===================== Product Identification =====================
MSDS NAME:ABCITE 1060/60; X0545/X45 BLACK 9005/2
NIIN:00N093413
Status Code:A
MSDS Number: CJXXM
=== Responsible Party ===
Company:CONTINENTAL INDUSTRIES INC
Address:20757 SW 105TH AVE
Box:927
City:TUALATIN
State:OR
ZIP:97062
Country:US
Info Phone Num:503-692-3400
Emergency Phone Num:503-692-3400
Preparer's Name:JF BEHRENS
CAGE:TO416
=== Contractor Identification ===
Company:CONTINENTAL INDUSTRIES INC
Address:20757 SW 105TH AVE
Box:927
City:TUALATIN
State:OR
ZIP:97062
Country:US
Phone:503-692-3400
CAGE:TO416
============= Composition/Information on Ingredients =============
Name:ETHYLENE COPOLYMER, PARTIAL ZINC SALT
> Wt:90.
OSHA PEL:15MG/M3TOTALDUST
Name:ZINC COMPOUNDS
CAS:7440-66-6
RTECS #:ZG8600000
< Wt:5.
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:C.I. PIGMENT BLACK 28
CAS:68186-91-4
< Wt:1.
OSHA PEL:1MG/M3(AS CR)DUST
ACGIH TLV:0.5MG/M3(AS CR)DUST
Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
< Wt:1.
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:NO INFO AVAIL FOR THIS ABCITE
RESIN/FOR ETHYLENE COPOLYMER PARTIAL METAL SALT. BASED ON ITS
SIMILARITY TO OTHER POLYMERS, THIS ABCITE RESIN IS PREDICTED TO
HAVE LOW TOXICITY. EFTS OF OVEREXP STATEMENT S MAY NOT BE
APPLICABLE AS HAZ PIGMENT INGREDS LISTED ARE HOMOGENEOUSLY &
IONICALLY INTERDIFFUSED TO FORM A CRYSTALLINE MATRIX OF SPINEL.
ACUTE: INHAL: EXCESS INHAL OF DUST MAY CAUSE ACUTE PHYSICAL IR RIT
OF RESP TRACT. RPTD/EXCESS EXPOSURE MAY CAUSE COPPER POISONING. AT
PROCESSING TEMPS, ESPECIALLY ABOVE 300C(572F), FUMES WHICH ARE
IRRITATING TO EYES, NOSE & THROAT MAY BE RELEASED DUE TO POLYMER (
EFTS OF OVEREXP)
Explanation of Carcinogenicity:CARBON BLACK: MONOGRAPHS, VOL 65, PG
149, 1996: GROUP 2B.
Effects of Overexposure:HLTH HAZS: DEGRADATION & STABILIZER
VOLATILIZATION. EXPOSURE MAY RESULT IN REDNESS, ITCHING, & TEARING
OF EYES, & SORENESS IN NOSE & THROAT TOGETHER W/COUGHING. EYES:
PHYSICAL MECHANICAL IRRIT MAY RES ULT FROM CONT WITH DUST. SKIN:
DUSTS MAY HAVE DRYING EFT ON SKIN. PROLONGED/REPEATED CONT MAY
CAUSE IRRIT. NO UNUSUAL DERMATITIS PROBLEM IS EXPECTED FROM ROUTINE
HANDLING. MOLTEN POLYMER CONTACTING SK IN WILL CAUSE THERMAL BURNS.
INGEST: NOT PROBABLE ROUTE OF EXPOSURE. TOXICITY IS EXPECTED TO BE
LOW. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT.
======================= First Aid Measures =======================
First Aid:INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING
GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE
OXYGEN. GET MEDICAL ATTENTION. EYE CONTACT: FLUSH WITH PLENTY OF
WATER FOR AT LEAST 15 MINUTES. CALL PHYSICIAN IF IRRITATION
DEVELOPS, OR PERSISTS. SKIN: WASH WITH MILD SOAP AND WATER. GET
MEDICAL ATTENTION IF IRRITATION OCCURS. INGEST: GIVE 1-2 GLASSES OF
WATER TO DRINK AND T HEN INDUCE VOMITING. NEVER GIVE ANYTHING BY
MOUTH TO UNCONSCIOUS PERSON. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:SUPDAT
Autoignition Temp:Autoignition Temp Text:SUPDAT
Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CO*2.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . KEEP PERSONNEL REMOVED AND UPWIND OF FIRE. UNDER FIRE
CONDITIONS IRRITATING AND/OR TOXIC FUMES AND GASES MAY BE PRESENT.
AVOID DUSTING.
Unusual Fire/Explosion Hazard:HAZARDOUS GASES/VAPORS PRODUCED IN FIRE
ARE CARBON MONOXIDE, CARBON DIOXIDE HAZARDOUS OXIDATION PRODUCTS,
INCLUDING ORGANIC ACIDS, ALDEHYDES, ALCOHOLS AND ZINC OXIDES.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP, OR USE DRY VACUUM OR WET PROCEDURES.
AVOID GENERATING DUST DURING CLEANUP. RECOVER UNDAMAGED AND
MINIMALLY CONTAMINATED MATERIAL FOR REUSE AND RECLAMATION. AVOID
RUN-0FF INTO STORM SEWERS AND D ITCHES WHICH LEAD TO NATURAL
WATERWAYS.
====================== Handling and Storage ======================
Handling and Storage Precautions:SEE FIRST AID AND PERSONAL PROTECTIVE
SECTIONS. MINIMIZE DUST GENERATION AND ACCUMULATION. AVOID
BREATHING DUST. WASH HANDS BEFORE EATING AND SMOKING.
Other Precautions:KEEP AWAY FROM FOOD OR DRINKING WATER. KEEP CONTAINER
CLOSED TO PREVENT CONTAMINATION. STORE IN A COOL, DRY PLACE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATORS WITH HEPA FILTER.
Ventilation:USE PROCESS ENCLOSURES AND LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE DUST LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N0.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:GOOD HOUSEKEEPING PROCEDURES SHOULD BE FOLLOWED
TO PVNT DUST DURING PROCESSING. NEVER EAT, DRINK/SMOKE IN WORK
AREA. (SUPDAT)
Supplemental Safety and Health
FL PT: NONE. THE SOLID POLYMER CAN BE COMBUSTED ONLY WITH DIFFICULTY.
AUTOIGNITION TEMP: CARBON BLACK IGNIT IN AIR ABOVE 500F.HYGIENE
PRACT: PRACTICE GOOD PERSONAL HYGIENE AFTER USING MATL, ESPECIALLY
BEFORE EATING, DRINKING, SMKNG, USING TOILET/APPLYING COSMETICS.
================== Physical/Chemical Properties ==================
Solubility in Water:NEGLIGIBLE
Appearance and Odor:FINE BLACK POWDER. MILD METHACRYLIC ACID ODOR.
Percent Volatiles by Volume:NEGLIGIBLE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE OR CAN REACT WITH OXIDIZING AGENTS.
Stability Condition to Avoid:STABLE AT NORMAL TEMPERATURES AND STORAGE
CONDITIONS. TEMPERATURES ABOVE 300C(572F). STRONG OXIDIZERS, SUCH
AS CHLORATES, BROMATES AND NITRATES.
Hazardous Decomposition Products:IN FIRE: CARBON MONOXIDE; CARBON
DIOXIDE; HYDROCARBON OXIDATION PRODUCTS, INCLUDING ORGANIC ACIDS,
ALDEHYDES, ALCOHOLS AND ZINC CODES.
=================== Toxicological Information ===================
Toxicological Information:CHROMIUM & CERTAIN CMPDS HAVE BEEN LISTED AS
CARCINOGENIC, BOTH IN ANIMALS & HUMANS, BY NTP & IARC ON CANCER.
SOME CHROMIUM VI CMPDS ARE IDENTIFIED AS LUNG CARCINS BY
TOXICOLOGICAL STUDIES. EVID OF CH ROMIUM III CMPD CARCINOGENICITY
IN ANIMALS & HUMANS IS INCONCLUSIVE. THIS RPOD CNTNS CHROMIUM III.
CHRONIC: MANGANESE POISONING IS DFCLT TO RECOGNIZE. HDCH,
HYPERSOMNIA, SPASMS, WEAK OF LEGS, ARTHRALG IAS & IRRITABILITY ARE
FREQUENTLY NOTED. PROGRESSION OF DISEASE RLSTS IN VARIED
NEUROLOGICAL MANIFESTATIONS SUCH AS DISTURBANCES OF SPEECH,
(ECOLOGICAL INFO)
===================== Ecological Information =====================
Ecological:NO SPECIFIC INFO IS AVAIL. TOX OF ABCITE IS EXPECTED TO BE
LOW BASED ON INSOLUBILITY IN WATER. TOX INFO: GAIT & BALANCE, &
TREMORS. INDIVIDUALS W/WILSON'S DISEASE ARE AT INCR RISK OF COPPER
POISONING. CARBON BLACK - HUMAN STUDIES: EPIDEMIOLOGICAL STUDIES
OF WORKERS IN CARBON BLACK PRODUCING INDUSTRIES OF NORTH AMERICA &
WESTERN EUROPE SHOW SIGNIFICANT ADVERSE HLTH EFT DUE TO OCCUP EXPOS
TO CARBON BLACK. EARLY STUDIES IN FORMER USSR & EASTERN EUROPE RPT
RESP DISEASES AMONG WORKERS EXPOSED TO CARBON BLACK, INCL; BRONCH,
PNEUM, EMPHYSEMA & RHINITIS. (TRANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:PREFERRED OPTIONS FOR DISPOSAL ARE RECYCLING,
INCINERATION WITH ENERGY RECOVERY, AND LANDFILL. TREATMENT,
STORAGE, TRANSPORTATION AND DISPOSAL MUST BE IN ACCORDANCE WITH
APPLICABLE FEDERAL, STATE/PROV INCIAL, AND LOCAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:D.O.T. SHIPPING NAME: NOT REGULATED. D.O.T.
HAZARD CLASS: NOT REGULATED. D.O.T. LABEL: NOT REGUALTED. UN/NA
NUMBER: NOT REGULATED. ECOLOGICAL INFO: SUCH STUDIES ARE OF
QUESTIONABLE VALIDITY, DUE TO IN ADEQ STUDY DESIGN & METHODOLOGY,
LACK OF APPROP CONTROLS FOR CIGARETTE SMOKING, & OTHER CONFOUNDING
FACTORS, SUCH AS CONCURRENT EXPOSURES TO CARBON MONOXIDE, COAL OIL
& PETROLEUM VAPS. MOREOVER, REVIE W OF THESE STUDIES INDICATES THAT
CONCS OF CARBON BLACK WERE GREATER THAN CURRENT OCCUP EXPOSURE
STDS. IN MONO 65, ISSUED IN APRIL 1996, THE IARC ON CANCER (SARA
TITLE III)
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302/304 - NO EXTREMELY HAZ
SUBSTANCES. SECTION 313 - THIS PROD CNTNS FOLLOWING TOXIC CHEMS
SUBJECT TO RPTG REQUIREMENTS OF SECTION 313 OF EMERGENCY PLANNING &
COMMUNITY RIGHT-TO-KNOW ACT OF 19 86 & 40 CFR 372: COPPER, CHROMIUM
CMPDS, MANGANESE & ZINC COMPOUNDS. TRANSPORT INFO: RE-EVALUATED
CARBON BLACK & CONCLUDED THAT, "ALTHOUGH 1 COHORT STUDY ON CARBON
BLACK PRODUCTION INDUSTRY SHOWED SLI GHT EXCESSES OF CANCER,
TOTALITY OF EPIDEMIOLOGY STUDIES, BOTH IN CARBON BLACK PRODUCTION
INDUSTRY & IN SOME USER (FED REGULATORY INFO)
Federal Regulatory Information:TSCA INVENTORY STATUS: ALL INGREDIENTS
ARE LISTED. CERCLA REPORTABLE QUANTITY: NONE. NOTE: CONSULT STATE &
LOCAL REGS WHICH MAY APPLY. SARA TITLE III: INDUSTRIES, SUGGESTED
THAT THERE IS INADEQ EVID F OR CARCINOGENICITY IN HUMANS OF CARBON
BLACK." ANIMAL TOX STUDIES: THIS CARBON BLACK PIGMENT CNTNS <0.1%
OF ADSORBED PAH'S (POLYNUCLEAR AROMATIC HYDROCARBONS). IN
NON-ADSORBED FORM, SOME PAH'S HAVE BE EN FOUND TO BE CARCINS IN
ANIMAL STUDIES. NO CORRELATING CARCINOGENIC EFT, HOWEVER, HAS BEEN
OBSERVE D IN HUMANS DUE TO EXPOSURE TO CARBON BLACK. (STATE
REGULATORY INFO)
State Regulatory Information:N/P. FED REGULATORY INFO: CHRONIC INFLAMM,
LUNG FIBROSIS & LUNG TUMORS HAVE BEEN OBSERVED IN SOME RATS
EXPERIMENTALLY EXPOSED, FOR LONG PERIODS OF TIME, TO VERY HIGH
CONCS OF CARBON BLACK & SEVERAL OT HER INSOL FINE DUST PARTICLES.
TUMORS HAVE NOT BEEN OBSERVED IN OTHER ANIMAL SPECIES (I.E., MOUSE
& HAMSTER) UNDER SIMILAR CIRCUMSTANCES & STUDY CNDTNS. FOR MORE
INFORMATION CONT NEHC .
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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