===================== Product Identification =====================
MSDS NAME:POLY-ETCH, MATNE503
NIIN:00N093362
Status Code:A
MSDS Number: CJXWS
=== Responsible Party ===
Company:MATHESON GAS PRODUCTS
Address:959 ROUTE 46 EAST
City:PARSIPPANY
State:NJ
ZIP:07054-0624
Country:US
Info Phone Num:905-668-3570
Emergency Phone Num:973-257-1100
Chemtrec Ind/Phone:(800)424-9300
CAGE:65169
=== Contractor Identification ===
Company:MATHESON TRI- GAS, INC.
Address:959 ROUTE 46 EAST
Box:City:PARSIPPANY
State:NJ
ZIP:07054-0624
Country:US
Phone:973-257-1100
CAGE:65169
============= Composition/Information on Ingredients =============
Name:TETRAETHYLENE GLYCOL DIMETHYL ETHER. EC NUMBER (EINECS):
205-594-7.
CAS:143-24-8
RTECS #:SB0400000
= Wt:73.86
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Name:SODIUM NAPHTHALENE COMPLEX. EC NUMBER (EINECS): 222-460-3.
CAS:3481-12-7
= Wt:26.14
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: IRRITATION (POSSIBLY
SEVERE), ITCHING, NAUS, VOMIT, DIARRHEA, DIFFICULTY BREATHING,
HDCH, DROW, SYMPS OF DRUNKENNESS, DIZZ, BLURRED VISION, BLUISH SKIN
COLOR, LUNG CONGESTION, KIDNEY & L IVER DAMAGE. SKIN: IRRIT
(POSSIBLY SEV). EYES: BURNS, BLINDNESS. INGEST: BURNS, DIFFICULTY
BREATHING, HDCH, DROW, SYMPS OF DRUNKENNESS, BLURRED VISION, KIDNEY
DAMAGE. CHRONIC: INHAL: SAME AS EFFECTS R EPORTED IN SHORT TERM
EXPOS, DIGESTIVE DISORDERS. SKIN: HDCH, DROW, SYMPS OF DRUNKENNESS,
BLURRED VISION, LUNG CONGESTION, KIDNEY & LIVER DAMAGE. EYES: NO
INFO ON SIGNIFICANT ADVERSE EFTS. INGEST: KID NEY & LIVER DAMAGE,
REPRODUCTIVE EFTS.
Effects of Overexposure:STATE REGS: INGEST: ING 2: MAY REACT W/MOISTURE
TO FORM SODIUM HYDROXIDE, AN ALKALINE CORR. SEE INFO ON ALKALINE
CORR. ING 1: GLYCOL ETHERS MAY CAUSE DIGESTIVE TRACT IRRIT, & CNS
DEPRESS W/HDCH, DROW, SLURRED SPEECH, RECRUDESCENT STUTTERING,
STAG GAIT, TREMOR, & BLURRED VISION. ALKALINE CORR: MAY CAUSE IMMED
PAIN, CIRCUMORAL BURNS & CORR OF MUC MEMBS WHICH AT FIRST TURN
WHITE & SOAPY & THEN BECOME BROWN, EDEMATOUS & ULCERATED. THERE
MAY BE PROFUSE SALIVATION & DFCLTY/INABILITY TO SWALLOW/SPEAK. CONT
NEHC FOR MORE COMPLETE INFO .
======================= First Aid Measures =======================
First Aid:INHAL: WHEN SAFE TO ENTER AREA, REMOVE FROM EXPOS. USE BAG
VALVE MASK/SIMILAR DEVICE TO PERFORM ARTF RESP (RESCUE BRTHG) IF
NEEDED. KEEP WARM & AT REST. GET MED ATTN IMMED. SKIN: REMOVE
CONTAM CLTHG, JEWELRY, & SHOES IMMED. WASH W/SOAP OR MILD
DETERGENT & LGE AMTS OF WATER UNTIL NO EVIDENCE OF CHEM REMAINS (AT
LEAST 15-20 MINS). FOR BURNS, COVER AFFECTED AREA SECURELY
W/STERILE, DRY, LOOSE-FITTING DRESSING. GET MED ATTN IMMED. EYES:
WASH IMMED W/LGE AMTS OF WATER, OCCAS LIFTING UPPER & LOWER LIDS,
UNTIL NO EVIDENCE OF CHEM REMAINS (AT LEAST 15 MINS). CONTINUE
IRRIGATING W/NORM SALINE UNTIL REA DY TO TRANSPORT TO HOSPITAL.
(SUP DAT)
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:=97.8C, 208.F
Extinguishing Media:LARGE FIRES: USE REGULAR FOAM OR FLOOD WITH FINE
WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
MOVE CONTR FROM FIRE AREA IF IT CAN BE DONE W/OUT RISK. COOL CONTRS
W/WATER SPRAY WELL AFTER FIRE IS OUT. STAY AWAY FROM ENDS OF TANKS.
USE EXTING AGEN TS APPROP FOR SURROUNDING FIRE. DO NOT GET WATER
DIRECTLY ON MATL. LGE FIRES: FLOOD W/FINE WATER SPRAY. (OTHER INFO)
Unusual Fire/Explosion Hazard:FLAMMABILITY CLASS (OSHA): IIIB. SLIGHT
FIRE HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT TOUCH SPILLED MATERIAL. STOP LEAK IF
POSSIBLE WITHOUT PERSONAL RISK. SMALL SPILLS: ABSORB WITH SAND OR
OTHER NON-COMBUSTIBLE MATERIAL. SMALL DRY SPILLS: COLLECT SPILLED
MATERIAL IN APPROPRIATE CONTAINER FOR DISPOSAL. KEEP UNNECESSARY
PEOPLE AWAY, ISOLATE HAZARD AREA AND DENY ENTRY.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AND HANDLE IN ACCORDANCE WITH
ALL CURRENT REGULATIONS AND STANDARDS. KEEP SEPARATE FROM
INCOMPATIBLE SUBSTANCES. SEE ORIGINAL CONTAINER FOR STORAGE
RECOMMENDATIONS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:UNDER CNDTNS OF FREQUENT USE/HEAVY EXPOS, NIOSH
APPRVD RESP PROT MAY BE NEEDED. RESP PROT IS RANKED IN ORDER FROM
MIN TO MAX. CONSIDER WARNING PROPERTIES BEFORE USE. ANY CHEM
CARTRIDGE RESP W/ORG VAP CARTRIDGE(S). ANY CHEM CARTRIDGE RESP
W/FULL FACEPIECE & ORG VAP CARTRIDGE(S). ANY AIR-PURIFYING RESP
W/FULL FACEPIECE & ORG VAP CANISTER. (OTHER INFO)
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION SYSTEM. ENSURE COMPLIANCE
WITH APPLICABLE EXPOSURE LIMITS.
Protective Gloves:WEAR APPROPRIATE CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR APPROPRIATE CHEMICAL-RESISTANT CLOTHING.
Supplemental Safety and Health
FIRST AID PROC: COVER W/STERILE BANDAGES. GET MED ATTN IMMED. INGEST:
CONT LOC POIS CTL CTR/MD IMMED. NEVER MAKE UNCON PERS VOMIT/DRINK
FLUIDS. WHEN VOMIT OCCURS KEEP HEAD LOWER THAN HIPS TO PVNT ASPI R.
IF UNCON TURN HEAD TO SIDE. GET MED ATTN IMMED. NOTE TO MD: INHAL:
CONSIDER OXYGEN. INGEST: CONSIDER GASTRIC LAVAGE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:SEE ECOLOGICAL INFO
Vapor Pres:SEE ECOLOGICAL INFO
Vapor Density:ECO INFO
Evaporation Rate & Reference:SEE ECOLOGICAL INFO
Solubility in Water:REACTS
Appearance and Odor:DARK GREEN-BLACK LIQUID WITH AN ODOR OF ETHER AND
NAPHTHALENE.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATLS, COMBUST MATLS. TETRAETHYLENE GLYCOL DIMETHYL ETHER:
STRONG OXIDIZERS: FIRE & EXPLO HAZ. SODIUM NAPHTHALENE COMPLEX:
ALCOHOLS: MAY REACT VIOLENTLY; STRONG OXIDIZERS: FIRE & EXPLO HAZ.
ETHERS: BORON TRIIODIDE
Stability Condition to Avoid:MAY REACT ON CONTACT WITH WATER. AVOID
HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION. MAY IGNITE OR
EXPLODE ON CONTACT WITH COMBUSTIBLE MATERIALS.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS:
MISCELLANEOUS DECOMPOSITION PRODUCTS.
=================== Toxicological Information ===================
Toxicological Information:ING 1: IRRIT DATA: 500 MG EYES-RABBIT MILD.
TOX DATA: 5140 MG/KG ORAL-RAT LD50. ACUTE TOX LEVEL: SLIGHTLY TOX:
INGEST. REPRO EFTS DATA: 1000 PPM INHAL-RAT TCLO/7 HRS 5 DAYS MALE;
1000 PPM INHAL-MOUSE TCLO/7 HRS 5 DAYS MALE. ING 2: LOC EFTS:
CORR: INHAL, SKIN, EYE, INGEST. ACUTE: INHAL: ING 2: MAY REACT
W/MOISTURE TO FORM SODIUM HYDROXIDE, AN ALKALINE CORR. SEE INFO ON
ALKALINE CORR. ING 1: GLYCOL ETHERS MAY IRRITATE NOSE & THROAT
W/BURNING & ITCH, & MAY CAUSE CNS DEPRESS. CNS SYMPS MAY INCL HDCH,
DROW, WEAK, SLURRED SPEECH, RECRUDESCENT STUTTERING, STAGG GAIT,
TREMORS, & BLURRED VISION. (ECOLO GICAL INFO)
===================== Ecological Information =====================
Ecological:NOT AVAIL. PHYSICAL/CHEM PROPERTIES: BP: 527F (275C)
(TETRAETHYLENE GLYCOL DIMETHYL ETHER); VP: <0.01 MMHG @ 20C
(TETRAETHYLENE GLYCOL DIMETHYL ETHER); VAP DENS (AIR=1): >1.0
(TETRAETHYLENE GLYCOL DIM ETHYL ETHER); EVAP RATE: <0.01 (BU AC=1,
TETRAETHYLENE GLYCOL DIMETHYL ETHER). TOX INFO: GLYCOL ETHERS MAY
ALSO CAUSE NAUS, VOMIT, DIARR, PULM EDEMA, & KIDNEY & LIVER DMG.
ALKALINE CORR: MAY CAUSE IRR IT OF RESP TRACT W/COUGH, CHOKING,
PAIN & POSS BURNS OF MUC MEMBS. IN SOME CASES, PULM EDEMA MAY
DEVELOP, EITHER IMMED IN SEV CASES/MORE OFTEN W/LATENT PERIOD OF
5-72 HRS. SYMPS MAY INCL TIGHTNESS IN CHEST, DYSPNEA, (SARA REGS)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
REGULATIONS. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS .
=================== MSDS Transport Information ===================
Transport Information:U.S. DOT 49 CFR 172.101 SHIPPING NAME-UN #: CORR
LIQS, N.O.S. (SODIUM)-UN1760. U.S. DOT 49 CFR 172.101: HAZ
CLASS/DIVISION: 8; PACKING GRP: III; SUBPART E LABELING REQS: CORR;
PACKAGING AUTHORIZATIONS : EXCEPTIONS: 49 CFR 173.154; NON-BULK
PACKAGING: 49 CFR 173.203; BULK PACKAGING: 49 CFR 173.241. U.S. DOT
49 CFR 172.101 QTY LIMITATIONS: PASSENGER AIRCRAFT/RAILCAR: 5 L;
CARGO AIRCRAFT ONLY: 60 L. L AND TRANSPORT ADR/RID: SUBSTANCE NAME:
CORR LIQ, N.O.S.; UN #: UN1760; ADR/RID CLASS: 8; ITEM #: 66 (C);
WARNING SIGN/LABEL: 8; HAZ IN #: 80. AIR TRANSPORT IATA/ICAO:
CORRECT TECHNICAL NAME: CORR LIQ, N.O.S.; UN/ID #: UN1760; (SARA
REGS)
===================== Regulatory Information =====================
SARA Title III Information:SARA SECTION 302: (40 CFR 355.30): N. SARA
SECTION 304 (40 CFR 355.40): N. SARA SECTION 313 (40 CFR 372.65):
N. SARA SECTIONS CATEGORIES, SARA SECTIONS 311/312 (40 CFR 370.21):
ACUTE: Y; CHRONIC: N; F IRE: N; REACTIVE: N; SUDDEN RELEASE: N.
TRANSPORT INFO: IATA/ICAO CLASS: 8; PACKAGING GROUP: III; LABEL:
CORR. MARITIME TRANSPORT IMDG: CORRECT TECHNICAL NAME: CORR LIQS,
N.O.S.; UN/ID #: UN1760; IMDG CLASS: 8; PACKAGING GROUP: III; EMS
#: 8-15; MFAG TABLE #: 760; MARINE POLLUTANT: Y. ECOLOGICAL INFO:
FROTHY SPUTUM, CYANOSIS, & DIZZ. PHYSICAL FINDINGS MAY INCL
HYPOTENSION, WEAK & RAPID PULSE & MOI ST RALES. (FED REGS)
Federal Regulatory Information:U.S. REGS: TSCA INVENTORY STATUS: N.
TSCA 12(B) EXPORT NOTIFICATION: NOT LISTED. CERCLA SECTION 103 (40
CFR 302.4): N. OSHA PROCESS SFTY (29 CFR 1910.119): N. EUROPEAN
REGS: EC #: NOT ASSIGNED. SARA R EGS: SEV CASES MAY BE FATAL. SKIN:
ING 2: MAY REACT W/MOISTURE TO FORM SODIUM HYDROXIDE, AN ALKALINE
CORR. SEE INFO ON ALKALINE CORR. POLY-ETCH: APPLICATION TO RABBIT
SKIN RSLTD IN NECROSIS W/SURROUND ING EDEMATOUS AREA. ING 1: MAY
CAUSE MILD IRRIT. ALKALINE CORR: DIRECT CONT MAY CAUSE SEV PAIN,
BURN S & POSS BROWNISH STAINS. CORRODED AREAS MAY BE SOFT,
GELATINOUS & NECROTIC & TISS DESCTRUCTION MAY BE DEEP. (STATE REGS)
State Regulatory Information:CALIFORNIA PROPOSITION 65: N. FED REGS:
EYES: ING 2: MAY REACT W/MOISTURE TO FORM SODIUM HYDROXIDE, AN
ALKALINE CORR. SEE INFO ON ALKALINE CORR. ING 1: GLYCOL ETHERS MAY
CAUSE CONJ W/TEMPORARY CORNEAL CLOUDING. ALKALINE CORR: DIRECT
CONT MAY CAUSE PAIN & BURNS. THERE MAY BE EDEMA, DESTRUCTION OF
EPITHELIUM, CORNEAL OPACIFICATION & IRITIS. WHEN DMG IS LESS THAN
EXCESS, THESE SYMPS TEND TO AMELIORAT E. IN SEV BURNS, FULL EXTENT
OF INJURY MAY NOT BE IMMED APPARENT. LATE COMPLICATIONS MAY INCL
PERSIS TENT EDEMA, VASCULARIZATION & SCARRING OF CORNEA, PERM
OPACITY, STAPHYLOMA, CATARACT, SYMBLEPHARON & BLINDNESS. (EFTS OF
OVEREXP)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|