===================== Product Identification =====================
MSDS NAME:KF POLYMER COATING POWDER, RED 347 (GRINNELL)
NIIN:00N093406
Status Code:A
MSDS Number: CJXYM
=== Responsible Party ===
Company:CONTINENTAL INDUSTRIES, INC
Address:20757 SW 105TH AVE
Box:927
City:TUALATIN
State:OR
ZIP:97062
Country:US
Info Phone Num:503-692-3400
Emergency Phone Num:503-692-3400
Preparer's Name:J.F. BEHRENS
CAGE:TO414
=== Contractor Identification ===
Company:CONTINENTAL INDUSTRIES, INC
Address:20757 SW 105TH AVE
Box:927
City:TUALATIN
State:OR
ZIP:97062
Country:US
Phone:503-692-3400
CAGE:TO414
============= Composition/Information on Ingredients =============
Name:POLY(VINYLIDENE FLUORIDE); (POLYVINYIDENE FLUORIDE)
CAS:24937-79-9
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:10 MG/M3
ACGIH STEL:N/K
Name:IRON OXIDE; (RED IRON OXIDE)
CAS:1332-37-2
RTECS #:NO7380000
< Wt:5.
Other REC Limits:N/K
OSHA PEL:15 MG/M3 (AS CR)
OSHA STEL:N/K
ACGIH TLV:10 MG/M3 (AS CR)
ACGIH STEL:N/K
Name:QUARTZ; (SILICA (QUARTZ))
CAS:14808-60-7
RTECS #:VV7330000
< Wt:25.
Other REC Limits:N/K
OSHA PEL:see Table Z-3
OSHA STEL:N/K
ACGIH TLV:0.1 MG/M3
ACGIH STEL:N/K
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXCESSIVE INHALATION OF
DUST MAY CAUSE ACUTE PHYSICAL IRRITATION OF RESPIRATORY TRACT.
EXPOSURE TO DUST MAY AGGRAVATE PRE-EXISTING RESPIRATORY CONDITIONS.
DO NOT SMOKE IN AREAS WHERE DUST IS PRESENT IN THE AIR. EYES: MAY
CAUSE EYE IRRITATION. SKIN: MAY CAUSE SKIN IRRITATION. INGESTION:
NO HAZARD DURING NORMAL INDUSTRIAL USE. MAY CAUSE IRRITATION TO THE
GASTROINTESTINAL TRACT.
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC
MONOGRAPHS, SUPPLEMENT, VOLUME 68, 1997: GROUP 1. NTP 8TH ANNUAL
REPORT ON CARCINOGENS, 1998: REASONABLY ANTICIPATED TO BE HUMAN
CARCINOGEN. HUMAN: LUNG.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:EXPOSURE TO DUST MAY AGGRAVATE
PRE-EXISTING RESPIRATORY CONDITIONS.
======================= First Aid Measures =======================
First Aid:INHALATION: IF INHALED, REMOVE TO FRESH AIR. NO ADVERSE
EFFECTS ANTICIPATED BY THIS ROUTE OF EXPOSURE INCIDENTAL TO PROPER
INDUSTRIAL HANDLING. EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST
15 MINUTES . CALL A PHYSICIAN IF IRRITATION DEVELOPS, OR PERSISTS.
SKIN: WASH WITH MILD SOAP AND WATER. IF IRRITATION DEVELOPS, CALL A
PHYSICIAN. INGESTION: NO ADVERSE EFFECTS ANTICIPATED BY THIS ROUTE
OF EXPOSU RE INCIDENTAL TO PROPER INDUSTRIAL HANDLING. IF
SWALLOWED, INDUCE VOMITING IMMEDIATELY BY GIVING TWO GLASSES OF
WATER AND STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PE RSON. CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CO*2. REMOVE FROM FLAME.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . KEEP PERSONNEL REMOVED
AND UPWIND OF FIRE. UNDER FIRE CONDITIONS HAZARDOUS GASES AND/OR
TOXIC FUMES AND GAS ES MAY BE PRESENT.
Unusual Fire/Explosion Hazard:THE SOLID POLYMER CAN BE COMBUSTED ONLY
WITH DIFFICULTY. HAZARDOUS HYDROGEN FLUORIDE AND HYDROGEN CHLORIDE
FUMES ARE PRODUCED.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP, OR USE DRY VACUUM OR WET PROCEDURES.
AVOID GENERATING DUST DURING CLEANUP. RECOVER UNDAMAGED AND
MINIMALLY CONTAMINATED MATERIAL FOR REUSE AND RECLAMATION. AVOID
RUN-OFF INTO STORM SEWERS AND D ITCHES WHICH LEAD TO NATURAL
WATERWAYS.
====================== Handling and Storage ======================
Handling and Storage Precautions:SEE FIRST AID AND PERSONEL PROTECTIVE
PROTECTION SECTIONS. MINIMIZE DUST GENERATION AND ACCUMULATION.
AVOID BREATHING DUST. WASH HANDS BEFORE EATING AND SMOKING. KEEP
AWAY FROM FOOD OR DRINKING WATER. KEEP CONTAINER CLOSED TO PREVENT
CONTAMINATION. STORE IN A COOL, DRY PLACE.
Other Precautions:KEEP AWAY FROM COMBUSTIBLE MATERIALS. KEEP AWAY FROM
HEAT, FLAME AND SOURCES OF IGNITION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATORS WITH HEPA FILTER.
Ventilation:USE PROCESS ENCLOSURES AND LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE DUST LEVELS BELOW THE RECOMMENDED EXPOSURE LIMITS.
Protective Gloves:GLOVES MAY BE USED TO PROT SKIN FROM DRYING EFT. WEAR
IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER .
Work Hygienic Practices:GOOD HOUSEKEEPING PROCEDURES SHOULD BE FOLLOWED
TO PREVENT DUST DURING PROCESSING. NEVER EAT, DRINK OR SMOKE IN
WORK AREAS. PRACTICE GOOD PERSONAL HYGIENE AFTER USING THIS
MATERIAL, (SUP DAT)
Supplemental Safety and Health
GENERAL USE OF THE PRODUCT: THERMOPLASTIC COATING POWDER. -- HMIS
RATINGS: HEALTH = 1; FLAMMABILITY = 0; REACTIVITY = 0; PERSONAL
PROTECTIVE EQUIPMENT = E. -- HYGIENE PRACTICES: ESPECIALLY BEFORE
EATI NG, DRINKING, SMOKING, USING THE TOILET OR APPLYING COSMETICS.
================== Physical/Chemical Properties ==================
Solubility in Water:NEGLIGIBLE
Appearance and Odor:FINE RED POWDER; ODORLESS.
Percent Volatiles by Volume:NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES AND ALKALI METALS. PIGMENT MAY REACT WITH HYDRAZINE,
CALCIUM HYPOCHLORITE, PERFORMIC ACID, AND BROMINE PENTAFLUORIDE.
Stability Condition to Avoid:TEMPERATURES ABOVE 600F. THERMAL
DECOMPOSITION. FLAMES.
Hazardous Decomposition Products:IN FIRE: HYDROGEN FLUORIDE & HYDROGEN
CHLORIDE ARE RELEASED DURING THERMAL DECOMPOSITION WHICH IS
CORROSIVE, & WILL BURN ON CONTACT WITH THE SKIN & OTHER TISSUE, &
HAS A TLV OF 3 PPM CEILING LIMIT.
=================== Toxicological Information ===================
Toxicological Information:UNDER NORM CNDTNS OF USE & EXPOS, AVAIL
EVIDENCE INDICATES THAT THERE ARE NO ADVERSE HLTH EFTS FROM
POLYVINYIDENE FLUORIDE. PIGMENT MAY CAUSE MECH SKIN & EYE IRRIT. NO
TOXICITY DATA IS AVAIL FOR SILIC A. CHRONIC: PRLNG INHAL OF IRON
OXIDE DUST IS KNOWN TO PRDCE A CNDTN KNOWN AS SIDEROSIS. ON X-RAYS
IT APPEARS TO BE A BENIGN PNEUMOCONIOSIS & IS NOT ASSOC W/PULM
FIBROSIS/DISABILITY UNLESS THERE IS CO NCURRENT EXPOS TO OTHER
FIBROSIS-PRODUCING MATLS, SUCH AS SILICA. TLV IS SET TO PROTECT
AGAINST SIDEROSIS. SILICOSIS: EXCESS INHAL OF RESP CRYSTALLINE
SILICA DUST MAY CAUSE PROGRESSIVE, DISABLING & SO METIMES FATAL
LUNG (ECOLOGICAL INFO)
===================== Ecological Information =====================
Ecological:NO DATA AVAIL ON ADVERSE EFTS OF POLYVINYIDENE FLUORIDE ON
ENVIRON. BASED ON CHEM COMPOSITION & WATER INSOL OF KF POLYMER, IT
IS ASSUMED THAT MATL WILL NOT CAUSE ANY SIGNIFICANT ADVERSE ENVIRON
EFTS. TOX INFO: DISEASE CALLED SILICOSIS. SYMPS INCL COUGH,
SHORTNESS OF BREATH, WHEEZING, NON-SPECIFIC CHEST ILLNESS & REDUCED
PULM FUNC. THIS DISEASE IS EXACERBATED BY SMKNG. INDIVIDUALS
W/SILICOSIS ARE P REDISPOSED TO DEVELOP TUBERCULOSIS. CANCER
STATUS: IARC HAS DETERMINED THAT CRYSTALLINE SILICA INHALED IN THE
FORM OF QUARTZ/CRISTOBALITE FROM OCCUP SOURCES IS CARCIN TO HUMANS
(GROUP 1 - CARCIN TO HU MANS). (TRANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:POLYVINYIDENE FLUORIDE IS NOT CONSIDERED A
HAZARDOUS WASTE UNDER FEDERAL HAZARDOUS WASTE REGULATIONS 40 CFR
261. DISPOSAL MUST BE MADE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS. PURSUANT TO 40 CFR PART 261 OF THE RCRA
REGULATIONS CURRENTLY IN EFFECT, DISCARDED IRON OXIDE WOULD NOT BE
C LASSIFIED AS A HAZARDOUS WASTE.
=================== MSDS Transport Information ===================
Transport Information:D.O.T. SHIPPING NAME: NOT REGULATED. D.O.T.HAZ
CLASS, D.O.T. LABEL, UN/NA #: NONE. ECOLOGICAL INFO: REFER TO IARC
MONO 66, SILICA, SOME SILICATES & ORG FIBRES (PUBLISHED IN JUNE
1997) IN CONJUNCTION W /USE OF THESE MATLS. NTP CLASSIFIES RESP
CRYSTALLINE SILICA AS "REASONABLY ANTIC TO BE CARCIN". OTHER DATA
W/POSS RELEVANCE TO HUMAN HLTH: THERE IS SOME EVIDENCE THAT BRTHG
RESP CRYSTALLINE SILICA/DIS EASE SILICOSIS IS ASSOC W/INCREASED
INCIDENCE OF SIGNIFICANT DISEASE ENDPOINTS, SUCH AS SCLERODERMA
(IMMUNE SYS DISORDER, MANIFESTED BY FIBROSIS OF LUNGS, SKIN & OTHER
INTERNAL ORGANS) & KIDNEY DISEAS E. (STATE REGS)
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302/304 - NO EXTREMELY HAZARDOUS
SUBSTANCES. SECTION 313 - THIS PRODUCT DOES NOT CONTAIN TOXIC
CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF
THE EMERGENCY PLANNING AND COMM UNITY RIGHT-TO-KNOW ACT OF 1986 AND
OF 40 CFR 372.
Federal Regulatory Information:TSCA INVENTORY STATUS: ALL INGREDIENTS
ARE LISTED. CERCLA REPORTABLE QUANTITY: NONE. NOTE: CONSULT STATE
AND LOCAL REGULATIONS WHICH MAY APPLY.
State Regulatory Information:N/P -- TRANSPORTATION INFORMATION: FOR
OTHER INFORMATION, CONSULT "ADVERSE EFFECTS OF CRYSTALLINE SILICA
EXPOSURE" PUBLISHED BY THE AMERICAN THORACIC SOCIETY MEDICAL
SECTION OF THE AMERICAN LUNG ASSOC IATION, AMERICAN JOURNAL OF
RESPIRATORY AND CRITICAL CARE MEDICINE, VOLUME 155, PAGE 762-765,
1997.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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