumum % Wt:52.
Maxumum % Wt:100.
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
ACGIH STEL:3 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:0.
Maxumum % Wt:48.
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 ORAL RAT: 2140 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION PRODUCES DAMAGING EFFECTS
ON THE MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. SWALLOWING CAN
CAUSE SEVERE BURNS TO THE MOUTH, THROAT & STOMACH, LEADING TO
DEATH. SKIN CONTACT MAY CAUSE REDNE SS, PAIN & SEVERE BURNS. EYE
CONTACT CAN CAUSE BLURRED VISION, REDNESS, APIN & SEVERE BURNS,
BLINDNESS. CHRONIC EXPOSURE TO MIST OR VAPORS MAY CAUSE DAMAGE TO
TEETH. CHRONIC EXPOSURE TO MISTS CONTAINI NG SUFURIC ACID IS A
CANCER HAZARD.
Explanation of Carcinogenicity:THE INTERNATIONAL AGENCY FOR RESEARCH ON
CANCER (IARC) HAS CLASSIFIED "STRONG INORGANIC ACID MISTS
CONTAINING SULFURIC ACID" AS A KNOWN HUMAN CARCINOGEN, (IARC
CATAGORY 1). THIS CLASSIFICATION APPLIES TO MISTS CONTAINING
SULFURIC ACID AND NOT TO SULFURIC ACID OR SULFURIC ACID SOLUTIONS.
Effects of Overexposure:INHALED-IRRITATION OF THE NOSE & THROAT,
LABORED BREATHING, LUNG EDEMA. INGESTION-BURNS TO MOUTH, THROAT
&STOMACH, SORETHROAT, VOMITING, DIARRHEA, CIRCULATORY COLLAPSE WITH
CLAMMY SKIN, WAEK RAPID PUL SE, SHALLOW RESPIRATIONS, SCANTY URINE.
SKIN-REDNESS, PAIN, SEVERE BURNS, CIRCULATORY COLLAPSE WITH CLAMMY
SKIN, WEAK/RAPID PULSE, SHALLOW RESPIRATIONS, SCANTY URINE.
EYES-BLURRED VISION, REDNESS, PA IN, SEVERE TISSUE BURNS.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE
MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:INHALED-REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF
NOT BREATHING. GIVE OXYGEN IF BREATHING DIFFICULT. CALL PHYSICIAN
IMMEDIATELY. INGESTED-DO NOT INDUCE VOMITING! GIVE ALRGE QUANTITIES
OF WAT ER. NEVER ANYTHING BY MOUTH IF UNCONSCIOUS. CALL A PHYSICIAN
IMMEDIATELY. SKIN-IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15
MINUTES WHILE REMOVING CONTAMINATED CLOTHES. EXCESS ACID ON SKIN
CAN BE NEUT RALIZED WITH A 2% SOLUTION OF SODIUM BICARBONATE. CALL
A PHYSICIAN IMMEDIATELY. EYES-IMMEDIATELY FLUSH WITH WATER, LIFING
LIDS. CALL PHYSICIAN IMMEDIATELY.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE. DO NOT USE
WATER ON MATERIAL. HOWEVER, WATER SPRAY MAY BE USED TO KEEP FIRE
EXPOSED CONTAINERS COOL.
Fire Fighting Procedures:IN THE EVENT OF FIRE, WEAR FULL PROTECTIVE
CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH
FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE
PRESSURE MODE. STRUCTURA L FIREFIGHTER'S PROTECTIVE CLOTHING IS
INEFFECTIVE FOR FIRES INVOLVING THIS MATERIAL. STAY AWAY FROM
SEALED CONTAINERS.
Unusual Fire/Explosion Hazard:CONCENTRATED MATERIAL IS A STRONG
DEHYDRATING AGENT. REACTS WITH ORGANIC MATERIAL AND MAY CAUSE
IGNITION OF FINELY DIVIDED MATERIALS ON CONTACT.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. WEAR APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT. ISOLATE HAZARD AREA. KEEP UNECESSARY &
UNPROTECTED PERSONNEL AWAY. CONTAIN & RECOVER WHEN POSSIBLE.
NEUTRALIZE WITH ALKALINE MATERIAL (S ODA ASH, LIME) THEN ABSORB
WITH INERT MATERIAL (VERMICULITE, DRY SAND) & PLACE IN A CHEMICAL
WASTE CONTAINER. DO NOT USE COMBUSTIBLE MATERIALS SUCH AS SAWDUST.
Neutralizing Agent:ALKALINE MATERIAL SUCH AS SODA ASH, LIME.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A DRY, VENTILATED STORAGE
AREA WITH ACID RESISTANT FLOORS & GOOD DRAINAGE. PROTECT FROM
PHYSICAL DAMAGE. KEEP OUT OF DIRECT SUNLIGHT & AWAY FROM HEAT,
WATER & INCOMPATIBLE MATERIALS. DO NOT W ASH OUT CONTAINER & USE
FOR OTHER PURPOSES.
Other Precautions:WHEN DILUTING, ADD SULFURIC ACID TO WATER. WHEN
OPENING METAL CONTAINERS, USE NON-SPARKING TOOLS BECAUSE OF
POSSIBILITY OF HYDROGEN GAS BEING PRESENT. CONTAINERS OF THIS
MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT
RESIDUES (GAS, LIQUID). OBSERVE ALL WARNING & PRECAUTIONS LISTED ON
THE PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE LIMIT IS EXCEEDED, A FULL FACEPIECE
RESPIRATOR WITH ACID GAS CARTRIDGE & DUST/MIST FILTER MAY BE WORN
UP TO 50 TIMES THE EXPOSURE LIMIT OR THE MAXIMUM USE CONCENTRATION
SPECIFIED BY THE AP PROPRIATE REGUALTORY AGENCY/RESPIRATOR
SUPPLIER. FOR EMERGENCIES OR WHERE THE LEVELS ARE NOT KNOWN, USE A
FULL-FACE, POSITIVE-PRESSURE, AIR-SUPPLIED RESPIRATOR.
Ventilation:A SYSTEM OF LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED TO
KEEP EMPLOYEES EXPOSURES BELOW THE AIRBORNE EXPOSURE LIMITS.
Protective Gloves:WEAR IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL SAFETY GOGGLES AND/OR A FULL FACE SHIELD.
Other Protective Equipment:WEAR IMPERVIOUS PROTECTIVE CLOTHING
INCLUDING BOOTS, LAB COAT, APRON OR COVERALLS, AS APPROPRIATE, TO
PREVENT SKIN CONTACT. MAINTAIN EYE WASH FOUNTAIN AND QUICK-DRENCH
FACILITIES IN WORK AREA.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT BREATH
IST. DO NOT GET IN EYES, ON SKIN OR CLOTHES.
Supplemental Safety and Health
PRODUCT USE: LABORATORY REAGENT.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:=290.C, 554.F
Decomp Temp:=340.C, 644.F
Vapor Pres:1@145.8C
Vapor Density:3.4
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR OILY LIQUID, ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, POTASSIUM CHLORATE, POTASSIUM PERCHLORATE, POTASSIUM
PERMANGANATE, SODIUM, LITHIUM, BASES, ORGANIC MATERIAL, HALOGENS,
METAL ACETYLIDES, OXIDES AND HYDRIDES, METALS, STRONG OXIDIZING &
REDUCING AGENTS & MANY OTHER RE
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE
AND STORAGE. CONCENTRATED SOLUTIONS REACT VIOLENTLY WITH WATER,
SPATTERING AND LIBERATING HEAT.
Hazardous Decomposition Products:THERMAL DECOMPOSITION:OXIDES OF
SULFUR.WATER CONTACT:TOXIC & CORROSIVE FUMES.CARBONATE
REACTION:CARBON DIOXIDE. CYANIDES & SULFIES REACTIONS POISONOUS
HYDROGEN CYANIDE & HYDROGEN SULFIDE, RESPECTIVELY.
Conditions to Avoid Polymerization:HEAT, MOISTURE, INCOMPATIBLES.
=================== Toxicological Information ===================
Toxicological Information:ORAL RAT LD50: 2140 MG/KG; INHALATION RAT
LC50: 510 MG/M3/2HR; STANDARD DRAIZE, EYE RABBIT, 250 UG (SEVERE);
INVESTIGATED AS A TUMORIGEN, REPRODUCTIVE EFFECTOR. CANCER STATUS:
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) HAS
CLASSIFIED "STRONG INORGANIC ACID MISTS CONTAINING SULFURIC ACID AS
A KNWON HUMAN CARCINOGEN, (IARC CATEGORY 1). THIS CLASSIFICATION
APPLIES ONLY TO MISTS CONTAINING SULFURIC ACID & NOT TO SULFURIC
ACID OR SULFURIC ACID SOLUTIONS. SULFURIC ACID: NTP KNOWN: NO; NTP
ANTICIPATED: NO; IARC CATAGORY: NONE. WATER: NTP KNOWN: NO; NTP
ANTICIPATED: NO;IARC CATAGORY: NONE.
===================== Ecological Information =====================
Ecological:ENVIRONEMNTAL FATE: WHEN RELEASED INTO THE SOIL, MAY LEACH
INTO GROUNDWATER. WHEN RELEASED INTO THE AIR, MAY BE REMOVED FROM
ATMOSPHERE TO A MODERATE EXTENT BY WET DEPOSITION AND/OR DRY
DEPOSITION. EN VIRONEMNTAL TOXICITY: LC50 FLOUNDER 100-330 MG/L/48
HR/CONDITIONS NOT SPECIFIED; LC50 SHRIMP 80-90 MG/L/48
HR/CONDITIONS NOT SPECIFIED; LC50 PRAWN 42.5 PPM/48 HR SALT
WATER/CONDITIONS NOT SPECIFIED. T HIS MATERIAL MAY BE TOXIC TO
AQUATIC LIFE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR
RECYCLING SHOULD BE HANDLED AS A HAZARDOUS WASTE & SENT TO A RCRA
APPROVED INCINERATOR OR DISPOSED IN A RCRA APPROVED WASTE FACILITY.
PROCESSING, USE OR CONTAM INATION MAY CHANGE THE WASTE MANAGEMENT
OPTIONS. DISPOSE OF CONTAINER & UNUSED CONTENTS IAW FEDERAL, STATE
& LOCAL REGUALTIONS.
=================== MSDS Transport Information ===================
Transport Information:TRANSPORT BY LAND: SHIPPING NAME: SULFURIC ACID
(MORE THAN 51% ACID)HAZARD CLASS: 8; UN/NA: UN1830; PACKING GROUP
II; INFORMATION REPORTED FOR PRODUCT/SIZE 440 LB. INTERNATIONAL
(WATER, IMO): PROPER S HIPPING NAME: SULPHURIC ACID (WITH MORE THAN
51% ACID), HAZARD CLASS 8; UN/NA: UN1830; PACKING GROUP: II.
INFORMATION REPORTED FOR PRODUCT/SIZE: 440 LB.
===================== Regulatory Information =====================
SARA Title III Information:SULFURIC ACID: SARA 302-RQ=1000LB,
TPQ=1000LB; SARA 313 LIST: YES; CHEMICAL CATG: NO. SARA 311/312:
ACUTE-YES; CHRONIC-YES; FIRE-NO; PRESSURE-NO; REACTIVITY-YES
(PURE/LIQUID).
Federal Regulatory Information:SULFURIC ACID: TSCA-YES; CERCLA-1000 LB;
RCRA 261.33-NO; TSCA 8(D)-NO. TSCA 12(B)-NO.
State Regulatory Information:NONE SPECIFIED BY MANUFACTURER.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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