===================== Product Identification =====================
MSDS NAME:A/W HYDRAULIC OIL 46, 33420
NIIN:00N093378
Status Code:A
MSDS Number: CJXZB
=== Responsible Party ===
Company:CITGO PETROLEUM CORP
Box:3758
City:TULSA
State:OK
ZIP:74102-3758
Country:US
Info Phone Num:918-495-5933
Emergency Phone Num:918-495-5933;800-424-9300
Resp. Party Other MSDS Num.:33420
Chemtrec Ind/Phone:(800)424-9300
CAGE:7X110
=== Contractor Identification ===
Company:CITGO PETROLEUM CORP
Address:6100 S YALE AVE
Box:3758
City:TULSA
State:OK
ZIP:74102
Country:US
Phone:918-495-5933
CAGE:7X110
============= Composition/Information on Ingredients =============
Name:DISTILLATES (PETROLEUM), SOLVENT-REFINED HEAVY PARAFFINIC
AND ING 2. LD50: (ORAL,RAT) >5000 MG/KG
CAS:64741-88-4
RTECS #:PY8040500
Minumum % Wt:98.
Maxumum % Wt:100.
Name:DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT PARAFFINIC
CAS:64741-89-5
RTECS #:PY8041500
Name:PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYL ESTERS, ZINC
SALTS; (ZINC C1-C14 ALKYLDITHIOPHOSPHATE)
CAS:68649-42-3
Minumum % Wt:0.
Maxumum % Wt:1.
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE ING 1
Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: AT ELEVATED TEMPS,
MIST/VAPS MAY IRRITATE MUC MEMB OF NOSE, THROAT, BRONCHI, & LUNGS.
EYE CONT: PROD CAN CAUSE MILD, TRANSIENT, EYE IRRIT W/SHORT-TERM
CONT W/LIQ OR SPRAYS. SKIN CONT: MA TL CAN CAUSE MILD SKIN IRRIT
FROM PRLNGD/RPTD SKIN CONT. INJECTION UNDER SKIN, IN MUSCLE/INTO
BLOOD STREAM CAN CAUSE IRRIT, INFLAMM, SWELL, FEVER, & SYSTEMIC
EFTS & MILD CNS DEPRESS. INJECTION OF PRES SURIZED HYDROCARBONS CAN
CAUSE SEV, PERM TISS DMG. INITIAL SYMPS MAY BE MINOR. INJECTION OF
PETROLEUM HYDROCARBONS REQS IMMED MED ATTN. INGEST: IF SWALLOWED,
NO SIGNIFICANT ADVERSE HLTH EFTS ARE ANTIC . INGEST CAN CAUSE (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:THIS PRODUCT DOES NOT CONTAIN ANY
COMPONENTS AT CONCENTRATIONS ABOVE 0.1% WHICH ARE CONSIDERED
CARCINOGENIC BY OSHA, IARC, OR NTP.
Effects of Overexposure:HLTH HAZS: MILD IRRIT TO DIGESTIVE TRACT/CAUSE
LAXATIVE EFT. BECAUSE OF LOW VISCOSITY OF MATL, MATL CAN ENTER
LUNGS DIRECTLY BY ASPIR (E.G., DURING SWALLOWING/VOMIT). IF
ASPIRATED INTO LUNGS, MATL CAN CAUSE SEV LUNG DMG/DEATH. CHRONIC:
CNTNS PETROLEUM-BASED OIL. PRLNGD/RPTD SKIN CONT CAN CAUSE MILD
IRRIT & INFLAMM CHARACT BY DRYING, CRACKING, (DERM) OR OIL ACNE.
INHAL OF PETROLEUM-BASED MINERAL OI LS CAN CAUSE RESP IRRIT/OTHER
PULM EFTS AFTER RPTD/PRLNGD INHAL OF OIL MISTS AT CONCENTRATIONS
ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS. TARGET ORGANS: SKIN.
Medical Cond Aggravated by Exposure:PERSONNEL WITH PRE-EXISTING SKIN
DISORDERS SHOULD AVOID REPEATED OR PROLONGED CONTACT WITH THIS
PRODUCT.
======================= First Aid Measures =======================
First Aid:TAKE PROPER PRECS TO ENSURE YOUR OWN HLTH & SFTY BEFORE
ATTEMPTING RESCUE/PROVIDING FIRST AID. FOR MORE SPECIFIC INFO,
REFER TO EXPOS CTLS & PERSONAL PROT IN SECTION 8 OF MSDS. INHAL:
MOVE TO FRESH AI R. IF VICTIM IS NOT BRTHG, IMMED BEGIN RESCUE
BRTHG. IF BRTHG IS DFCLT, 100% HUMIDIFIED OXYG SHOULD BE ADMIN BY
QUALIFIED INDIVIDUAL. SEEK MED ATTN IMMED. KEEP AFFECTED INDIVIDUAL
WARM & AT REST. EYE CONT: CHECK FOR & REMOVE CONT LENSES. FLUSH
W/COOL, CLEAN, LOW-PRESS WATER WHILE OCCASNLY LIFTING & LOWERING
EYELIDS FOR AT LST 15 MINS. SEEK MED ATTN IF EXCESS TEARING,
REDNESS/PAIN PERSISTS. (SUPDAT )
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=212.C, 413.6F
SUPDAT
Lower Limits:AP 1%
Upper Limits:AP 7%
Extinguishing Media:USE DRY CHEMICAL, FOAM, CARBON DIOXIDE OR WATER
FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . WITHDRAW IMMED FROM AREA IF THERE IS A RISING SOUND
FROM A VENTING SAFETY DEVICE/DISCOLORATION OF VESSELS, TANKS, OR
PIPELINES.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE ITS FLASH POINT TEMP,
MATL WILL RELEASE VAPS WHICH, IF EXPOS TO IGNIT SOURCE, CAN IGNITE.
IN ENCLOSED SPACES VAPS CAN IGNITE W/EXPLO FORCE. MISTS/SPRAYS MAY
BURN @ TEMPS BELOW FLASH POINT. HAZ COMBUST PRODS: CO*2, SMOKE,
FUMES, UNBURNED HYDROCARBS & TRACE OXIDES OF SULFUR, NITROGEN,
PHOSPHORUS & ZINC.
================== Accidental Release Measures ==================
Spill Release Procedures:TAKE PROPER PRECS TO ENSURE YOUR OWN HLTH &
SFTY BEFORE ATTEMPTING SPILL CTL/CLEAN-UP. FOR MORE SPECIFIC INFO,
REFER TO EMER OVERVIEW ON PG 1, EXPOS CTLS & PERSONAL PROT IN
SECTION 8 & DISP CONSIDERAT IONS IN SECTION 13 OF MSDS. DO NOT
TOUCH DMGD CNTNRS/SPILLED MATL UNLESS WEARING APPROP PROT EQUIP.
SLIPPING HAZARD; DO NOT WALK THROUGH SPILLED MATL. STOP LEAK IF YOU
(STATE REGULATORY INFO)
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID WATER CONTAM & EXTREME TEMPS TO
MINIMIZE PROD DEGRADATION. EMPTY CNTNRS MAY CNTN PROD RESIDUES THAT
CAN IGNITE W/EXPLO FORCE. DO NOT PRESSURIZE, CUT, WELD, BRAZE
SOLDER, DRILL, GRIND/EXPOSE CNTN RS TO FLAMES, SPKS, HEAT/OTHER
POTNTL IGNIT SOURCES. KEEP CNTNR CLSD.
Other Precautions:CONSULT APPROP FED, STATE & LOC AUTH BEFORE REUSING,
RECONDITIONING, RECLAIMING, RECYCLING/DISPOSING OF EMPTY CNTNRS
&/OR WASTE RESIDUES OF PROD. DO NOT STORE W/STRONG OXIDIZING
AGENTS. DO NOT STORE @ TEMPS >120F/IN DIRECT SUNLIGHT FOR EXTENDED
PERIODS OF TIME. FOR MORE SPECIFIC INFO CONT NEHC (FP N ).
============= Exposure Controls/Personal Protection =============
Respiratory Protection:VAPORIZATION/MISTING IS NOT EXPECTED @ AMBIENT
TEMPS. THEREFORE, NEED FOR RESP PROT IS NOT ANTIC UNDER NORM USE
CNDTNS & W/ADEQ VENT. IF ELEVATED AIRBORNE CONCS > APPLIC WORKPLACE
EXPOS LEVELS ARE ANT IC, NIOSH APPRVD ORG VAP RESP EQUIPPED
W/DUST/MIST PREFILTER SHOULD BE USED. PROT FACTORS VARY DEPENDING
UPON TYPE OF RESP USED. FOR MORE INFO CONT NEHC .
Ventilation:PROVIDE EXHST VENT/OTHER ENGINEERING CTLS TO KEEP AIRBORNE
CONCS OF MISTS &/OR VAPS BELOW REC EXPOS LIMITS. FOR MORE INFO CONT
NEHC .
Protective Gloves:CHEM RESIST MATLS SUCH AS NEOPRENE/HEAVY NITRILE RUBB
GLOVES. CONT NEHC .
Eye Protection:ANSI APPROVD CHEM WORKERS GOGGS . FOR MORE INFO CONT
NEHC .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . USE
CLEAN & IMPERVIOUS CLTHG (E.G., NEOPRENE/TYVEK) IF
SPLASHING/SPRAYING CNDTNS ARE PRESENT. FOR MORE SPECIFIC INFO
CONTACT NEHC .
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE PRACT. WASH HANDS &
OTHER EXPOS SKIN AREAS W/PLENTY OF MILD SOAP & WATER BEFORE EATING,
DRINKING, SMKNG, USE OF TOILET FACILITIES/ LEAVING WORK. FOR MORE
INFO CONT NEHC .
Supplemental Safety and Health
FL PT METH: OC: FL PT: 242C,467.6F. FIRST AID PROC: SKIN CONT: REMOVE
CONTAMD SHOES & CLTHG. WIPE OFF EXCESS MATL. WASH EXPOS SKIN W/SOAP
& WATER. SEEK MED ATTN IF TISS APPEARS DMGD/IF IRRIT PERSISTS.
THORO CLEAN CONTAMD CLTHG BEFORE REUSE. DISCARD CONTAMD LEATHER
GOODS. IF MATL IS INJECTED UNDER SKIN, (TRANSPORT INFO)
================== Physical/Chemical Properties ==================
Vapor Pres:<1 @ 20C
Vapor Density:>1(AIR=1)
Spec Gravity:0.87 (WATER =1)
Viscosity:44 (CST@40C)
Solubility in Water:INSOL IN COLD WATER
Appearance and Odor:LIGHT AMBER LIQUID. MILD PETROLEUM ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:KEEP AWAY FROM EXTREME HEAT AND OPEN
FLAME.
Hazardous Decomposition Products:CO*2, CO, SMOKE, FUMES, UNBURNED
HYDROCARBONS & TRACE OXIDES OF SULFUR, NITROGEN, PHOSPHOROUS &
ZINC.
=================== Toxicological Information ===================
Toxicological Information:FOR OTHER HLTH-RELATED INFO, REFER TO EMER
OVERVIEW ON PG 1 & HAZS IDENTIFICATION IN SECTION 3 OF MSDS. TOX
DATA: HIGHLY-REFINED PETROLEUM LUBRICANT OILS: ORAL (LD50): ACUTE:
>5000 MG/KG(RAT). DERMAL (LD50): ACUTE: >2000 MG/KG(RABBIT).
HIGHLY-REFINED PETROLEUM LUBRICANT OILS: MINERAL OILS MISTS DERIVED
FROM HIGHLY REFINED OILS ARE RPTD TO HAVE LOW ACUTE & SUB-ACUTE TOX
IN ANIMALS. EFTS FROM SINGLE & SHORT-TERM RPTD EXPOS TO HIGH CONCS
OF MINERAL OIL MISTS WELL ABOVE APPLIC WORKPLACE EXPOS LEVELS INCL
LUNG INFLAMMATORY RXN. LIPOID GRANULOMA FORMATION & LIPOID PNEUM.
FOR MORE SPECIFIC INFO CONT NEHC .
===================== Ecological Information =====================
Ecological:ECOTOXICITY: ANALYSIS FOR ECOLOGICAL EFTS HAS NOT BEEN
CONDUCTED ON PROD. HOWEVER, IF SPILLED, PROD & ANY CONTAMD
SOIL/WATER MAY BE HARMFUL TO HUMAN, ANIMAL, & AQUATIC LIFE. ALSO,
COATING ACTION ASSOC W/PETROLEUM & PETROLEUM PRODS CAN BE
HARMFUL/FATAL TO AQUATIC LIFE & WATERFOWL. ENVIRON FATE: ECOLOGICAL
EFTS TESTING HAS NOT BEEN CONDUCTED ON PROD. HOWEVER, PLANTS &
ANIMALS MAY EXPERIENCE HARMFUL/ FATAL EFTS WHEN COATED W/PETROLEUM
BASED PRODS. PETROLEUM-BASED(MINERAL)LUBE OILS WILL NORMALLY FLOAT
ON WATER. FOR MORE SPECIFIC INFO CONT NEHC .
==================== Disposal Considerations ====================
Waste Disposal Methods:HAZ CHARACT & REGULATORY WASTE STREAM
CLASSIFICATION CAN CHANGE W/PROD USE. ACCORD, IT IS RESPONSIBILITY
OF USER TO DETERM PROPER STOR, TRANSPORTATION, TREATMENT AND/OR
DISP METHODOLOGIES FOR SPENT MA TLS & RESIDUES @ TIME OF
DISPOSITION. CNDTNS OF USE MAY CAUSE MATL TO BECOME "HAZ WASTE", AS
DEFINED (OTHER INFO)
=================== MSDS Transport Information ===================
Transport Information:DOT STATUS: NOT U.S. DEPARTMENT OF TRANSPORTATION
REGULATED MATL. PROPER SHIPPING NAME: PETROLEUM OIL, N.O.I.B.N. HAZ
CLASS: NOT A DOT CONTROLLED MATL(U.S.). PACKING GROUP(S): N/A.
UN/NA ID: N/A. REPO RTABLE QTY: A REPORTABLE QUANTITY (RQ)HAS NOT
BEEN ESTABLISHED FOR ANY COMPONENTS OF MATL. SUPDAT: INTO
MUSCLE/INTO BLOODSTREAM. SEEK MED ATTN IMMED. INGEST: DO NOT INDUCE
VOMIT UNLESS DIRECTED TO BY PHYS. DO NOT GIVE ANYTHING TO DRINK
UNLESS DIRECTED TO BY PHYS. NEVER GIVE ANYTHING BY MOUTH TO PERSON
WHO IS NOT FULLY CONSCIOUS. SEEK MED ATTN IMMED. NOTES TO PHYS: IN
EVENT OF INJECTION (STATE REG ULATORY INFO)
===================== Regulatory Information =====================
SARA Title III Information:SARA 302/304 - THE SARA TITLE III REQS
FACILITIES SUBJECT TO SUBPARTS 302 & 304 TO SUBMIT EMER PLANNING &
NOTIFICATION INFO BASED ON THRESHOLD PLANNING QTYS(TPQS) &
REPORTABLE QUANTITIES(RQS) FOR "EXT REMELY HAZ SUBSTANCES) LISTED
IN 40 CFR302.4 & 40 CFR 355. NO COMPONENTS WERE IDENTIFIED. SARA
311/312: SARA TITLE III REQS FACILITIES SUBJECT TO THIS SUBPART TO
SUBMIT AGGREGATE INFO ON CHEMS BY "HAZ CATEGORY" AS DEFINED IN 40
CFR 370.2. THIS MATL WOULD BE CLASSIFIED UNDER FOLLOWING HAZ
CATEGORIES: NO SARA 311/312 HAZ CATEGORIES IDENTIFIED. SARA 313:
NONE IDENTIFIED.
Federal Regulatory Information:TSCA INVENTORY - THIS PROD AND/OR ITS
COMPONENTS ARE LISTED ON TSCA INVENTORY. THE CERCLA REQS
NOTIFICATION OF NATL RESPONSE CTR CONCERNING RELEASE OF "HAZ
SUBSTANCES" EQUAL TO/GTR THAN (RQ'S) LISTED IN 40 CFR 302.4. AS
DEFINED BY CERCLA, TERM "HAZ SUBSTANCE" DOES NOT INCL PETROLEUM,
INCL CRUDE OIL/ANY FRACTION THEREOF WHICH IS NOT OTHERWISE
SPECIFICALLY DESIGNATED IN 40 CFR 302.4. PROD/REFINERY S TREAM IS
NOT KNOWN TO CNTN CHEM SUBSTANCES SUBJECT TO THIS STATUTE. HOWEVER,
IT IS REC THAT YOU CONT STATE & LOC AUTH TO DETERM IF THERE ARE
ANY OTHER RPTG REQUIREMENTS IN EVENT OF SPILL. FOR MORE INFO CONT
NEHC .
State Regulatory Information:CALIFORNIA PROP 65: PROD IS NOT KNOWN TO
CNTN ANY COMPONENTS FOR WHICH STATE OF CALIFORNIA HAS FOUND TO
CAUSE CANCER, BIRTH DEFECTS/OTHER REPRO HARM. NEW JERSEY
RIGHT-TO-KNOW LABEL: PETROLEUM OIL(HYDR AULIC FLUID). TRANSPORT
INFO: IN UNDERLYING TISS, IMMED TREATMENT SHOULD INCL EXTENSIVE
INCISION, DEBRIDEMENT & SALINE IRRIGATION. INADEQ TREATMENT CAN
RSLT IN ISCHEMIA & GANGRENE. EARLY SYMPS MAY BE MINIMAL. SPILL
PROC: CAN DO SO W/OUT RISK. FOR SM SPILLS, ABSORB/COVER W/DRY
EARTH, SAND/OTHER INE RT NON-COMBUST ABSORB MATL & PLACE INTO WASTE
CNTNRS FOR LATER DISP. FOR MORE INFO CONT NEHC .
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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