===================== Product Identification =====================
MSDS NAME:THINNER #2, 0522S1NL
NIIN:00N093424
Status Code:A
MSDS Number: CJXWQ
=== Responsible Party ===
Company:CARBOLINE CO
Address:350 S HANLEY INDUSTRIAL CT
City:ST. LOUIS
State:MO
ZIP:63144-1599
Country:US
Info Phone Num:314-644-1000
Emergency Phone Num:412-681-6669
Chemtrec Ind/Phone:(800)424-9300
CAGE:06634
=== Contractor Identification ===
Company:CARBOLINE CO
Address:350 S HANLEY INDUSTRIAL CT
Box:City:ST. LOUIS
State:MO
ZIP:63144-1599
Country:US
Phone:314-644-1000
CAGE:06634
============= Composition/Information on Ingredients =============
Name:TOLUENE. LD50 (ORAL, RAT): 2500 MG/KG; LD50 (INHALATION,
RAT): 18000 PPM/4HRS.
CAS:108-88-3
RTECS #:XS5250000
= Wt:80.
Other REC Limits:N/K
OSHA PEL:see Table Z-2
OSHA STEL:N/K
ACGIH TLV:188 MG/M3;50 PPM
ACGIH STEL:N/K
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:METHYL ETHYL KETONE. LD50 (ORAL, RAT): 2737 MG/KG; LD50
(INHALATION, RAT): 2000 PPM/H HRS.
CAS:78-93-3
RTECS #:EL6475000
= Wt:25.
Other REC Limits:N/K
OSHA PEL:590 MG/M3;200 PPM
OSHA STEL:N/K
ACGIH TLV:590 MG/M3;200 PPM
ACGIH STEL:885 MG/M3;300 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: HARMFUL IF INHALED, MAY
AFFECT THE BRAIN OR NERVOUS SYSTEM, CAUSING DIZZINESS, HEADACHE OR
NAUSEA. MAY CAUSE NOSE AND THROAT IRRITATION. EYES: MAY CAUSE
IRRITATION. SKIN: MAY CAUSE IRRITAT ION. NOTICE: REPORTS HAVE
ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO
SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. TOLUENE
APPEARS ON THE NAVY OCCUPATIONAL CHEMICAL REPR ODUCTIVE HAZARDS
LIST. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS
CONCERNING LATEST HAZARD LIST INFORMATION AND SAFE HANDLING AND
EXPOSURE INFORMATION .
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:IF YOU HAVE A CONDITION THAT COULD
BE AGGRAVATED BY EXPOSURE TO DUST OR ORGANIC VAPORS, SEE A
PHYSICIAN PRIOR TO USE.
======================= First Aid Measures =======================
First Aid:WHEN EXPOSED ALWAYS GET MEDICAL ATTENTION. EYES: FLUSH WITH
WATER FOR AT LEAST 15 MINUTES. SKIN: WASH WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND CLEAN BEFORE REUSE. INHALATION:
REMOVE TO FR ESH AIR. PROVIDE OXYGEN IF BREATHING IS DIFFICULT. USE
ARTIFICIAL RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING! ALWAYS GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:=-4.4C, 24.F
Lower Limits:1.3%
Upper Limits:10.1%
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . EVACUATE HAZARD AREA OF
UNPROTECTED PERSONNEL. COOL SURROUNDING CONTAINERS WITH WATER IN
CASE OF FIRE EXPOS URE.
Unusual Fire/Explosion Hazard:OSHA CLASSIFICATION: FLAMMABLE LIQUID.
VAPORS ARE HEAVIER THAN AIR AND WILL ACCUMULATE. VAPORS WILL FORM
EXPLOSIVE CONCENTRATIONS WITH AIR. VAPORS TRAVEL LONG DISTANCES AND
WILL FLASHBACK. USE MECHANI CAL VENTILATION WHEN NECESSARY TO KEEP
PERCENT VAPOR BELOW THE "LOWER EXPLOSION LEVEL" (LEL).
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. HANDLING
EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING. EVACUATE AREA OF
UNPROTECTED PERSONNEL. WEAR APPROPRIATE PERSONAL PROTECTIVE
CLOTHING & EQUIPMENT. FOLLOW SAFE HANDLING & USE GUIDELINES IN
HANDLING/STORAGE PROCEDURES SECTION. CONTAIN & SOAK UP RESIDUAL
W/ABSORBENT (CLAY/SAND). TAKE UP ABSORBENT MATERIAL & SEAL TIGHTLY
FOR PROPER DISPOSAL.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, OPEN
FLAME, AND STRONG OXIDIZING AGENTS. KEEP CONTAINERS CLOSED. STORE
IN COOL, DRY PLACE WITH ADEQUATE VENTILATION. IF POURING OR
TRANSFERRING MATERIALS, GROUND ALL CONTA INERS AND TOOLS.
Other Precautions:DO NOT WELD, HEAT, CUT OR DRILL ON FULL OR EMPTY
CONTAINERS. FOR INDUSTRIAL USE ONLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE ONLY WITH VENTILATION TO KEEP LEVELS BELOW
EXPOSURE GUIDELINES (SEE INGREDIENTS SECTION). USER SHOULD TEST AND
MONITOR EXPOSURE LEVELS TO INSURE ALL PERSONNEL ARE BELOW
GUIDELINES. IF NOT SURE OR IF NOT ABLE TO MONITOR USE NIOSH
APPROVED AIR-PURIFYING RESPIRATOR.
Ventilation:USE EXPLOSION-PROOF VENTILATION WHEN REQUIRED TO KEEP BELOW
HEALTH EXPOSURE GUIDELINES AND LOWER EXPLOSION LIMIT (LEL).
Protective Gloves:IMPERVIOUS GLOVES RECOMMENDED.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . IMPERVIOUS CLOTHING RECOMMENDED. IF MATERIAL PENETRATES TO
SKIN, CHANGE GLOVES AND CLOTHING.
Work Hygienic Practices:WASH WITH SOAP AND WATER BEFORE EATING,
DRINKING, APPLYING COSMETICS OR USING TOILET FACILITIES. USE OF A
HAND CLEANER IS RECOMMENDED. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. (SUP DAT)
Supplemental Safety and Health
HYGIENE PRACTICES: LEATHER SHOES CAN ABSORB AND PASS THROUGH HAZARDOUS
MATERIALS. CHECK SHOES CAREFULLY AFTER SOAKING BEFORE REUSE.
PHYSICAL/CHEMICAL PROPERTIES: VOLATILE BY WEIGHT: 100%; PRODUCT
WT/G AL: 7.1 LBS/U.S. GAL.
================== Physical/Chemical Properties ==================
Boiling Pt:>79.4C, 175.F
B.P. Text:175F TO 232F
Vapor Density:HVR/AIR
Spec Gravity:0.85
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS, AND OPEN FLAMES.
Hazardous Decomposition Products:CARBON MONOXIDE, NITROGEN OXIDES, &
UNIDENTIFIED ORGANIC COMPOUNDS. CONSIDER ALL SMOKE & FUMES FROM
BURNING MATL AS VERY HAZ. WELDING, CUTTING/ABRASIVE GRINDING CAN
CREATE SMOKE & FUMES. DO NOT BREATHE.
===================== Ecological Information =====================
Ecological:NO SPECIFIC INFO IS AVAIL. TOX OF ABCITE IS EXPECTED TO BE
LOW BASED ON INSOLUBILITY IN WATER. TOX INFO: GAIT & BALANCE, &
TREMORS. INDIVIDUALS W/WILSON'S DISEASE ARE AT INCR RISK OF COPPER
POISONING. CARBON BLACK - HUMAN STUDIES: EPIDEMIOLOGICAL STUDIES
OF WORKERS IN CARBON BLACK PRODUCING INDUSTRIES OF NORTH AMERICA &
WESTERN EUROPE SHOW SIGNIFICANT ADVERSE HLTH EFT DUE TO OCCUP EXPOS
TO CARBON BLACK. EARLY STUDIES IN FORMER USSR & EASTERN EUROPE RPT
RESP DISEASES AMONG WORKERS EXPOSED TO CARBON BLACK, INCL; BRONCH,
PNEUM, EMPHYSEMA & RHINITIS. (TRANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. REFER TO REGULATIONS SECTION FOR SARA TITLE
III AND CERCLA INFORMATION.
=================== MSDS Transport Information ===================
Transport Information:OSHA: FLAMMABLE LIQUID, 3, UN1263, PACKING GROUP
II. DOT: PAINT-RELATED MATERIAL, 3, UN1263, PACKING GROUP II.
CANADIAN TDGA: PAINT-RELATED MATERIAL, 3, UN1263, PACKING GROUP II.
===================== Regulatory Information =====================
SARA Title III Information:INGREDIENTS ARE NOT LISTED IN SARA SECTION
302. INGREDIENTS ARE LISTED IN SARA SECTION 313. SARA SECTIONS
311-312 CATEGORIES: 1, 2, 3.
Federal Regulatory Information:CERCLA REPORTABLE QUANTITY: TOLUENE:
1000 LBS/U220; METHYL ETHYL KETONE: 5000 LBS. WHMIS CLASSIFICATION:
B2 -- D2B.
State Regulatory Information:
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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