===================== Product Identification =====================
MSDS NAME:KF POLYMER COATING POWDER, GREEN 6010
NIIN:00N093409
Status Code:A
MSDS Number: CJXWW
=== Responsible Party ===
Company:CONTINENTAL INDUSTRIES INC
Address:20757 SW 105TH AVE
Box:927
City:TUALATIN
State:OR
ZIP:97062
Country:US
Info Phone Num:503-692-3400
Emergency Phone Num:503-692-3400
Preparer's Name:J F BEHRENS
CAGE:TO416
=== Contractor Identification ===
Company:CONTINENTAL INDUSTRIES INC
Address:20757 SW 105TH AVE
Box:927
City:TUALATIN
State:OR
ZIP:97062
Country:US
Phone:503-692-3400
CAGE:TO416
============= Composition/Information on Ingredients =============
Name:POLY(VINYLIDENE FLUORIDE); (POLYVINYIDENE FLUORIDE)
CAS:24937-79-9
Name:CHROMIUM(3+) OXIDE; (CHROMIUM (CR3+)
CAS:1308-38-9
RTECS #:GB6475000
< Wt:3.
Name:SILICA, CRYSTALLINE QUARTZ; (SILICA (QUARTZ))
CAS:14808-60-7
RTECS #:VV7330000
< Wt:25.
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:0.1 MG/M3
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXCESSIVE INHALATION OF
DUST MAY CAUSE ACUTE PHYSICAL IRRITATION OF RESPIRATORY TRACT.
EXPOSURE TO DUST MAY AGGRAVATE PRE-EXISTING RESPIRATORY CONDITIONS.
DO NOT SMOKE IN AREAS WHERE DUST IS PRESENT IN THE AIR. EYES: MAY
CAUSE EYE IRRITATION. SKIN: MAY CAUSE SKIN IRRITATION. INGESTION:
NO HAZARD DURING NORMAL INDUSTRIAL USE. MAY CAUSE IRRITATION TO THE
GASTROINTESTINAL TRACT.
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC
MONOGRAPHS ON EVALUATION OF CARCIN RISK OF CHEM TO MAN: VOL 68,
PAGE 41, 1997: GROUP 1. NTP 8TH ANNUAL RPT ON CARCIN 1998:
REASONABLY ANTICIPATED TO BE HUMAN CARCIN.
Effects of Overexposure:TOX INFO: UNDER NORM CNDTNS OF USE & EXPOS,
AVAIL EVID INDICATES THAT THERE ARE NO ADVERSE HLTH EFTS FROM
POLYVINYIDENE FLUORIDE. CHROMIUM & CERTAIN CMPDS HAVE BEEN LISTED
AS CARCIN, BOTH IN ANIMALS & BY HUMANS, BY NATIONAL TOXICOLOGY
PROGRAM & INTERNATIONAL AGENCY FOR RESEARCH ON CANCER. SOME
CHROMIUM VI CMPDS ARE IDENTIFIED AS LUNG CARCIN BY TOX STUDIES.
EVID OF CHROMIUM III CMPD CARCIN IN ANIMA LS IS INCONCLUSIVE. THIS
PROD CNTNS CHROMIUM III. CHRONIC: PIGMENT CNTNS TRIVALENT CHROMIUM
CMPD. AS NOTED BY AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS IN THERE PUBLICATION (TOX INFO)
======================= First Aid Measures =======================
First Aid:INHALATION: IF INHALED, REMOVE TO FRESH AIR. NO ADVERSE
EFFECTS ANTICIPATED BY THIS ROUTE OF EXPOSURE INCIDENTAL TO PROPER
INDUSTRIAL HANDLING. EYE CONTACT: FLUSH WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES. CALL A PHYSICIAN IF IRRITATION DEVELOPS, OR
PERSISTS. SKIN: WASH WITH MILD SOAP AND WATER. IF IRRITATION
DEVELOPS, CALL A PHYSICIAN. INGESTION: NO ADVERSE EFFECTS
ANTICIPATED BY THIS ROUTE OF EXPOSURE INCIDENTAL TO PROPER
INDUSTRIAL HANDLING. IF SWALLOWED, INDUCE VOMITING IMMEDIATELY BY
GIVING TWO GLASSES OF WATER AND STICKING FINGER DOWN THROAT. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSC IOUS PERSON. CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CO2. REMOVE FROM FLAME.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . KEEP PERSONNEL REMOVED AND UPWIND OF FIRE. UNDER FIRE
CONDITIONS HAZARDOUS GASES AND/OR TOXIC FUMES AND GASES MAY BE
PRESENT.
Unusual Fire/Explosion Hazard:FLASH POINT: THE SOLID POLYMER CAN BE
COMBUSTED ONLY WITH DIFFICULTY. HAZARDOUS COMBUSTION PRODUCTS:
HAZARDOUS HYDROGEN FLUORIDE AND HYDROGEN CHLORIDE FUMES ARE
PRODUCED.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP, OR USE DRY VACUUM OR WET PROCEDURES.
AVOID GENERATING DUST DURING CLEANUP. RECOVER UNDAMAGED AND
MINIMALLY CONTAMINATED MATERIAL FOR REUSE AND RECLAMATION. AVOID
RUN-OFF INTO STORM SEWERS AND D ITCHES WHICH LEAD TO NATURAL
WATERWAYS.
====================== Handling and Storage ======================
Handling and Storage Precautions:HANDLING: SEE FIRST AID & PERS PROT
PROTECTION SECTIONS. MIN DUST GENERATION & ACCUMULATION. AVOID
BRTHG DUST. STORAGE: KEEP AWAY FROM FOOD/DRINKING WATER. KEEP CNTNR
CLOSED TO PREVENT CONTAM. STORE I N COOL, DRY PLACE. KEEP AWAY FROM
COMBUST MATLS. KEEP AWAY FROM HEAT, FLAME & SOURCES OF IGNITION.
Other Precautions:TOX INFO: INHALED IN FORM OF QUARTZ/CRISTOBALITE FROM
OCCUP SOURCES IS CARCIN TO HUMANS. (GROUP 1-CARCIN TO HUMANS).
REFER TO IARC MONO 66, SILICA, SOME SILICATES & ORG FIBRES
(PUBLISHED IN JUNE 1997) IN CONJUNCTION W/USE OF THESE MATLS.
NATIONAL TOX PROGRAM CLASSIFIES RESPIRABLE CRYSTALLINE SILICA AS
(TRANSPORT INFO)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATORS WITH HEPA FILETER.
Ventilation:USE PROCESS ENCLOSURES AND LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE DUST LEVELS BELOW THE RECOMMENDED EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
Work Hygienic Practices:WASH HANDS BEFORE EATING & SMOKING. GOOD
HOUSEKEEPING PROC SHOULD BE FOLLOWED TO PVNT DUST DURING
PROCESSING. NEVER EAT, DRINK/SMOKE IN WORK AREAS. PRACTICE GOOD
PERSONAL HYGIENE AFTER USING (SUPDAT)
Supplemental Safety and Health
HYGIENE PRACT: THIS MATERIAL, ESPECIALLY BEFORE EATING, DRINKING,
SMOKING, USING TOILET/APPLYING COSMETICS. HAZ DECOMP PROD: OF
REVERSION TO HEXAVALENT CHROMIUM MAY OCCUR IF PIGMENT IS EXPOSED TO
ELEV ATED TEMPERATURES.
================== Physical/Chemical Properties ==================
Solubility in Water:NEGLIGIBLE
Appearance and Odor:FINE GREEN POWDER; ODORLESS.
Percent Volatiles by Volume:NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES AND ALKALI METALS. PIGMENT MAY REACT WITH CHLORINE
TRIFLUORIDE, LITHIUM, NITROALKANES, DIRUBIDIUM ACETYLIDE, OXYGEN
DIFLUORIDE AND OTHER STRONG OXIDIZERS.
Stability Condition to Avoid:TEMPERATURES ABOVE 600F. THERMAL
DECOMPOSITION. FLAMES.
Hazardous Decomposition Products:IN FIRE: HYDROGEN FLUORIDE & HYDROGEN
CHLORIDE ARE RELEASED DURING THERMAL DECOMP WHICH IS CORR & WILL
BURN ON CNTCT W/SKIN & OTHER TISS, & HAS TLV OF 3 PPM CEILING
LIMIT. SMALL AMOUNT (SUPDAT)
=================== Toxicological Information ===================
Toxicological Information:EFTS OF OVEREXP: "DOCUMENTATION OF THRESHOLD
LIMIT VALUES" RPTD & PRLNG EXPOS TO TRIVALENT CHROMIUM CMPDS MAY
CAUSE DELAYED EFTS INVOLVING RESP SYS. NO ACUTE TOX DATA IS AVAIL
FOR SILICA. CHRONIC: SIL ICOSIS: EXCESSIVE INHAL OF RESP
CRYSTALLINE SILICA DUST MAY CAUSE PROGRESSIVE, DISABLING &
SOMETIMES FATAL LUNG DISEASE CALLED SILICOSIS. SYMPS INCL COUGH,
SHORTNESS OF BREATH, WHEEZING, NON-SPECIFIC CHEST ILLNESS &
REDUCED PULM FUNCTION. THIS DISEASE IS EXACERBATED BY SMOKING.
INDIVIDUALS W/SILICOSIS ARE PREDISPOSED TO DEVELOP TUBERCULOSIS.
CANCER STATUS: IARC ON CANCER HAS DETERM THAT CRYSTALLIN E SILICA
(OTHER PREC)
===================== Ecological Information =====================
Ecological:NO DATA AVAILABLE ON THE ADVERSE EFFECTS OF POLYVINYIDENE
FLUORIDE ON THE ENVIRONMENT. BASED ON THE CHEMICAL COMPOSITION AND
WATER INSOLUBILITY OF KF POLYMER, IT IS ASSUMED THAT THE MATERIAL
WILL NOT CAUSE ANY SIGNIFICANT ADVERSE ENVIRONMENTAL EFFECTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:POLYVINYIDENE FLUORIDE IS NOT CONSIDERED A
HAZARDOUS WASTE UNDER FEDERAL HAZARDOUS WASTE REGULATIONS 40 CFR
261. DISPOSAL MUST BE MADE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS. PURSUANT TO 40 CFR PART 261 OF THE RCRA.
REGULATIONS CURRENTLY IN EFFECT, DISCARDED CHROMIUM (III) OXIDE WOU
LD NOT BE CLASSIFIED AS A HAZARDOUS WASTE.
=================== MSDS Transport Information ===================
Transport Information:DOT SHIPPING NAME:NOT REGULATED. DOT HAZ CLASS,
DOT LBL, UN/NA #: NONE. OTHER PREC:"REASONABLY ANTIC TO BE CARCIN".
OTHER DATA W/POSS RELEVANCE TO HUMAN HLTH:THERE IS SOME EVID THAT
BRTHG RESPIRABLE C RYSTALLINE SILICA/DISEASE SILICOSIS ISASSOC
W/INCR INCIDENCE OF SIGNIFICANT DISEASE ENDPOINTS, SUCH AS
SCLERODERMA (IMMUNE SYS DISORDER, MANIFESTED BY FIBROSIS OF LUNGS,
SKIN & OTHER INTERNAL ORGS) & KIDNEY DISEASE. FOR OTHER INFO,
CONSULT "ADVERSE EFTS OF CRYSTALLINE SILICA EXPOS PUBLISHED BY
AMERICAN THORACIC SOCIETY MED SECTION OF AMERICAN LUNG ASSOC,
AMERICAN JOURNAL OF RESP & CRITICAL CARE ME DICINE, VOL 155, PG
762-765, 1997.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302/304 - NO EXTREMELY HAZARDOUS
SUBSTANCES. SECTION 313 - THIS PRODUCT CONTAINS THE FOLLOWING TOXIC
CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF
THE EMERGENCY PLANNING AN D COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND
40 CFR 372: CHROMIUM (III) OXIDE. CHROMIUM (CR3+) CAS # 1308-38-9:
DISCLOSURE AS A TOXIC CHEMICAL IS REQUIRED UNDER SECTION 313 OF
TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF
1986 AND 40 CFR 372. CHROMIUM (AS CR3+).
Federal Regulatory Information:TSCA INVENTORY STATUS: ALL INGREDIENTS
ARE LISTED. CERCLA REPORTABLE QUANTITY: NONE.
State Regulatory Information:NOTE: CONSULT STATE AND LOCAL REGULATIONS
WHICH MAY APPLY. CALIFORNIA - PROPOSITION 65: THIS PIGMENT MAY
CONTAIN 100 PPM HEXAVALENT CHROMIUM. HEXAVALENT CHROMIUM IS ON THE
CALIFORNIA GOVERNOR'S LIST O F "CHEMICALS KNOWN TO CAUSE CANCER OR
REPRODUCTIVE TOXICITY." THE CALIFORNIA HEALTH AND WELFARE AGENCY
HAS ESTABLISHED A "NO SIGNIFICANT RISK" LEVEL FOR HEXAVALENT
CHROMIUM OF 0.001 MICROGRAMS/DAY. WO RKPLACE EXPOSURES TO THIS
PIGMENT BELOW THE TLV FOR CHROMIC OXIDE COULD RESULT IN EXPOSURES
TO HEXAV ALENT CHROMIUM IN EXCESS OF 0.001 MICROGRAM/DAY.
APPROPRIATE WARNING SHOULD BE GIVEN.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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